Palladium-Catalyzed Construction of Spirooxindoles by Arylative Cyclization of 3-(γ,δ-Disubstituted)allylidene-2-Oxindoles

Catalytic Enantioselective 1,3-Dipolar Cycloadditions of Azomethine Ylides for Biology-Oriented Synthesis

(2014) Rishikesh Narayan et al.   ACCOUNTS OF CHEMICAL RESEARCH

2,3-Dichloro-5,6-dicyano-para-benzoquinone (DDQ)/Methanesulfonic Acid (MsOH)-Mediated Intramolecular Arene-Alkene Oxidative Coupling

(2014) Ko Hoon Kim et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed C(sp3)H Activation: A Facile Method for the Synthesis of 3,4-Dihydroquinolinone Derivatives

(2014) Jia-Xuan Yan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Construction of Spirocyclopentaneoxindoles Containing Four Consecutive Stereocenters through an Organocatalytic Iminium-Enamine Cascade Reaction

(2014) Liang-Zhong Ding et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Total synthesis and isolation of citrinalin and cyclopiamine congeners

(2014) Eduardo V. Mercado-Marin et al.   NATURE

Synthesis of Heterasumanene

(2014) Xiangfeng Shao et al.   SYNLETT

An expedient synthesis of 3-alkylideneoxindoles by Ti(OiPr)4/pyridine-mediated Knoevenagel condensation

(2014) Hyun Ju Lee et al.   TETRAHEDRON LETTERS

Organocatalytic Asymmetric Assembly Reactions: Synthesis of Spirooxindoles via Organocascade Strategies

(2014) Daojuan Cheng et al.   ACS Catalysis

Asymmetric Vinylogous Michael Addition/Cyclization Cascade Reaction for the Construction of Diversely Structured Spiro- Oxindole Skeletons

(2013) Xiao-Mei Shi et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Advances in Asymmetric Organocatalytic Construction of 3,3′-Spirocyclic Oxindoles

(2013) Liang Hong et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Through-Space C(sp3)H and C(sp2)H Bond Activation by 1,4-Palladium Migration: Efficient Synthesis of [3,4]-Fused Oxindoles

(2013) Tiffany Piou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Spirooxindoles from Carbamoyl Chlorides via Cyclopropyl Methine C(sp3)–H Activation Using Palladium Catalyst

(2013) Chihiro Tsukano et al.   CHEMISTRY LETTERS

Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides: Reaction Development and Mechanistic Studies

(2013) Dmitry Katayev et al.   CHEMISTRY-A EUROPEAN JOURNAL

Towards Ideal Synthesis: Alkenylation of Aryl CH Bonds by a Fujiwara-Moritani Reaction

(2013) Lihong Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective Preparation of Functionalized Dienes from Allylic Phosphonium Salts through the Wittig Reaction

(2013) Marcus M. Sá et al.   HETEROATOM CHEMISTRY

Rapid Access to Spirocyclic Oxindole Alkaloids: Application of the Asymmetric Palladium-Catalyzed [3 + 2] Trimethylenemethane Cycloaddition

(2013) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Promoted, Palladium-Catalyzed Direct Arylation of Cyclopropanes: Facile Access to Spiro 3,3′-Cyclopropyl Oxindoles

(2013) Carolyn L. Ladd et al.   ORGANIC LETTERS

Cyclodextrin host as a supramolecular catalyst in nonpolar solvents: stereoselective synthesis of (E)-3-alkylideneoxindoles

(2013) Haruyasu Asahara et al.   TETRAHEDRON

Aminocatalytic asymmetric Diels–Alder reaction of phosphorus dienophiles and 2,4-dienals

(2013) Qing-Qing Zhou et al.   TETRAHEDRON

Three to seven C–C or C–heteroatom bonds from domino reactions involving a Heck process

(2013) Jacques Muzart   TETRAHEDRON

A facile and efficient synthesis of 3-spirocyclopentene-2-oxindoles via palladium mediated vinylcyclopropane–cyclopentene rearrangement of oxindole derived vinylcyclopropanes

(2013) Kandapalam Arun Prasath Lingam et al.   TETRAHEDRON LETTERS

An efficient synthesis of o-terphenyls from Morita–Baylis–Hillman adducts of cinnamaldehydes: a consecutive bromination, Wittig reaction, 6π-electrocyclization, and an aerobic oxidation process

(2013) Cheol Hee Lim et al.   TETRAHEDRON LETTERS

Stereoselective synthesis of benzofulvenes via a palladium-catalyzed cyclization of 1,3-dienes derived from Morita–Baylis–Hillman adducts

(2013) Cheol Hee Lim et al.   TETRAHEDRON LETTERS

Asymmetric Catalysis for the Synthesis of Spirocyclic Compounds

(2013) Annaliese K. Franz et al.   ACS Catalysis

Palladium-Catalyzed, Chelation-Assisted Stereo- and Regioselective Synthesis of Tetrasubstituted Olefins by Oxidative Heck Arylation

(2012) Hyun Seung Lee et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Direct CH Arylation of Enamides with Simple Arenes

(2012) Sreekumar Pankajakshan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)-Catalyzed Enantioselective CH Arylation of Cyclopropanes: Efficient Access to Functionalized Tetrahydroquinolines

(2012) Tanguy Saget et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of a C(sp3)H Bond by a Transient σ-Alkylpalladium(II) Complex: Synthesis of Spirooxindoles Through a Palladium-Catalyzed Domino Carbopalladation/C(sp3)C(sp3) Bond-Forming Process

(2012) Tiffany Piou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isatins As Privileged Molecules in Design and Synthesis of Spiro-Fused Cyclic Frameworks

(2012) Girija S. Singh et al.   CHEMICAL REVIEWS

“Organo-Metal” Synergistic Catalysis: The 1+1>2 Effect for the Construction of Spirocyclopentene Oxindoles

(2012) Wangsheng Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

η1-Allylpalladium complexes with a tridentate PNP ligand with different phosphino groups

(2012) Bruno Crociani et al.   DALTON TRANSACTIONS

Diastereo- and Enantioselective [3 + 2] Cycloaddition Reaction of Morita–Baylis–Hillman Carbonates of Isatins with N-Phenylmaleimide Catalyzed by Me-DuPhos

(2012) Yan Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Strategies for the enantioselective synthesis of spirooxindoles

(2012) Nicolas R. Ball-Jones et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Pericyclic Cascade Approach to Spirocyclic Oxindoles

(2012) Edward Richmond et al.   ORGANIC LETTERS

Asymmetric Synthesis of Chiral 9,10-Dihydrophenanthrenes Using Pd-Catalyzed Asymmetric Intramolecular Friedel–Crafts Allylic Alkylation of Phenols

(2012) Yuta Suzuki et al.   ORGANIC LETTERS

Pyridine Ligands as Promoters in PdII/0-Catalyzed C–H Olefination Reactions

(2012) Asako Kubota et al.   ORGANIC LETTERS

Spirocyclization by Palladium-Catalyzed Domino Heck–Direct C–H Arylation Reactions: Synthesis of Spirodihydroquinolin-2-ones

(2012) Tiffany Piou et al.   ORGANIC LETTERS

Palladium-catalyzed arylation of α,β-unsaturated Weinreb amides

(2012) Ko Hoon Kim et al.   TETRAHEDRON LETTERS

Palladium(II)-catalyzed oxidative homo-coupling of 1,3-dimethyluracil derivatives

(2012) Ko Hoon Kim et al.   TETRAHEDRON LETTERS

Palladium-catalyzed oxidative arylation of chromones via a double C–H activation: an expedient approach to flavones

(2012) Ko Hoon Kim et al.   TETRAHEDRON LETTERS

Palladium-catalyzed oxidative arylation of trisubstituted olefin: an efficient synthesis of 3-(disubstituted)alkylidene-oxindoles

(2012) Hyun Ju Lee et al.   TETRAHEDRON LETTERS

An expedient synthesis of 3-arylmethylbutenolides from α-methylene-γ-butyrolactones: a useful synthetic application of palladium-catalyzed chelation-controlled oxidative arylation protocol

(2012) Se Hee Kim et al.   TETRAHEDRON LETTERS

An efficient synthesis of poly-substituted benzene and tricyclo[3.2.1.02,7]oct-3-ene derivatives starting from Morita–Baylis–Hillman adducts

(2012) Cheol Hee Lim et al.   TETRAHEDRON LETTERS

Palladium-catalyzed arylation of methyl 2-(acetoxymethyl)acrylate: a convenient synthesis of rearranged Morita–Baylis–Hillman acetates

(2012) Ko Hoon Kim et al.   TETRAHEDRON LETTERS

Recent Advances in the Construction of Polycyclic Compounds by Palladium-Catalyzed Atom-Economical Cascade Reactions

(2012) Hiroaki Ohno   Asian Journal of Organic Chemistry

Recent Advances in Palladium-Catalyzed Cascade Cyclizations

(2011) Tjøstil Vlaar et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Enantioselective [3+2] Annulation of Morita-Baylis-Hillman Adducts Mediated by L-Threonine-Derived Phosphines: Synthesis of 3-Spirocyclopentene-2-oxindoles having Two Contiguous Quaternary Centers

(2011) Fangrui Zhong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Mechanistic Studies of Pd-Catalyzed Regioselective Aryl CH Bond Functionalization with Strained Alkenes: Origin of Regioselectivity

(2011) David I. Chai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Flexible Strategy for Syntheses of Spirooxindoles using Palladium-Catalyzed Carbosilylation and Sakurai-Type Cyclization

(2011) Sudhir M. Hande et al.   ORGANIC LETTERS

Palladium-catalyzed double arylations of terminal olefins in acetic acid

(2011) Daichao Xu et al.   TETRAHEDRON

A novel MgI2 mediated unusual dimerization–spirocyclopropanation of bromo isomerised Morita–Baylis–Hillman adduct of isatin: a facile synthesis of 3-spirocyclopropane-2-oxindole derivatives

