Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 8, Pages 4470-4476Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b00479
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Funding
- Science and Engineering Research Board (SERB-DST), Government of India [SR/S1/OC/12/2012]
- CSIR
- UGC
- DST
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A mild and transition-metal-free synthesis of beta-keto arylthioethers has been developed by the aryne triggered [2,3] Stevens rearrangement of allylthioethers. The key sulfur ylide intermediate for the rearrangement was formed by the S-arylation of allylthioethers with arynes generated from 2-(trimethylsilyl)aryl triflates using CsF. Later, the reaction products are converted into valuable heterocycles in two steps.
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