Bond Activation with an Apparently Benign Ethynyl Dithiocarbamate ArCCSC(S)NR2

A Stable Acyclic Ligand Equivalent of an Unstable 1,3-Dithiol-5-ylidene

(2011) Gaël Ung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair

(2010) Blanca Inés et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Activation of EH3 (E=P, As) by an Ylide-like Silylene and Formation of a Donor-Stabilized Arsasilene with a HSiAsH Subunit

(2010) Carsten Präsang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)

(2010) Gregorio Guisado-Barrios et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ammonia N–H activation by a N,N′-diamidocarbene

(2010) Todd W. Hudnall et al.   CHEMICAL COMMUNICATIONS

Activation of dihydrogen by non-metal systems

(2010) Douglas W. Stephan   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes

(2010) Manuel Iglesias et al.   DALTON TRANSACTIONS

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene (NHC)-Stabilized Silanechalcogenones: NHC→Si(R2)E (E=O, S, Se, Te)

(2009) Shenglai Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Abnormal Carbenes as Ligands in Transition Metal Chemistry: Curiosities with Exciting Perspectives

(2009) Martin Albrecht   CHIMIA

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

(2009) Douglas W. Stephan   DALTON TRANSACTIONS

Betaine Adducts of N-Heterocyclic Carbenes: Synthesis, Properties, and Reactivity

(2009) Lionel Delaude   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Heterolytic Cleavage of Disulfides by Frustrated Lewis Pairs

(2009) Meghan A. Dureen et al.   INORGANIC CHEMISTRY

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insertion Reaction of a Silylene into a N−H Bond of Hydrazine and a [1+4] Cycloaddition with Diphenyl Hydrazone§

(2009) Anukul Jana et al.   ORGANOMETALLICS

Isolation of a C5-Deprotonated Imidazolium, a Crystalline "Abnormal" N-Heterocyclic Carbene

(2009) E. Aldeco-Perez et al.   SCIENCE

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C4-bound imidazolylidenes: from curiosities to high-impact carbene ligands

(2008) Martin Albrecht   CHEMICAL COMMUNICATIONS