A new look at the role of thiolate ligation in cytochrome P450

Reactivity of an FeIV-Oxo Complex with Protons and Oxidants

(2016) Ethan A. Hill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ferryl Protonation in Oxoiron(IV) Porphyrins and Its Role in Oxygen Transfer

(2015) Nicholas C. Boaz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Significantly shorter Fe–S bond in cytochrome P450-I is consistent with greater reactivity relative to chloroperoxidase

(2015) Courtney M. Krest et al.   Nature Chemistry

Setting an Upper Limit on the Myoglobin Iron(IV)Hydroxide pKa: Insight into Axial Ligand Tuning in Heme Protein Catalysis

(2014) Timothy H. Yosca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Neutron cryo-crystallography captures the protonation state of ferryl heme in a peroxidase

(2014) C. M. Casadei et al.   SCIENCE

Driving Force for Oxygen-Atom Transfer by Heme-Thiolate Enzymes

(2013) Xiaoshi Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron(IV)hydroxide pKa and the Role of Thiolate Ligation in C-H Bond Activation by Cytochrome P450

(2013) T. H. Yosca et al.   SCIENCE

Detection and Kinetic Characterization of a Highly Reactive Heme–Thiolate Peroxygenase Compound I

(2012) Xiaoshi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective hydroxylation of alkanes by an extracellular fungal peroxygenase

(2011) Sebastian Peter et al.   FEBS Journal

Unprecedented Rate Enhancements of Hydrogen-Atom Transfer to a Manganese(V)-Oxo Corrolazine Complex

(2010) Katharine A. Prokop et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystallographic and Single-Crystal Spectral Analysis of the Peroxidase Ferryl Intermediate

(2010) Yergalem T. Meharenna et al.   BIOCHEMISTRY

Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

(2010) J. Rittle et al.   SCIENCE

Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes

(2009) Paul R. Ortiz de Montellano   CHEMICAL REVIEWS

Enhanced Reactivities of Iron(IV)-Oxo Porphyrin π-Cation Radicals in Oxygenation Reactions by Electron-Donating Axial Ligands

(2009) Yaeun Kang et al.   CHEMISTRY-A EUROPEAN JOURNAL

CH bond activation in heme proteins: the role of thiolate ligation in cytochrome P450

(2009) Michael T Green   CURRENT OPINION IN CHEMICAL BIOLOGY

Effect of Imidazole and Phenolate Axial Ligands on the Electronic Structure and Reactivity of Oxoiron(IV) Porphyrin π-Cation Radical Complexes: Drastic Increase in Oxo-Transfer and Hydrogen Abstraction Reactivities

(2009) Akihiro Takahashi et al.   INORGANIC CHEMISTRY