(2011) Kandapalam Arun Prasath Lingam et al.   TETRAHEDRON LETTERS

Palladium(0)-catalyzed cyclopropane C–H bond functionalization: synthesis of quinoline and tetrahydroquinoline derivatives

(2011) Sophie Rousseaux et al.   Chemical Science

Palladium-catalyzed intramolecular decarboxylative allylic arylation of α-aryl-γ-methylidene-δ-valerolactones

(2010) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Recent Contributions from the Baylis−Hillman Reaction to Organic Chemistry

(2010) Deevi Basavaiah et al.   CHEMICAL REVIEWS

Construction of a Tetracyclic Butterfly-Like Scaffold: Palladium-Catalyzed Heck/Arylation Cascade

(2010) Ko Hoon Kim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic Tandem Reaction to Construct Six-Membered Spirocyclic Oxindoles with Multiple Chiral Centres through a Formal [2+2+2] Annulation

(2010) Kun Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Domino Process to Spirooxindoles: Ligand Effect on Aminopalladation versus Carbopalladation

(2010) Stéphanie Jaegli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tuned CH Functionalization to Construct Aza-Podophyllotoxin/Aza-Conidendrin Derivatives by Means of Domino Cyclization

(2010) Yimin Hu et al.   Chemistry-An Asian Journal

Wittig Olefination between Phosphine, Aldehyde, and Allylic Carbonate: A General Method for Stereoselective Synthesis of Trisubstituted 1,3-Dienes with Highly Variable Substituents

(2010) Rong Zhou et al.   ORGANIC LETTERS

Palladium-Catalyzed Carbo-Heterofunctionalization of Alkenes for the Synthesis of Oxindoles and Spirooxindoles

(2010) Stéphanie Jaegli et al.   ORGANIC LETTERS

Novel Method for Synthesizing Spiro[4.5]cyclohexadienones through a Pd-Catalyzed Intramolecularipso-Friedel−Crafts Allylic Alkylation of Phenols

(2010) Tetsuhiro Nemoto et al.   ORGANIC LETTERS

One-Step Synthesis of the Benzocyclo[penta- to octa-]isoindole Core

(2009) Yimin Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Targeting Structural and Stereochemical Complexity by Organocascade Catalysis: Construction of Spirocyclic Oxindoles Having Multiple Stereocenters

(2009) Giorgio Bencivenni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid construction of five contiguous stereocenters in a multi-cascade reaction

(2009) Yimin Hu et al.   CHEMICAL COMMUNICATIONS

Formation of pentacyclic structures by a domino sequence on cyclic enamides

(2009) Gedu Satyanarayana et al.   CHEMICAL COMMUNICATIONS

Selective Synthesis of 3-Aryl Quinolin-2(1H)-ones and 3-(1-Arylmethylene)oxindoles Involving a 2-Fold Arene C−H Activation Process

(2009) Dong-Jun Tang et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Synthesis of Spirooxindoles by Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isatins

(2009) Ryo Shintani et al.   ORGANIC LETTERS

Domino Palladium-Catalyzed Heck-Intermolecular Direct Arylation Reactions

(2009) Olivier René et al.   ORGANIC LETTERS

Asymmetric Syntheses of Oxindole and Indole Spirocyclic Alkaloid Natural Products

(2009) Barry Trost et al.   SYNTHESIS-STUTTGART

Recent advances in the Pd-catalyzed chemical transformations of Baylis–Hillman adducts

(2009) Saravanan Gowrisankar et al.   TETRAHEDRON

Pd-catalyzed intramolecular amidation of 2-(buta-1,3-dienyl)phenylcarbamoyl chloride: a concise synthesis of spiro[indoline-3,3′-pyrrolidine]

(2009) Haruhi Kamisaki et al.   TETRAHEDRON LETTERS

Palladium–Oxygen and Palladium–Arene Interactions in Complexes Derived from Biaryl Aminocarbenes: Comparison with Biaryl Phosphanes

(2008) Joan Vignolle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Tandem Heck Reaction/CH Functionalization—Preparation of Spiro-Indane-Oxindoles

(2008) Rebecca T. Ruck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Construction of Tri- and Tetracyclic Heterocycles from Linear 1,6-Dienes by a Domino Reaction

(2008) Yimin Hu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles

(2008) Nathalie Lebrasseur et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Carbene Insertion and Trapping with Carbon Nucleophiles

(2008) Sean K. J. Devine et al.   ORGANIC LETTERS

Advances in the Baylis–Hillman reaction-assisted synthesis of cyclic frameworks

(2008) Vijay Singh et al.   TETRAHEDRON

Synthesis, Structure and Emission Properties of Spirocyclic Benzofuranones and Dihydroindolones: A Domino Insertion–Coupling–Isomerization– Diels–Alder Approach to Rigid Fluorophores

(2007) Daniel M. D'Souza et al.   CHEMISTRY-A EUROPEAN JOURNAL

Substrate dependent intramolecular palladium-catalysed cyclisation and subsequent β-H elimination or C–H activation: a general method for the synthesis of fused pyran rings

(2007) Rathin Jana et al.   TETRAHEDRON LETTERS