Enantioselective synthesis of cyclic quaternary α-amino acid derivatives by chiral phosphoric acid catalysis

Recent progress in transition-metal-catalyzed enantioselective indole functionalizations

(2017) Jing-Biao Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric synthesis of CF3- and indole-containing tetrahydro-β-carbolines via chiral spirocyclic phosphoric acid-catalyzed aza-Friedel–Crafts reaction

(2017) En Xie et al.   Organic Chemistry Frontiers

Organocatalytic Asymmetric Synthesis of Dihydrobenzoxazinones Bearing Trifluoromethylated Quaternary Stereocenters

(2016) Hengqiao Lou et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphoric Acid-Catalyzed Asymmetric Synthesis of SPINOL Derivatives

(2016) Shaoyu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Construction of Cyclic Indolyl α-Amino Estersviaa Friedel-Crafts Alkylation Reaction

(2015) Liang Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Organocatalytic Asymmetric Addition of Naphthols and Electron-Rich Phenols to Isatin-Derived Ketimines: Highly Enantioselective Construction of Tetrasubstituted Stereocenters

(2015) Marc Montesinos-Magraner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

H8-BINOL chiral imidodiphosphoric acid catalyzed highly enantioselective aza-Friedel–Crafts reactions of pyrroles and enamides/imines

(2015) Kun Wu et al.   CHEMICAL COMMUNICATIONS

Stereoselective Synthesis of Chiral Polycyclic Indolic Architectures through Pd0-Catalyzed Tandem Deprotection/Cyclization of Tetrahydro-β-carbolines on Allenes

(2015) Valérian Gobé et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic Enantioselective Decarboxylative Reaction of Malonic Acid Half Thioesters with CyclicN-Sulfonyl Ketimines by UsingN-Heteroarenesulfonyl Cinchona Alkaloid Amides

(2015) Shuichi Nakamura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triply Hydrogen-Bond-Directed Enantioselective Assembly of Pyrrolobenzo-1,4-diazine Skeletons with Quaternary Stereocenters

(2015) Xiaoming Shen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dynamic Kinetic Asymmetric Amination of Alcohols: From A Mixture of Four Isomers to Diastereo- and Enantiopure α-Branched Amines

(2015) Zi-Qiang Rong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio-, Diastereo-, and Enantioselective Mannich Reaction of Allylic Ketones and Cyclic Ketimines: Access to Chiral Benzosultam

(2015) Baokun Qiao et al.   ORGANIC LETTERS

Bifunctional Amino Sulfonohydrazide Catalyzed Direct Asymmetric Mannich Reaction of Cyclic Ketimines with Ketones: Highly Diastereo- and Enantioselective Construction of Quaternary Carbon Stereocenters

(2015) Sheng Zhang et al.   ORGANIC LETTERS

Nickel-Catalyzed Enantioselective Addition of Styrenes to Cyclic N-Sulfonyl α-Ketiminoesters

(2015) Ren-Rong Liu et al.   ACS Catalysis

Hydrogenative Dearomatization of Pyridine and an Asymmetric Aza-Friedel-Crafts Alkylation Sequence

(2014) Shuo-Guo Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Arylative Dearomatization of 2,3-Disubstituted Indoles Enabled by Tandem Reactions

(2014) Yu-Chen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of benzazepinoindoles bearing trifluoromethylated quaternary stereocenters catalyzed by chiral spirocyclic phosphoric acids

(2014) Xuejian Li et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Fluorescence Polarization for the Evaluation of Small-Molecule Inhibitors of PCAF BRD/Tat-AcK50 Association

(2014) Ping Hu et al.   ChemMedChem

Chiral Phosphoric Acid-Catalyzed Asymmetric Aza-Friedel-Crafts Reaction of Indoles with CyclicN-Acylketimines: Enantioselective Synthesis of Trifluoromethyldihydroquinazolines

(2013) Ke-Feng Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Complex Bioactive Alkaloid-Type Polycycles through Efficient Catalytic Asymmetric Multicomponent Aza-Diels-Alder Reaction of Indoles with Oxetane as Directing Group

(2013) Zhilong Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic asymmetric multicomponent reactions of aromatic aldehydes and anilines with β-ketoesters: facile and atom-economical access to chiral tetrahydropyridines

(2013) Xuejian Li et al.   CHEMICAL COMMUNICATIONS

Simple Branched Sulfur–Olefins as Chiral Ligands for Rh-Catalyzed Asymmetric Arylation of Cyclic Ketimines: Highly Enantioselective Construction of Tetrasubstituted Carbon Stereocenters

(2013) Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Brønsted acid-catalyzed enantioselective addition of indoles to ketimines

