Direct access to 2-(hetero)arylated pyridines from 6-substituted 2-bromopyridines via phosphine-free palladium-catalyzed C–H bond arylations: the importance of the C6 substituent

One-Pot Synthesis of Symmetrical 2,6-DiarylpyridinesviaPalladium/Copper-Catalyzed Sequential Decarboxylative and Direct CH Arylation

(2015) Zhiyong Ma et al.   ADVANCED SYNTHESIS & CATALYSIS

Regioselective oxidative Pd-catalysed coupling of alkylboronic acids with pyridin-2-yl-substituted heterocycles

(2015) Julian Wippich et al.   CHEMICAL COMMUNICATIONS

Dimethyl carbonate and switchable anionic surfactants: two effective tools for the extraction of polyhydroxyalkanoates from microbial biomass

(2015) Chiara Samorì et al.   GREEN CHEMISTRY

N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex Catalyzed Direct C–H Bond Arylation of Benzo[b]furans with Aryl Chlorides

(2015) Shun-Chao Yin et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile synthesis of aryl-substituted pyridines via Suzuki–Miyaura approach

(2015) Eda Karadeniz et al.   TETRAHEDRON

Functionalization of C–H Bonds via Metal-Catalyzed Desulfitative Coupling: An Alternative Tool for Access to Aryl- or Alkyl-Substituted (Hetero)arenes

(2015) Kedong Yuan et al.   ACS Catalysis

Reusable and Removable Directing Groups for C(sp2)−H Bond Functionalization of Arenes

(2015) M. Ramu Yadav et al.   Asian Journal of Organic Chemistry

Reactivity of 3-Substituted Fluorobenzenes in Palladium- Catalysed Direct Arylations with Aryl Bromides

(2014) Tao Yan et al.   ADVANCED SYNTHESIS & CATALYSIS

Cross-Coupling of Heteroarenes by CH Functionalization: Recent Progress towards Direct Arylation and Heteroarylation Reactions Involving Heteroarenes Containing One Heteroatom

(2014) Renzo Rossi et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of (Poly)fluorobiphenyls through Metal-catalyzed CH Bond Activation/Arylation of (Poly)fluorobenzene Derivatives

(2014) Mian He et al.   ChemCatChem

Malononitrile as a Key Reagent in Multicomponent Reactions for the Synthesis of Pharmaceutically Important Pyridines

(2014) Anshu Dandia et al.   CURRENT ORGANIC CHEMISTRY

Second-Order NLO Switches from Molecules to Polymer Films Based on Photochromic Cyclometalated Platinum(II) Complexes

(2014) Julien Boixel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalysed Regioselective Sequential C-5 and C-2 Direct Arylations of 3-Acetylpyrroles with Aryl Bromides

(2013) Yijing Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Luminescent biscyclometalated arylpyridine iridium(iii) complexes with 4,4′-bi-1,2,3-triazolyl ancillary ligands

(2013) Christine E. Welby et al.   DALTON TRANSACTIONS

Iron-Catalyzed Direct C-H Arylation of Heterocycles and Quinones with Arylboronic Acids

(2013) Arghya Deb et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iridium(III) Emitters Based on 1,4-Disubstituted-1H-1,2,3-triazoles as Cyclometalating Ligand: Synthesis, Characterization, and Electroluminescent Devices

(2013) Jesús M. Fernández-Hernández et al.   INORGANIC CHEMISTRY

Synthesis of trisubstituted thiazoles by ligand-free palladium-catalyzed direct 5-arylation of 2,4-disubstituted thiazoles under conventional and microwave-assisted heating

(2013) Su Kang Kim et al.   TETRAHEDRON

Direct heteroarylation of 5-bromothiophen-2-ylpyridine and of 8-bromoquinoline via palladium-catalysed C–H bond activation: simpler access to heteroarylated nitrogen-based derivatives

(2013) Jenny Laroche et al.   Catalysis Science & Technology

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalysed Direct Polyarylation of Pyrrole Derivatives

(2012) Liqin Zhao et al.   ChemCatChem

A general and efficient aldehyde decarbonylation reaction by using a palladium catalyst

(2012) Atanu Modak et al.   CHEMICAL COMMUNICATIONS

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Arylation of a CH Bond in Pyridine and Related Six-Membered N-Heteroarenes Using Organozinc Reagents

