Asymmetric synthesis of CF3- and indole-containing tetrahydro-β-carbolines via chiral spirocyclic phosphoric acid-catalyzed aza-Friedel–Crafts reaction

Recent progress in transition-metal-catalyzed enantioselective indole functionalizations

(2017) Jing-Biao Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organocatalytic Asymmetric Synthesis of Dihydrobenzoxazinones Bearing Trifluoromethylated Quaternary Stereocenters

(2016) Hengqiao Lou et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphoric Acid-Catalyzed Asymmetric Synthesis of SPINOL Derivatives

(2016) Shaoyu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of CF3- and Indole-Containing Thiochromanes via a Squaramide-Catalyzed Michael–Aldol Reaction

(2016) Yuanyuan Zhu et al.   ORGANIC LETTERS

Organocatalytic Asymmetric Addition of Naphthols and Electron-Rich Phenols to Isatin-Derived Ketimines: Highly Enantioselective Construction of Tetrasubstituted Stereocenters

(2015) Marc Montesinos-Magraner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

H8-BINOL chiral imidodiphosphoric acid catalyzed highly enantioselective aza-Friedel–Crafts reactions of pyrroles and enamides/imines

(2015) Kun Wu et al.   CHEMICAL COMMUNICATIONS

Stereoselective Synthesis of Chiral Polycyclic Indolic Architectures through Pd0-Catalyzed Tandem Deprotection/Cyclization of Tetrahydro-β-carbolines on Allenes

(2015) Valérian Gobé et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triply Hydrogen-Bond-Directed Enantioselective Assembly of Pyrrolobenzo-1,4-diazine Skeletons with Quaternary Stereocenters

(2015) Xiaoming Shen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dynamic Kinetic Asymmetric Amination of Alcohols: From A Mixture of Four Isomers to Diastereo- and Enantiopure α-Branched Amines

(2015) Zi-Qiang Rong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogenative Dearomatization of Pyridine and an Asymmetric Aza-Friedel-Crafts Alkylation Sequence

(2014) Shuo-Guo Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Arylative Dearomatization of 2,3-Disubstituted Indoles Enabled by Tandem Reactions

(2014) Yu-Chen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of benzazepinoindoles bearing trifluoromethylated quaternary stereocenters catalyzed by chiral spirocyclic phosphoric acids

(2014) Xuejian Li et al.   CHEMICAL COMMUNICATIONS

Fluorine effects in organocatalysis – asymmetric Brønsted acid assisted Lewis base catalysis for the synthesis of trifluoromethylated heterocycles exploiting the negative hyperconjugation of the CF3-group

(2014) Chandra M. R. Volla et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Chiral Phosphoric Acid-Catalyzed Asymmetric Aza-Friedel-Crafts Reaction of Indoles with CyclicN-Acylketimines: Enantioselective Synthesis of Trifluoromethyldihydroquinazolines

(2013) Ke-Feng Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Complex Bioactive Alkaloid-Type Polycycles through Efficient Catalytic Asymmetric Multicomponent Aza-Diels-Alder Reaction of Indoles with Oxetane as Directing Group

(2013) Zhilong Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic asymmetric multicomponent reactions of aromatic aldehydes and anilines with β-ketoesters: facile and atom-economical access to chiral tetrahydropyridines

(2013) Xuejian Li et al.   CHEMICAL COMMUNICATIONS

Highly Enantioselective Construction of Trifluoromethylated All-Carbon Quaternary Stereocenters via Nickel-Catalyzed Friedel–Crafts Alkylation Reaction

(2013) Jian-Rong Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Brønsted acid-catalyzed enantioselective addition of indoles to ketimines

(2013) Taichi Kano et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A combination of directing groups and chiral anion phase-transfer catalysis for enantioselective fluorination of alkenes

(2013) Jeffrey Wu et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Highly Enantioselective Synthesis of Dihydroquinazolinones Catalyzed by SPINOL-Phosphoric Acids

(2013) Dan Huang et al.   ACS Catalysis

Highly Enantioselective Pictet-Spengler Reaction Catalyzed by SPINOL-Phosphoric Acids

(2012) Dan Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Asymmetric Synthesis of 1,2,4-Trioxane Anticancer Agents via Desymmetrization of Peroxyquinols through a Brønsted Acid Catalysis Cascade

(2012) David M. Rubush et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric NH Insertion Reaction Cooperatively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids

(2011) Bin Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Pictet-Spengler Reaction in Nature and in Organic Chemistry

(2011) Joachim Stöckigt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acids in enantioselective carbonyl activations – activation modes and applications

(2011) Magnus Rueping et al.   CHEMICAL SOCIETY REVIEWS

Optically Active 1,1′-Spirobiindane-7,7′-diol (SPINOL)-Based Phosphoric Acids as Highly Enantioselective Catalysts for Asymmetric Organocatalysis

(2011) Chun-Hui Xing et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Organocatalytic Synthesis of Quaternary α-Amino Acids Bearing a CF3Moiety

(2011) Ralph Husmann et al.   ORGANIC LETTERS

Organocatalytic Asymmetric Strecker Reaction of Di- and Trifluoromethyl Ketoimines. Remarkable Fluorine Effect

(2011) Yun-Lin Liu et al.   ORGANIC LETTERS

Discovery of tetrahydro-β-carbolines as inhibitors of the mitotic kinesin KSP

(2010) Fei Liu et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

(2010) Anna J. Kochanowska-Karamyan et al.   CHEMICAL REVIEWS

SPINOL-Derived Phosphoric Acids: Synthesis and Application in Enantioselective Friedel−Crafts Reaction of Indoles with Imines

(2010) Fangxi Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Kinetic Resolution of Homoaldols via Catalytic Asymmetric Transacetalization

(2010) Ilija Čorić et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

(2010) Masahiro Terada   SYNTHESIS-STUTTGART

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acid catalyzed Friedel–Crafts alkylation reactions

(2009) Shu-Li You et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of fluorinated chiral amines usingN-tert-butylsulfinyl imines

(2009) Jun Liu et al.   Future Medicinal Chemistry

A β-Carboline Alkaloid from the Papua New Guinea Marine SpongeHyrtios reticulatus

(2009) Wayne D. Inman et al.   JOURNAL OF NATURAL PRODUCTS

Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions

(2008) Masahiro Terada   CHEMICAL COMMUNICATIONS

Catalytic Asymmetric Friedel−Crafts Alkylation ReactionsCopper Showed the Way

(2008) Thomas B. Poulsen et al.   CHEMICAL REVIEWS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS