Reactions of heavier main-group compounds with hydrogen, ammonia, ethylene and related small molecules

Access to a Stable Si2N2Four-Membered Ring with Non-Kekulé Singlet Biradical Character from a Disilyne

(2011) Katsuhiko Takeuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleavage of the SnSn Multiple Bond in a Distannyne by Cyclooctatetraene: Formation of the π-Bound Inverse Sandwich Complex [(Ar′Sn)2(μ2-η2:η3-cot)]

(2010) Owen T. Summerscales et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Characterization of Two of the Three Isomers of a Germanium-Substituted Bicyclo[2.2.0]hexane Diradicaloid: Stretching the GeGe Bond

(2010) Xinping Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible complexation of isocyanides by the distannyne Ar′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2)

(2010) Yang Peng et al.   CHEMICAL COMMUNICATIONS

Activation of dihydrogen by non-metal systems

(2010) Douglas W. Stephan   CHEMICAL COMMUNICATIONS

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

Nature of Bonding in Group 13 Dimetallenes: a Delicate Balance between Singlet Diradical Character and Closed Shell Interactions

(2010) Jani Moilanen et al.   INORGANIC CHEMISTRY

Unsymmetrically Substituted Disilyne Dsi2iPrSi—Si≡Si—SiNpDsi2(Np = CH2tBu): Synthesis and Characterization

(2010) Yoshitaka Murata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unusual Electrocyclic Rearrangements with Group 14 Element Compounds: Reversible Isomerization of a π-Aromatic Digermyl Complex with Carbon−Carbon and Germanium−Germanium Multiple Bond Cleavage

(2010) Owen T. Summerscales et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Reaction of M(II) Diaryls (M = Mn or Fe) with Ammonia to Afford Parent Amido Complexes

(2010) Chengbao Ni et al.   ORGANOMETALLICS

Substituent effects in ditetrel alkyne analogues: multiple vs. single bonded isomers

(2010) Yang Peng et al.   Chemical Science

Synthesis and Characterization of [Ar′GaC(Ph)CH]2and K2[Ar′GaC(Ph)CH]2⋅OEt2: From Digallene to Digallacyclohexadiene to Digallatabenzene

(2009) Zhongliang Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Remarkable Base-Stabilized Bis(silylene) with a Silicon(I)-Silicon(I) Bond

(2009) Sakya S. Sen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of Hydrogen or Ammonia to a Low-Valent Group 13 Metal Species at 25 °C and 1 Atmosphere

(2009) Zhongliang Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

Synthesis, Characterization and Real Molecule DFT Calculations for Neutral Organogallium(I) Aryl Dimers and Monomers: Weakness of GalliumGallium Bonds in Digallenes and Digallynes

(2009) Zhongliang Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

N−H and N=C Bond Formation via Germanium(III) Diradicaloid Intermediates and C−S Bond Cleavage in Reactions of the Digermyne Ar′GeGeAr′ (Ar′ = C6H3-2,6-(C6H3-2,6-Pri2)2) with Azides

(2009) Xinping Wang et al.   INORGANIC CHEMISTRY

An Unsymmetric Oxo/Imido-Bridged Germanium-Centered Singlet Diradicaloid

(2009) Xinping Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature Reaction of Carbon Monoxide with a Stable Diarylgermylene

(2009) Xinping Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chalcogenide/Chalcogenolate Structural Isomers of Organo Group 13 Element Derivatives: Reactions of the Dimetallenes Ar′MMAr′ (Ar′ = C6H3-2,6-(C6H3-2,6-Pri2)2; M = Ga or In) with N2O or S8To Give (Ar′MIIIE)2(E = O or S) and the Synthesis and Characterization of [Ar′EMI]2(M = In or Tl; E = O, S)

(2009) Zhongliang Zhu et al.   ORGANOMETALLICS

Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions

(2009) Y. Peng et al.   SCIENCE

[{2,6-(Me2NCH2)2C6H3}Sn]2: An Intramolecularly Coordinated Diorganodistannyne

(2008) Roman Jambor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of H2 to distannynes under ambient conditions

(2008) Yang Peng et al.   CHEMICAL COMMUNICATIONS

Reactivity of the Disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) toward Silylcyanide: Two Pathways To Form the Bis-Adduct [RSiSiR(CNSiMe3)2] with Some Silaketenimine Character and a 1,4-Diaza-2,3-disilabenzene Analogue

(2008) Katsuhiko Takeuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

(2008) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY