From Dibismuthenes to Three- and Two-Coordinated Bismuthinidenes by Fine Ligand Tuning: Evidence for Aromatic BiC3N Rings through a Combined Experimental and Theoretical Study

Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene

(2015) Deepak Dange et al.   CHEMICAL COMMUNICATIONS

Quantifying aromaticity with electron delocalisation measures

(2015) Ferran Feixas et al.   CHEMICAL SOCIETY REVIEWS

Cyclo-Pnicta-triazanes: Biradicaloids or Zwitterions?

(2015) Alexander Hinz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of N,C,N-Chelated Antimony(III) and Bismuth(III) Chlorides with Lithium Reagents: Addition vs Substitution

(2015) Iva Vránová et al.   ORGANOMETALLICS

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

One-, Two-, and Three-Electron Reduction of a Cyclic Alkyl(amino)carbene-SbCl3Adduct

(2014) Robert Kretschmer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Syntheses and Structures of Terminal Arylalumylene Complexes

(2014) Koichi Nagata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Temperature-Dependent Electron Shuffle in Molecular Group 13/15 Intermetallic Complexes

(2014) Chelladurai Ganesamoorthy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Persistent Antimony- and Bismuth-Centered Radicals in Solution

(2014) Shintaro Ishida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Coordination Compound of Ge0Stabilized by a Diiminopyridine Ligand

(2014) Terry Chu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the mechanism of the reaction of a magnesium(i) complex with CO2: a concerted type of pathway

(2014) Christos E. Kefalidis et al.   CHEMICAL COMMUNICATIONS

New bonding modes of carbon and heavier group 14 atoms Si–Pb

(2014) Gernot Frenking et al.   CHEMICAL SOCIETY REVIEWS

Bromination of a Stable 1,2-Bis(ferrocenyl)dibismuthene: Synthesis of a 1,2-Dibromodibismuthane Derivative

(2014) Takahiro Sasamori et al.   HETEROATOM CHEMISTRY

Reactivity Profile of a Peri-Substitution-Stabilized Phosphanylidene-Phosphorane: Synthetic, Structural, and Computational Studies

(2014) Brian A. Surgenor et al.   INORGANIC CHEMISTRY

N-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field

(2014) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Stibasilene Sb═Si and Its Lighter Homologues: A Comparative Study

(2014) Vladimir Ya. Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds

(2014) Terrance J. Hadlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Electron-Rich Pincer-Type Iron Complexes Bearing Innocent Bis(metallylene)pyridine Ligands: Syntheses, Structures, and Catalytic Activity

(2014) Daniel Gallego et al.   ORGANOMETALLICS

A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal borylene complexes

(2013) Holger Braunschweig et al.   CHEMICAL SOCIETY REVIEWS

Synthesis and Onwards Coordination of an AsICentered Zwitterion

(2013) Jonathan W. Dube et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Role of 2,6-Diaminopyridine Ligands in the Isolation of an Unprecedented, Low-Valent Tin Complex

(2013) Johanna Flock et al.   CHEMISTRY-A EUROPEAN JOURNAL

Insights into the Intramolecular Donor Stabilisation of Organostannylene Palladium and Platinum Complexes: Syntheses, Structures and DFT Calculations

(2013) Michael Wagner et al.   CHEMISTRY-A EUROPEAN JOURNAL

1,2-Bis(ferrocenyl)-Substituted Distibene and Dibismuthene: SbSb and BiBi Units as π Spacers between Two Ferrocenyl Units

(2013) Michiyasu Sakagami et al.   Chemistry-An Asian Journal

Synthesis of Zwitterionic Triphosphenium Transition Metal Complexes: A Boron Atom Makes The Difference

(2013) Jonathan W. Dube et al.   INORGANIC CHEMISTRY

Coordination Chemistry of Disilylated Stannylenes with Group 10 d10 Transition Metals: Silastannene vs Stannylene Complexation

(2013) Henning Arp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

(2013) Daniel Gallego et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Addition of Diphenyldichalcogenides PhEEPh (E = S, Se, Te) to Low-Valent CN- and NCN-Chelated Organoantimony and Organobismuth Compounds

(2013) Petr Šimon et al.   ORGANOMETALLICS

Dichlorosilylene: A High Temperature Transient Species to an Indispensable Building Block

(2012) Rajendra S. Ghadwal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Accessing the Coordination Chemistry of Phosphorus(I) Zwitterions

