Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 13, Pages 2716-2720Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob00277g
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Funding
- Fundamental Research Funds for the Central Universities [0903005203486]
- National Natural Science Foundation of China [21572027, 21372267]
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An effective method for the synthesis of multi-substituted beta-keto thioethers via Stevens rearrangement of simple beta-keto thioethers with arynes has been developed. In these reactions, successive C-S/C-H/C-C bonds were formed in one pot under mild and transition-metal free conditions to afford multi-substituted beta-keto thioethers in moderate to good yields.
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