(2012) Isao Hyodo et al.   Chemistry-An Asian Journal

Mechanistic Studies on Direct Arylation of Pyridine N-Oxide: Evidence for Cooperative Catalysis between Two Distinct Palladium Centers

(2012) Yichen Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalysed direct arylation of heteroaromatics with functionalised bromopyridines

(2012) Souhila Bensaid et al.   TETRAHEDRON

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Recent advances in new multicomponent synthesis of structurally diversified 1,4-dihydropyridines

(2012) Jie-Ping Wan et al.   RSC Advances

Glycerol and derived solvents: new sustainable reaction media for organic synthesis

(2011) Alba E. Díaz-Álvarez et al.   CHEMICAL COMMUNICATIONS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Cyclopentyl Methyl Ether: An Alternative Solvent for Palladium-Catalyzed Direct Arylation of Heteroaromatics

(2011) Kassem Beydoun et al.   ChemSusChem

Palladium-Catalyzed Direct Arylations of Five-Membered Heteroarenes Bearing N-Monoalkylcarboxamide Substituents

(2011) Nouria Laidaoui et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Greener solvents for ruthenium and palladium-catalysed aromatic C–H bond functionalisation

(2011) Cedric Fischmeister et al.   GREEN CHEMISTRY

4-Aminothiazolyl Analogues of GE2270 A: Antibacterial Lead Finding

(2011) Matthew J. LaMarche et al.   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Direct Arylation of Heteroaromatic Compounds: Improved Conditions Utilizing Controlled Microwave Heating

(2011) Mostafa Baghbanzadeh et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-catalysed direct arylations of heteroaromatics using more eco-compatible solvents pentan-1-ol or 3-methylbutan-1-ol

(2011) Souhila Bensaid et al.   TETRAHEDRON LETTERS

Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation

(2010) Chang-Liang Sun et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Recent Strategies for the Synthesis of Pyridine Derivatives

(2010) Matthew D. Hill   CHEMISTRY-A EUROPEAN JOURNAL

A robust hydrophilic pyridine-bridged bis-benzimidazolylidene palladium pincer complex: Synthesis and its catalytic application towards Suzuki–Miyaura couplings in aqueous solvents

(2010) Tao Tu et al.   DALTON TRANSACTIONS

Transition-Metal-Catalyzed Regioselective Arylation and Vinylation of Carboxylic Acids

(2010) Tetsuya Satoh et al.   SYNTHESIS-STUTTGART

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation

(2009) Julien Roger et al.   ChemCatChem

Metathesis in the Synthesis of Aromatic Compounds†

(2009) Willem A. L. van Otterlo et al.   CHEMICAL REVIEWS

Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides

(2009) Fabio Bellina et al.   CHEMICAL REVIEWS

Improved Palladium-Catalyzed Sonogashira Coupling Reactions of Aryl Chlorides

(2009) Christian Torborg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Free Palladium-Catalyzed Direct Arylation of Thiazoles at Low Catalyst Loadings

(2009) Julien Roger et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

(2009) Fabio Bellina et al.   TETRAHEDRON

Development and Application of Effective Protocols for the Synthesis of Arylheteroarenes and Biheteroaryls, Including Bioactive Derivatives, by Highly Regioselective Transition Metal-Catalyzed Direct Intermolecular Arylation Reactions of Five-Membered Heteroarenes with (Hetero)aryl Halides

(2008) Fabio Bellina et al.   CURRENT ORGANIC CHEMISTRY

Palladium-Catalysed Direct C-H Activation/Arylation of Heteroaromatics: An Environmentally Attractive Access to Bi- or Polydentate Ligands

(2008) Fazia Derridj et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Tetomilast suppressed production of proinflammatory cytokines from human monocytes and ameliorated chronic colitis in IL-10-deficient mice

(2008) Hitoshi Ichikawa et al.   INFLAMMATORY BOWEL DISEASES

Palladium-catalyzed direct heteroarylation of chloropyridines and chloroquinolines

(2008) Fazia Derridj et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Palladium-Catalyzed Benzylic C−H Insertion of 2-SubstitutedN-Iminopyridinium Ylides

(2008) James J. Mousseau et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART

Palladium-Catalyzed Direct C−H Arylation ofN-Iminopyridinium Ylides:  Application to the Synthesis of (±)-Anabasine

(2007) Alexandre Larivée et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY