Recent advances in molecular rearrangements involving aryne intermediates

Synthesis of Functionalized β-Keto Arylthioethers by the Aryne Induced [2,3] Stevens Rearrangement of Allylthioethers

(2017) Manikandan Thangaraj et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Synthesis of 2-Substituted 3-(2-Hydroxyaryl)quinolines and 4-(2-Hydroxyaryl)acridines via Benzyne Chemistry

(2017) Ankit Kumar Dhiman et al.   JOURNAL OF ORGANIC CHEMISTRY

Aryne triggered [2,3]-sigmatropic rearrangement of allyl and propargyl thioethers

(2017) Jiajing Tan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent advances in fluoride-free aryne generation from arene precursors

(2017) Fahima I. M. Idiris et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stevens rearrangement of thioethers with arynes: a facile access to multi-substituted β-keto thioethers

(2017) Xiao-Bo Xu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Reaction of Arynes with Vinyl Sulfoxides: Highly Stereospecific Synthesis of ortho-Sulfinylaryl Vinyl Ethers

(2017) Yuanming Li et al.   ORGANIC LETTERS

3-Hydroxy-2-(trialkylsilyl)phenyl Triflate: A Benzyne Precursor Triggered via 1,3-C-sp2-to-O Silyl Migration

(2017) Yong-Ju Kwon et al.   ORGANIC LETTERS

Synthesis of Diverse o-Arylthio-Substituted Diaryl Ethers by Direct Oxythiolation of Arynes with Diaryl Sulfoxides Involving Migratory O-Arylation

(2017) Tsubasa Matsuzawa et al.   ORGANIC LETTERS

Coumarin to Isocoumarin: One-Pot Synthesis of 3-Substituted Isocoumarins from 4-Hydroxycoumarins and Benzyne Precursors

(2017) Kashmiri Neog et al.   ORGANIC LETTERS

Highly Selective Synthesis of Dihydrobenzo[d]isoxazoles and Dihydrobenzo[d]oxazoles from Oximes and Arynes via in Situ Generation of Nitrones

(2017) Tuanli Yao et al.   ORGANIC LETTERS

Methodology and applications of the hexadehydro-Diels–Alder (HDDA) reaction

(2017) Oliver J. Diamond et al.   Organic Chemistry Frontiers

Employing Arynes in Diels–Alder Reactions and Transition-Metal-Free Multicomponent Coupling and Arylation Reactions

(2016) Sachin Suresh Bhojgude et al.   ACCOUNTS OF CHEMICAL RESEARCH

Sulfonium Ylides by (3+2) Cycloaddition of Arynes with Vinyl Sulfides: Stereoselective Synthesis of Highly Substituted Alkenes

(2016) Yuanming Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce-Smiles Rearrangement

(2016) Catherine M. Holden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of functionalized amino epoxides by a three-component coupling involving aziridines, arynes and aldehydes

(2016) Tony Roy et al.   CHEMICAL COMMUNICATIONS

Synthesis of biaryls using aryne intermediates

(2016) José-Antonio García-López et al.   CHEMICAL SOCIETY REVIEWS

Tandem Aryne-Capture/Sigmatropic Rearrangement as a Metal-Free Entry to Functionalized N -Aryl Pyrrolidines

(2016) Sam G. Moss et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tandem Reaction of Arynes with Tertiary Amines and Aldehydes: Formation of 9- and 10-Membered Dibenzo[1,5]oxaza Heterocycles

(2016) Kentaro Okuma et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The Epoxidation of Carbonyl Compounds with a Benzyne-Triggered Sulfur Ylide

(2016) Mei-Mei Lou et al.   JOURNAL OF ORGANIC CHEMISTRY

Aryne 1,2,3-Trifunctionalization with Aryl Allyl Sulfoxides

(2016) Yuanyuan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryne-Mediated [2,3]-Sigmatropic Rearrangement of Tertiary Allylic Amines

(2016) Juan Zhang et al.   ORGANIC LETTERS

The Aryne [2,3] Stevens Rearrangement

(2016) Tony Roy et al.   ORGANIC LETTERS

Reactions of Hexadehydro-Diels–Alder (HDDA)-Derived Benzynes with Thioamides: Synthesis of Dihydrobenzothiazino-Heterocyclics

(2016) Vignesh Palani et al.   ORGANIC LETTERS

Substrate-Controlled Selectivity Switch in the Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and CO2

(2016) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Pyridynes and indolynes as building blocks for functionalized heterocycles and natural products

(2015) Adam E. Goetz et al.   CHEMICAL COMMUNICATIONS

Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation

(2015) Suguru Yoshida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryne generation vs. Truce-Smiles and fries rearrangements during the Kobayashi fragmentation reaction: a new bi-aryl synthesis

(2015) O. K. Rasheed et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of o-Aminophenols via a Formal Insertion Reaction of Arynes into Hydroxyindolinones

(2015) Zhilong Chen et al.   ORGANIC LETTERS

Reaction of Arynes with Sulfoxides

(2015) Hong-Ying Li et al.   ORGANIC LETTERS

Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and Aldehydes via Aryl–Aryl Amino Group Migration

(2015) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Catalytic Stereoselective [2,3]-Rearrangement Reactions

(2015) Thomas H. West et al.   ACS Catalysis

The Hexadehydro-Diels-Alder Reaction: A New Chapter in Aryne Chemistry

(2014) Catherine Holden née Hall et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Practical Synthesis of Phthalimides and Benzamides by a Multicomponent Reaction Involving Arynes, Isocyanides, and CO2/H2O

(2014) Trinadh Kaicharla et al.   ORGANIC LETTERS

Interception of benzyne with thioethers: a facile access to sulfur ylides under mild conditions

(2014) Hua-Dong Xu et al.   RSC Advances

Transition-Metal-Free Multicomponent Reactions Involving Arynes, N-Heterocycles, and Isatins

(2013) Anup Bhunia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tandem thia-Fries rearrangement – cyclisation of 2-(trimethylsilyl)phenyl trifluoromethanesulfonate benzyne precursors

(2013) Catherine Hall et al.   CHEMICAL COMMUNICATIONS

Aryne Cycloaddition Reactions in the Synthesis of Large Polycyclic Aromatic Compounds

(2013) Dolores Pérez et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Multicomponent Reactions Involving Arynes, Quinolines, and Aldehydes

(2013) Anup Bhunia et al.   ORGANIC LETTERS

Employing Arynes in Transition-Metal-Free Monoarylation of Aromatic Tertiary Amines

(2013) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Tactics for probing aryne reactivity: mechanistic studies of silicon–oxygen bond cleavage during the trapping of (HDDA-generated) benzynes by silyl ethers

(2013) Thomas R. Hoye et al.   Chemical Science

Arynes in Transition-Metal-Free Multicomponent Coupling Reactions

(2012) Sachin Suresh Bhojgude et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arynes and Cyclohexyne in Natural Product Synthesis

(2012) Christian M. Gampe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

(2012) Anup Bhunia et al.   CHEMICAL SOCIETY REVIEWS

The hexadehydro-Diels–Alder reaction

(2012) Thomas R. Hoye et al.   NATURE

Use of benzynes for the synthesis of heterocycles

(2012) Anton V. Dubrovskiy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cycloaddition Reaction of 2-Vinylazetidines with Benzyne: A Facile Access to 1-Benzazocine Derivatives

(2012) Takashi Aoki et al.   ORGANIC LETTERS

Insertion of Arynes into Thioureas: A New Amidine Synthesis

(2011) Kallolmay Biswas et al.   ORGANIC LETTERS

Aryne,ortho-Quinone Methide, andortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates

(2010) Hiroto Yoshida et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

The Benzyne Aza-Claisen Reaction

(2009) Alastair A. Cant et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sigmatropic rearrangements of ‘onium’ ylids

(2009) J. B. Sweeney   CHEMICAL SOCIETY REVIEWS

[3,3]-Sigmatropic rearrangements: recent applications in the total synthesis of natural products

(2009) Elizabeth A. Ilardi et al.   CHEMICAL SOCIETY REVIEWS

Insertion of Benzene Rings into the Amide Bond: One-Step Synthesis of Acridines and Acridones from Aryl Amides

(2009) Didier G. Pintori et al.   ORGANIC LETTERS

RECENT APPLICATIONS OF ARYNE CHEMISTRY TO ORGANIC SYNTHESIS. A REVIEW

(2009) Roberto Sanz   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

A truce on the Smiles rearrangement: revisiting an old reaction—the Truce–Smiles rearrangement

(2008) Timothy J. Snape   CHEMICAL SOCIETY REVIEWS