Manganese complex-catalyzed oxidation and oxidative kinetic resolution of secondary alcohols by hydrogen peroxide

A new look at the role of thiolate ligation in cytochrome P450

(2017) Timothy H. Yosca et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants

(2017) Subhasree Kal et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations

(2017) Giorgio Olivo et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes

(2017) Michela Milan et al.   ACS Central Science

Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes

(2016) Xenia Engelmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bioinspired Mn-aminopyridine catalyzed epoxidations of olefins with various oxidants: Enantioselectivity and mechanism

(2016) Roman V. Ottenbacher et al.   CATALYSIS TODAY

Simple and Efficient Ruthenium-Catalyzed Oxidation of Primary Alcohols with Molecular Oxygen

(2016) Ritwika Ray et al.   CHEMISTRY-A EUROPEAN JOURNAL

Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes

(2016) Giorgio Olivo et al.   Chemistry-An Asian Journal

Spectroscopic analyses of 2-oxoglutarate-dependent oxygenases: TauD as a case study

(2016) Denis A. Proshlyakov et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Proton-Promoted and Anion-Enhanced Epoxidation of Olefins by Hydrogen Peroxide in the Presence of Nonheme Manganese Catalysts

(2016) Chengxia Miao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective

(2016) Sumit Sahu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts

(2016) Roman Ottenbacher et al.   MOLECULES

Oxidative diversification of amino acids and peptides by small-molecule iron catalysis

(2016) Thomas J. Osberger et al.   NATURE

Mechanism of Alkene, Alkane, and Alcohol Oxidation with H2O2 by an in Situ Prepared MnII/Pyridine-2-carboxylic Acid Catalyst

(2016) Pattama Saisaha et al.   ACS Catalysis

Iron-Catalyzed Enantioselective Epoxidations with Various Oxidants: Evidence for Different Active Species and Epoxidation Mechanisms

(2016) Alexandra M. Zima et al.   ACS Catalysis

Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates

(2015) Wonwoo Nam   ACCOUNTS OF CHEMICAL RESEARCH

Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes

(2015) Mayank Puri et al.   ACCOUNTS OF CHEMICAL RESEARCH

Molecular Designs for Controlling the Local Environments around Metal Ions

(2015) Sarah A. Cook et al.   ACCOUNTS OF CHEMICAL RESEARCH

Bioinspired Nonheme Iron Catalysts for C–H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants

(2015) Williamson N. Oloo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly efficient oxidation of alcohols catalyzed by a porphyrin-inspired manganese complex

(2015) Wen Dai et al.   CHEMICAL COMMUNICATIONS

A nonheme manganese(iv)–oxo species generated in photocatalytic reaction using water as an oxygen source

(2015) Xiujuan Wu et al.   CHEMICAL COMMUNICATIONS

Catalytic oxidation of water and alcohols by a robust iron(iii) complex bearing a cross-bridged cyclam ligand

(2015) Peng Tan et al.   CHEMICAL COMMUNICATIONS

Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives

(2015) Olaf Cussó et al.   CHEMICAL COMMUNICATIONS

The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations

(2015) Zhuqi Chen et al.   CHEMICAL SOCIETY REVIEWS

High-valent metal-oxo intermediates in energy demanding processes: from dioxygen reduction to water splitting

(2015) Kallol Ray et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Mechanism of Alcohol Oxidation by FeV(O) at Room Temperature

(2015) Munmun Ghosh et al.   INORGANIC CHEMISTRY

Mesoporous helical silica immobilizing manganese(III)-salen complex for oxidative kinetic resolution of secondary alcohols

(2015) Lin Ren et al.   JOURNAL OF POROUS MATERIALS

Formation and characterization of a reactive chromium(v)–oxo complex: mechanistic insight into hydrogen-atom transfer reactions

(2015) Hiroaki Kotani et al.   Chemical Science

Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes

(2014) Wonwoo Nam et al.   ACCOUNTS OF CHEMICAL RESEARCH

Biomimetic Iron-Catalyzed Asymmetric Epoxidations: Fundamental Concepts, Challenges and Opportunities

(2014) Feyissa Gadissa Gelalcha   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium-Catalyzed Oxidative Kinetic Resolution of Unactivated and Activated Secondary Alcohols with Air as the Hydrogen Acceptor at Room Temperature

(2014) Hirotaka Mizoguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Kinetic Resolution of Secondary Alcohols with Salen–Mn(III)/NBS/NaClO System

(2014) Yuecheng Zhang et al.   CATALYSIS LETTERS

Active sites and mechanisms of bioinspired oxidation with H2O2, catalyzed by non-heme Fe and related Mn complexes

(2014) Konstantin P. Bryliakov et al.   COORDINATION CHEMISTRY REVIEWS

Highly Enantioselective Organocatalytic Oxidative Kinetic Resolution of Secondary Alcohols Using Chiral Alkoxyamines as Precatalysts: Catalyst Structure, Active Species, and Substrate Scope

(2014) Keiichi Murakami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2

(2014) Duyi Shen et al.   ORGANIC LETTERS

Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations

(2014) Williamson N. Oloo et al.   Nature Communications

Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and their Applications in Organic Synthesis

(2013) Alexandre Lumbroso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complex with sodium hypochlorite as oxidant

(2013) Yuecheng Zhang et al.   CATALYSIS COMMUNICATIONS

Chiral Iron Catalysts for Asymmetric Synthesis

(2013) Kovuru Gopalaiah   CHEMICAL REVIEWS

Nonheme Iron Oxidant Formed in the Presence of H2O2 and Acetic Acid Is the Cyclic Ferric Peracetate Complex, Not a Perferryloxo Complex

(2013) Yong Wang et al.   ACS Catalysis

Mechanisms in manganese catalysed oxidation of alkenes with H2O2

(2012) Pattama Saisaha et al.   CHEMICAL SOCIETY REVIEWS

Chemo- and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

(2012) Evgenii P. Talsi et al.   COORDINATION CHEMISTRY REVIEWS

Catalytic reactions of chlorite with a polypyridylruthenium(ii) complex: disproportionation, chlorine dioxide formation and alcohol oxidation

(2011) Zongmin Hu et al.   CHEMICAL COMMUNICATIONS

Aerobic Oxidative Kinetic Resolution of Secondary Alcohols with Naphthoxide-Bound Iron(salan) Complex

(2011) Takashi Kunisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverting non-haem iron catalysed aliphatic C–H hydroxylations towards desaturations

(2011) Marinus A. Bigi et al.   Nature Chemistry

Iron-Catalyzed Olefin Epoxidation and cis-Dihydroxylation by Tetraalkylcyclam Complexes: the Importance of cis-Labile Sites

(2011) Yan Feng et al.   ACS Catalysis

Mechanism of the Enantioselective Oxidation of Racemic Secondary Alcohols Catalyzed by Chiral Mn(III)−Salen Complexes

(2010) M. Kevin Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE

Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts

(2009) Jihae Yoon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biologically inspired oxidation catalysis

(2008) Lawrence Que et al.   NATURE

The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope

(2008) Qigan Cheng et al.   TETRAHEDRON-ASYMMETRY