(2012) Jonathan W. Dube et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolable Phosphanylidene Phosphorane with a Sterically Accessible Two-Coordinate Phosphorus Atom

(2012) Brian A. Surgenor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of a Singlet Silylene to a stable Biradical

(2012) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclopentadiene Based Low-Valent Group 13 Metal Compounds: Ligands in Coordination Chemistry and Link between Metal Rich Molecules and Intermetallic Materials

(2012) Sandra González-Gallardo et al.   CHEMICAL REVIEWS

[Ru2Bi14Br4](AlCl4)4by Mobilization and Reorganization of Complex Clusters in Ionic Liquids

(2012) Matthias F. Groh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hypervalent organoantimony and -bismuth compounds with pendant arm ligands

(2012) Ciprian I. Raţ et al.   COORDINATION CHEMISTRY REVIEWS

Natural bond orbital analysis: A critical overview of relationships to alternative bonding perspectives

(2012) Frank Weinhold   JOURNAL OF COMPUTATIONAL CHEMISTRY

On the Covalent Character of Rare Gas Bonding Interactions: A New Kind of Weak Interaction

(2012) Wenli Zou et al.   JOURNAL OF PHYSICAL CHEMISTRY A

The Role of Group 14 Element Hydrides in the Activation of C–H Bonds in Cyclic Olefins

(2012) Owen T. Summerscales et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible and Irreversible Higher-Order Cycloaddition Reactions of Polyolefins with a Multiple-Bonded Heavier Group 13 Alkene Analogue: Contrasting the Behavior of Systems with π–π, π–π*, and π–n+ Frontier Molecular Orbital Symmetry

(2012) Christine A. Caputo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Group 14 Hydrides with Low Valent Elements for Activation of Small Molecules

(2011) Swadhin K. Mandal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

(2011) Philip P. Power   ACCOUNTS OF CHEMICAL RESEARCH

Reactions of heavier main-group compounds with hydrogen, ammonia, ethylene and related small molecules

(2011) Philip P. Power   CHEMICAL RECORD

Stable dimeric magnesium(i) compounds: from chemical landmarks to versatile reagents

(2011) Andreas Stasch et al.   DALTON TRANSACTIONS

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Structural Characterization of Et4Sb2and Et4Bi2

(2011) Andreas Kuczkowski et al.   ORGANOMETALLICS

Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures

(2010) Petr Šimon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

A Ditetrylyne as a π-Electron Donor: Synthesis and Characterization of [AgAr′GeGeAr′]+SbF6−and [Ag2Ar′GeGe(F)Ar′]+SbF6−(Ar′ = C6H3-2,6(C6H3-2,6-Pri2)2)

(2010) Xinping Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

[2-{E(CH2CH2)2NCH2}C6H4]nBiX3-n (E = O, NMe; X = Cl, Br, I; n = 1-3) and [2-(Me2NCH2)C6H4]BiBr2 - New Hypervalent Organobismuth(III) Compounds

(2010) Hans J. Breunig et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Substituent effects in ditetrel alkyne analogues: multiple vs. single bonded isomers

(2010) Yang Peng et al.   Chemical Science

Molecular Double-Bond Covalent Radii for Elements Li–E112

(2009) Pekka Pyykkö et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhenium−Bismuth Carbonyl Cluster Compounds

(2009) Richard D. Adams et al.   INORGANIC CHEMISTRY

A Density Functional Theory Study of the Topology of the Charge Density of Complexes of 8-Hydroxyquinoline with Mn(III), Fe(III), and Co(III)

(2009) Juan Murgich et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Consistent van der Waals Radii for the Whole Main Group

(2009) Manjeera Mantina et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Molecular Single-Bond Covalent Radii for Elements 1-118

(2008) Pekka Pyykkö et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactions of Terphenylbismuth Dihalides with KSi(SiMe3)3, K2Si2(SiMe3)4 and Na2[Fe(CO)]4: Reduction vs. Metathesis

(2008) Robert Wolf et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Mono- and Bidentate Benzannulated N-Heterocyclic Germylenes, Stannylenes and Plumbylenes

(2008) Alexander V. Zabula et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Syntheses and Structures of Ar3Sb5and Ar4Sb4Compounds (Ar = C6H3-2,6-(CH2NMe2)2)

(2008) Libor Dostál et al.   ORGANOMETALLICS

Doubly bonded systems between heavier Group 15 elements

(2007) Takahiro Sasamori et al.   DALTON TRANSACTIONS