Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene

(2013) Adrian Y. Houghton et al.   CHEMICAL COMMUNICATIONS

Quantum Chemical Study of B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Group

(2013) Ken Sakata et al.   JOURNAL OF ORGANIC CHEMISTRY

The “Catalytic Nitrosyl Effect”: NO Bending Boosting the Efficiency of Rhenium Based Alkene Hydrogenations

(2013) Yanfeng Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism

(2013) Julia Hermeke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity Models of Hydrogen Activation by Frustrated Lewis Pairs: Synergistic Electron Transfers or Polarization by Electric Field?

(2013) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes

(2013) Konstantin Chernichenko et al.   Nature Chemistry

Si–H Bond Activation at the Boron Center of Pentaphenylborole

(2013) Holger Braunschweig et al.   ORGANOMETALLICS

Silylium Ion Promoted Reduction of Imines with Hydrosilanes

(2013) Kristine Müther et al.   ORGANOMETALLICS

Abundant Metals Give Precious Hydrogenation Performance

(2013) R. M. Bullock   SCIENCE

Enantioselective Hydrosilylation with Chiral Frustrated Lewis Pairs

(2012) Dianjun Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbon Monoxide Activation via O-Bound CO Using Decamethylscandocinium–Hydridoborate Ion Pairs

(2012) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Activation of H–H and Si–H Bonds by Boranes

(2012) Georgii I. Nikonov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies on the Metal-Free Activation of Dihydrogen by Antiaromatic Pentarylboroles

(2012) Adrian Y. Houghton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of pentaarylboroles with carbon monoxide: an isolable organoboron carbonyl complex

(2012) Aiko Fukazawa et al.   Chemical Science

Mechanistic Aspects of Bond Activation with Perfluoroarylboranes

(2011) Warren E. Piers et al.   INORGANIC CHEMISTRY

Dihydrogen Activation withtBu3P/B(C6F5)3: A Chemically Competent Indirect Mechanism via in Situ-Generatedp-tBu2P–C6F4–B(C6F5)2

(2011) Adam J. V. Marwitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triethylsilyl Perfluoro-Tetraphenylborate, [Et3Si+][F20-BPh4–], a Widely Used Nonexistent Compound

(2011) Matthew Nava et al.   ORGANOMETALLICS

The Mechanism of Dihydrogen Activation by Frustrated Lewis Pairs Revisited

(2010) Stefan Grimme et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dihydrogen Activation by Antiaromatic Pentaarylboroles

(2010) Cheng Fan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Perfluoropentaphenylborole

(2009) Cheng Fan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B(C6F5)3-Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding

(2009) Daniel T. Hog et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation

(2008) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2

(2008) Preston A. Chase et al.   CHEMICAL COMMUNICATIONS

Solid-State Structures and Solution Analyses of a PhenylpropylpyridineN-Oxide and anN-Methyl Phenylpropylpyridine

(2008) Isabella Richter et al.   Chemistry-An Asian Journal

“Frustrated Lewis pairs”: a concept for new reactivity and catalysis

(2008) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY