期刊
ORGANIC CHEMISTRY FRONTIERS
卷 4, 期 7, 页码 1407-1410出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00229g
关键词
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资金
- National Natural Science Foundation of China [21572200]
- Fundamental Research Funds for the Central Universities
An enantioselective aza-Friedel-Crafts alkylation reaction of indoles with 1-trifluoromethyl-3,4-dihydro-beta-carbolines catalyzed by a chiral spirocyclic phosphoric acid has been realized. This methodology provides a facile route to 1-trifluoromethyl-1-indole-substituted tetrahydro-beta-carbolines featuring a CF(3)(-)containing quaternary stereocenter in considerable yields and good enantioselectivities.
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