(2013) Taichi Kano et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A combination of directing groups and chiral anion phase-transfer catalysis for enantioselective fluorination of alkenes

(2013) Jeffrey Wu et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Highly Enantioselective Synthesis of Dihydroquinazolinones Catalyzed by SPINOL-Phosphoric Acids

(2013) Dan Huang et al.   ACS Catalysis

Highly Enantioselective Pictet-Spengler Reaction Catalyzed by SPINOL-Phosphoric Acids

(2012) Dan Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Asymmetric Synthesis of 1,2,4-Trioxane Anticancer Agents via Desymmetrization of Peroxyquinols through a Brønsted Acid Catalysis Cascade

(2012) David M. Rubush et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly enantioselective Biginelli reaction catalyzed by SPINOL-phosphoric acids

(2012) Fangxi Xu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric NH Insertion Reaction Cooperatively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids

(2011) Bin Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo- and enantioselective conjugate addition of α-substituted nitroacetates to maleimides under base-free neutral phase-transfer conditions

(2011) Seiji Shirakawa et al.   CHEMICAL COMMUNICATIONS

Chiral Brønsted acids in enantioselective carbonyl activations – activation modes and applications

(2011) Magnus Rueping et al.   CHEMICAL SOCIETY REVIEWS

Binding of α,α-Disubstituted Amino Acids to Arginase Suggests New Avenues for Inhibitor Design

(2011) Monica Ilies et al.   JOURNAL OF MEDICINAL CHEMISTRY

Design, Synthesis, and X-ray Crystallographic Analysis of a Novel Class of HIV-1 Protease Inhibitors

(2011) Ashit K. Ganguly et al.   JOURNAL OF MEDICINAL CHEMISTRY

Asymmetric Synthesis of α-Methyl-α-Amino Acids via Diastereoselective Alkylation of (1S)-(+)-3-Carene Derived Tricyclic Iminolactone

(2011) Ta-Jung Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Optically Active 1,1′-Spirobiindane-7,7′-diol (SPINOL)-Based Phosphoric Acids as Highly Enantioselective Catalysts for Asymmetric Organocatalysis

(2011) Chun-Hui Xing et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthetic studies toward labionin, a new α,α-disubstituted amino acid from type III lantibiotic labyrinthopeptin A2

(2011) Georg M. Sambeth et al.   JOURNAL OF PEPTIDE SCIENCE

Enantioselective Organocatalytic Synthesis of Quaternary α-Amino Acids Bearing a CF3Moiety

(2011) Ralph Husmann et al.   ORGANIC LETTERS

Nickel-Catalyzed Regio- and Enantioselective Annulation Reactions of 1,2,3,4-Benzothiatriazine-1,1(2H)-dioxides with Allenes

(2010) Tomoya Miura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and synthesis of cyclic sulfonamides and sulfamates as new calcium sensing receptor agonists

(2010) Lionel Kiefer et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

(2010) Anna J. Kochanowska-Karamyan et al.   CHEMICAL REVIEWS

SPINOL-Derived Phosphoric Acids: Synthesis and Application in Enantioselective Friedel−Crafts Reaction of Indoles with Imines

(2010) Fangxi Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Kinetic Resolution of Homoaldols via Catalytic Asymmetric Transacetalization

(2010) Ilija Čorić et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

(2010) Masahiro Terada   SYNTHESIS-STUTTGART

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acid catalyzed Friedel–Crafts alkylation reactions

(2009) Shu-Li You et al.   CHEMICAL SOCIETY REVIEWS

Organocatalysis—after the gold rush

(2009) Søren Bertelsen et al.   CHEMICAL SOCIETY REVIEWS

Memory of Chirality of Tertiary Aromatic Amides: A Simple and Efficient Method for the Enantioselective Synthesis of Quaternary α-Amino Acids

(2009) Mathieu Branca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Organocatalysis: From Infancy to Adolescence

(2008) Alessandro Dondoni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions

(2008) Masahiro Terada   CHEMICAL COMMUNICATIONS

Catalytic Asymmetric Friedel−Crafts Alkylation ReactionsCopper Showed the Way

(2008) Thomas B. Poulsen et al.   CHEMICAL REVIEWS

The advent and development of organocatalysis

(2008) David W. C. MacMillan   NATURE

Enantioselective Synthesis and Enantiomeric Amplification of Amino Acids under Prebiotic Conditions

(2008) Mindy Levine et al.   ORGANIC LETTERS

Synthetic Studies on Altemicidin:  Stereocontrolled Construction of the Core Framework

(2007) Toshiyuki Kan et al.   ORGANIC LETTERS