Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 29, Pages 8048-8052Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01239b
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Funding
- Samuel Greatrix Fund
- University of Manchester
- Engineering and Physical Sciences Research Council [EP/K039547/1] Funding Source: researchfish
- EPSRC [EP/K039547/1] Funding Source: UKRI
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Treatment of (ortho-trimethysilyl)aryl phenylsulfonates with a soluble fluoride source initiates a Truce-Smiles rearrangement leading to the formation of functionalized bi-aryls. This new carbon-carbon bond-forming reaction proceeds without recourse to transition metal catalysis, under mild reaction conditions and with good functional group compatibility.
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