Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies

Zinc-Catalyzed Borylation of Primary, Secondary and Tertiary Alkyl Halides with Alkoxy Diboron Reagents at Room Temperature

(2014) Shubhankar Kumar Bose et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Synthesis of Aryl Boronates via Zinc-Catalyzed Cross-Coupling of Alkoxy Diboron Reagents with Aryl Halides at Room Temperature

(2014) Shubhankar Kumar Bose et al.   ORGANIC LETTERS

Alkoxide Activation of Aminoboranes towards Selective Amination

(2013) Cristina Solé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atrans-Selective Hydroboration of Internal Alkynes

(2013) Basker Sundararaju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Reactivity of Silylboranes toward Lewis Bases: Heterolytic B-Si Cleavage vs. Adduct Formation

(2013) Christian Kleeberg et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Design, Generation, and Synthetic Application of Borylzincate: Borylation of Aryl Halides and Borylzincation of Benzynes/Terminal Alkyne

(2013) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base Metal Catalysts for Photochemical C–H Borylation That Utilize Metal–Metal Cooperativity

(2013) Thomas J. Mazzacano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A decade advancement of transition metal-catalyzed borylation of aryl halides and sulfonates

(2013) Wing Kin Chow et al.   RSC Advances

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

(2012) Kazuyuki Oshima et al.   CHEMICAL COMMUNICATIONS

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

(2012) Hajime Ito et al.   CHEMICAL COMMUNICATIONS

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed Borylation of Organic Halides with Hydroboranes

(2012) Miki Murata   HETEROCYCLES

Use of Small-Molecule Crystal Structures To Address Solubility in a Novel Series of G Protein Coupled Receptor 119 Agonists: Optimization of a Lead and in Vivo Evaluation

(2012) James S. Scott et al.   JOURNAL OF MEDICINAL CHEMISTRY

Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems

(2012) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Ortho C–H Borylation of 2-Phenoxypyridines under Mild Conditions

(2012) Liting Niu et al.   ORGANIC LETTERS

Transition-Metal-Free Borylation of Aryltriazene Mediated by BF3·OEt2

(2012) Chuan Zhu et al.   ORGANIC LETTERS

Cross-Coupling of Aryl Grignard Reagents with Aryl Iodides and Bromides through SRN1 Pathway

(2011) Eiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with a Silica-Supported Compact Phosphane Ligand

(2011) Soichiro Kawamorita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Diboration Reaction by Activation of Diboron Compounds with Simple Lewis Bases

(2011) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pinacol Boronates by Direct Arene Borylation with Borenium Cations

(2011) Alessandro Del Grosso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Mechanistic Insights into the Reaction of Enantiomerically Pure Lithiosilanes and Electrophiles: Understanding the Differences between Aryl and Alkyl Halides

(2011) Christian Däschlein et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Structure Based Drug Design of Crizotinib (PF-02341066), a Potent and Selective Dual Inhibitor of Mesenchymal–Epithelial Transition Factor (c-MET) Kinase and Anaplastic Lymphoma Kinase (ALK)

(2011) J. Jean Cui et al.   JOURNAL OF MEDICINAL CHEMISTRY

Hydride as a Leaving Group in the Reaction of Pinacolborane with Halides under Ambient Grignard and Barbier Conditions. One-Pot Synthesis of Alkyl, Aryl, Heteroaryl, Vinyl, and Allyl Pinacolboronic Esters

(2011) Jacob W. Clary et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Catalytic C–Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2011) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Monophosphorus Ligands for Palladium-Catalyzed Miyaura Borylation

(2011) Wenjun Tang et al.   ORGANIC LETTERS

Mechanisms of Reactions of a Lithium Boryl with Organohalides

(2011) Man Sing Cheung et al.   ORGANOMETALLICS

Direct Conversion of Arylamines to Pinacol Boronates: A Metal-Free Borylation Process

(2010) Fanyang Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Opportunity for Mg-Catalyzed Grignard-Type Reactions: Direct Coupling of Benzylic Halides with Pinacolborane with 10 mol % of Magnesium

(2010) Christine Pintaric et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

α-Hydroxyalkyl Heterocycles via Chiral Allylic Boronates: Pd-Catalyzed Borylation Leading to a Formal Enantioselective Isomerization of Allylic Ether and Amine

(2009) Stéphanie Lessard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chelate Restrained Boron Cations for Intermolecular Electrophilic Arene Borylation

(2009) Alessandro Del Grosso et al.   ORGANOMETALLICS

Synthesis of Activated Alkenylboronates from Acetylenic Esters by CuH-Catalyzed 1,2-Addition/Transmetalation

(2008) Bruce H. Lipshutz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

An Improved System for the Palladium-Catalyzed Borylation of Aryl Halides with Pinacol Borane

(2008) Kelvin L. Billingsley et al.   JOURNAL OF ORGANIC CHEMISTRY

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

(2008) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequential Ni-Catalyzed Borylation and Cross-Coupling of Aryl Halides via in Situ Prepared Neopentylglycolborane

(2008) Brad M. Rosen et al.   ORGANIC LETTERS