Visible-Light-Catalyzed Direct Benzylic C(sp3)-H Amination Reaction by Cross-Dehydrogenative Coupling

Iodoarene-Catalyzed Stereospecific Intramolecular sp3 C–H Amination: Reaction Development and Mechanistic Insights

(2015) Chendan Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-catalysed azidation of tertiary C–H bonds suitable for late-stage functionalization

(2015) Ankit Sharma et al.   NATURE

Metal-free C–H amination of unactivated hydrocarbons with sulfonylimino-λ3-bromanes generated in situ from (diacetoxybromo)benzene

(2015) Kazunori Miyamoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Intramolecular C(sp3)H and C(sp2)H Amidation by Oxidative Cyclization

(2014) Zhen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient imidation of C(sp3)–H bonds adjacent to oxygen atoms of aryl ethers under metal-free conditions

(2014) Kai Sun et al.   CHEMICAL COMMUNICATIONS

Metal-free oxidative synthesis of quinazolinones via dual amination of sp3 C–H bonds

(2014) Dan Zhao et al.   CHEMICAL COMMUNICATIONS

Organic azides: “energetic reagents” for the intermolecular amination of C–H bonds

(2014) Daniela Intrieri et al.   CHEMICAL COMMUNICATIONS

n-Bu4NI/TBHP-catalyzed direct amination of allylic and benzylic C(sp3)–H with anilines under metal-free conditions

(2014) Xusheng Zhang et al.   CHEMICAL COMMUNICATIONS

Organocatalytic amination of alkyl ethers via n-Bu4NI/t-BuOOH-mediated intermolecular oxidative C(sp3)–N bond formation: novel synthesis of hemiaminal ethers

(2014) Longyang Dian et al.   CHEMICAL COMMUNICATIONS

Cooperative Effect of Two Metals: CoPd(OAc)4-Catalyzed CH Amination and Aziridination

(2014) Guan-Hao Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Intermolecular Amidation with Azides via C(sp3)–H Functionalization

(2014) Nuancheng Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Ligand-Controlled, Tunable Silver-Catalyzed C–H Amination

(2014) Juliet M. Alderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enzyme-Controlled Nitrogen-Atom Transfer Enables Regiodivergent C–H Amination

(2014) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analyzing Site Selectivity in Rh2(esp)2-Catalyzed Intermolecular C–H Amination Reactions

(2014) Elizabeth N. Bess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes

(2014) Ba L. Tran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Intermolecular Amidation of sp3 C–H Bonds: Late-Stage Functionalization of an Unactivated Methyl Group

(2014) Taek Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The road less travelled to amination

(2014) Olga V. Zatolochnaya et al.   Nature Chemistry

A powerful combination: recent achievements on using TBAI and TBHP as oxidation system

(2014) Xiao-Feng Wu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Aerobic Oxidative Amination of sp3C–H Bonds: Efficient Synthesis of 2-Hetarylquinazolin-4(3H)-ones

(2014) Qiang Li et al.   ORGANIC LETTERS

Transition-Metal-Assisted Radical/Radical Cross-Coupling: A New Strategy to the Oxidative C(sp3)–H/N–H Cross-Coupling

(2014) Liangliang Zhou et al.   ORGANIC LETTERS

Iron-Catalyzed Hetero-Cross-Dehydrogenative Coupling Reactions of Sulfoximines with Diarylmethanes: A New Route to N-Alkylated Sulfoximines

(2014) Ying Cheng et al.   ORGANIC LETTERS

Silver-catalysed direct amination of unactivated C–H bonds of functionalized molecules

(2014) Mingyu Yang et al.   Nature Communications

Iron-catalyzed efficient intermolecular amination of C(sp3)–H bonds with bromamine-T as nitrene source

(2014) Haiyu Wang et al.   RSC Advances

Iron-catalyzed/mediated oxidative transformation of C–H bonds

(2014) Fan Jia et al.   Organic Chemistry Frontiers

Stereoselective Synthesis of Chiral α-Amino-β-Lactams through Palladium(II)-Catalyzed Sequential Monoarylation/Amidation of C(sp3)H Bonds

(2013) Qi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Benzylic CH Activation for CO Bond Formation by Photoredox Catalysis

(2013) Ganesh Pandey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular C(sp3)N Coupling by Oxidation of Benzylic C,N-Dianions

(2013) Jenna L. Jeffrey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Regioselective Intermolecular Benzylic and Allylic CH Bond Amination

(2013) Yota Nishioka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Use of a Readily Removable Auxiliary Group for the Synthesis of Pyrrolidones by the Palladium-Catalyzed Intramolecular Amination of Unactivated γ C(sp3)H Bonds

(2013) Gang He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

(2013) Qicai Xue et al.   CHEMICAL COMMUNICATIONS

Mechanistic Insights into C–H Amination via Dicopper Nitrenes

(2013) Mae Joanne B. Aguila et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed redox-neutral C–H amination with amidoximes

(2013) Hui Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

1,2,3-Triazoles as versatile directing group for selective sp2 and sp3 C–H activation: cyclization vs substitution

(2013) Xiaohan Ye et al.   Chemical Science

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Intermolecular C(sp3)H Amidation

(2012) Álvaro Iglesias et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal-free Benzylic C–H Bond Intermolecular Amination Utilizing Chloramine-T and I2

(2012) Youhei Takeda et al.   CHEMISTRY LETTERS

Radical Amination of C(sp3)–H Bonds Using N-Hydroxyphthalimide and Dialkyl Azodicarboxylate

(2012) Yuuki Amaoka et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Tetramic Acid Derivatives via Intramolecular sp3 C–H Amination Mediated by Hypervalent Iodine(III) Reagents/Brønsted Acids

(2012) Lujia Mao et al.   JOURNAL OF ORGANIC CHEMISTRY

Intermolecular Ritter-Type C–H Amination of Unactivated sp3 Carbons

(2012) Quentin Michaudel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Intramolecular Allylic C–H Amination

(2012) Shauna M. Paradine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh2(II)-Catalyzed Intramolecular Aliphatic C–H Bond Amination Reactions Using Aryl Azides as the N-Atom Source

(2012) Quyen Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Aliphatic C–H Amination with an Amidine Moiety

(2012) Hui Chen et al.   ORGANIC LETTERS

CuI Controlled C–C and C–N Bond Formation of Heteroaromatics through C(sp3)–H Activation

(2012) Ran Xia et al.   ORGANIC LETTERS

Copper-Catalyzed sp3 C–H Amination

(2012) Raymond T. Gephart et al.   ORGANOMETALLICS

Intermolecular Hydrogen Abstraction Reaction between Nitrogen Radicals in Purine Rings and Alkyl Ethers: A Highly Selective Method for the Synthesis of N-9 Alkylated Purine Nucleoside Derivatives

(2011) Hai-Ming Guo et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Regioselective Copper-Catalyzed Benzylic CH Amination by N-Fluorobenzenesulfonimide

(2011) Zhikun Ni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)-Catalyzed Intermolecular Amination of Unactivated C sp 3H Bonds

(2011) Jun Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free, organocatalytic cascade formation of C–N and C–O bonds through dual sp3C–H activation: oxidative synthesis of oxazole derivatives

(2011) Jin Xie et al.   CHEMICAL COMMUNICATIONS

Catalytic C–H amination: the stereoselectivity issue

(2011) Florence Collet et al.   CHEMICAL SOCIETY REVIEWS

Direct C–N Coupling of Imidazoles and Benzylic Compounds via Iron-Catalyzed Oxidative Activation of C–H Bonds

(2011) Qinqin Xia et al.   JOURNAL OF ORGANIC CHEMISTRY

Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp2and Benzylic sp3C–H Bond Imidation

(2011) Hyun Jin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterocycle Synthesis via Direct C–H/N–H Coupling

(2011) Enrico T. Nadres et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Syntheses of Azetidines, Pyrrolidines, and Indolines via Palladium Catalyzed Intramolecular Amination of C(sp3)–H and C(sp2)–H Bonds at γ and δ Positions

(2011) Gang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Diruthenium Catalyst for Selective, Intramolecular Allylic C–H Amination: Reaction Development and Mechanistic Insight Gained through Experiment and Theory

(2011) Mark Edwin Harvey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regioselective Amination of Unactivated Alkanes by Hypervalent Sulfonylimino- 3-Bromane

(2011) M. Ochiai et al.   SCIENCE

Remote amide-directed palladium-catalyzed benzylic C–H amination with N-fluorobenzenesulfonimide

(2010) Tao Xiong et al.   CHEMICAL COMMUNICATIONS

Recent advances in transition metal-catalyzed N-atom transfer reactions of azides

(2010) Tom G. Driver   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Amidation of Unactivated C(sp3)H Bonds: from Anilines to Indolines

(2009) Julia J. Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–H amination: recent progress and future directions

(2009) Florence Collet et al.   CHEMICAL COMMUNICATIONS

A Catalytic, Brønsted Base Strategy for Intermolecular Allylic C−H Amination

(2009) Sean A. Reed et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free Intermolecular Amination of sp3C−H Bonds with Sulfonamides

(2009) Renhua Fan et al.   ORGANIC LETTERS

Hydrous zinc halide-catalyzed aminosulfonation of hydrocarbons

(2008) Biswajit Kalita et al.   CHEMICAL COMMUNICATIONS

N‐Tosyloxycarbamates as Reagents in Rhodium‐Catalyzed CH Amination Reactions

(2008) Kim Huard et al.   CHEMISTRY-A EUROPEAN JOURNAL

General and Efficient Copper-Catalyzed Amidation of Saturated C−H Bonds UsingN-Halosuccinimides as the Oxidants

(2008) Xiaowei Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE