Palladium-Catalyzed, Chelation-Assisted Stereo- and Regioselective Synthesis of Tetrasubstituted Olefins by Oxidative Heck Arylation

Oxidative Heck Arylation for the Stereoselective Synthesis of Tetrasubstituted Olefins Using Nitroxides as Oxidants

(2012) Zhiheng He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(ii)-catalyzed direct C5-arylation of azole-4-carboxylates through double C–H bond cleavage

(2012) Ziyuan Li et al.   CHEMICAL COMMUNICATIONS

Palladium(II)-catalyzed oxidative homo-coupling of 1,3-dimethyluracil derivatives

(2012) Ko Hoon Kim et al.   TETRAHEDRON LETTERS

Palladium-catalyzed oxidative arylation of chromones via a double C–H activation: an expedient approach to flavones

(2012) Ko Hoon Kim et al.   TETRAHEDRON LETTERS

Highly Regio- and Stereoselective Synthesis of Multialkylated Olefins through Carbozirconation of Alkynylboronates and Sequential Negishi and Suzuki-Miyaura Coupling Reactions

(2011) Yasushi Nishihara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Increasing synthetic efficiency via direct C–H functionalization: formal synthesis of an inhibitor of botulinum neurotoxin

(2011) Shathaverdhan Potavathri et al.   CHEMICAL COMMUNICATIONS

Pd-catalyzed coupling of β-hydroxy α-diazocarbonyl compounds with aryl iodides: a migratory insertion/β-hydroxy elimination sequence

(2011) Lei Zhou et al.   CHEMICAL COMMUNICATIONS

Synthesis of ketones by palladium-catalysed desulfitative reaction of arylsulfinic acids with nitriles

(2011) Tao Miao et al.   CHEMICAL COMMUNICATIONS

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Pd-NHC Catalyzed Conjugate Addition versus the Mizoroki-Heck Reaction

(2011) Aditya L. Gottumukkala et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chelation-Mediated Palladium(II)-Catalyzed Domino Heck−Mizoroki/Suzuki−Miyaura Reactions Using Arylboronic Acids: Increasing Scope and Mechanistic Understanding

(2011) Samir Yahiaoui et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Direct Arylation of Heteroaromatic Compounds: Improved Conditions Utilizing Controlled Microwave Heating

(2011) Mostafa Baghbanzadeh et al.   JOURNAL OF ORGANIC CHEMISTRY

Substrate-Directable Heck Reactions with Arenediazonium Salts. The Regio- and Stereoselective Arylation of Allylamine Derivatives and Applications in the Synthesis of Naftifine and Abamines

(2011) Patrícia Prediger et al.   JOURNAL OF ORGANIC CHEMISTRY

Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes

(2011) Serge I. Gorelsky et al.   JOURNAL OF ORGANIC CHEMISTRY

Theoretical Analysis of the Mechanism of Palladium(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of themeta-Regioselectivity

(2011) Songlin Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Olefination of Furans and Thiophenes with Allyl Esters

(2011) Yuexia Zhang et al.   ORGANIC LETTERS

Pd-Catalyzed Olefination of Perfluoroarenes with Allyl Esters

(2011) Zejiang Li et al.   ORGANIC LETTERS

Palladium-catalyzed synthesis of indane and cyclobuta[a]indenes from homoallylic alcohols derived from Baylis–Hillman adducts: base-dependent stereoselectivity for the benzylidene group in cyclobuta[a]indene

(2011) Ko Hoon Kim et al.   TETRAHEDRON

Palladium-catalyzed double arylations of terminal olefins in acetic acid

(2011) Daichao Xu et al.   TETRAHEDRON

Palladium-catalyzed direct 5-arylation of 1,3-dimethyluracil with aryl bromides: an electrophilic metalation–deprotonation with electrophilic arylpalladium intermediate

(2011) Ko Hoon Kim et al.   TETRAHEDRON LETTERS

Palladium-catalyzed synthesis of benzo[c]pyrimido[1,6-a]azepine scaffold from Morita–Baylis–Hillman adducts: intramolecular 6-arylation of uracil nucleus

(2011) Hyun Seung Lee et al.   TETRAHEDRON LETTERS

Chelation-assisted palladium-catalyzed high regioselective heck diarylation reaction of 9-allyl-9H-purine: synthesis of 9-(3,3-diaryl-allyl)-9H-purines

(2011) Hai-Ming Guo et al.   RSC Advances

Synthesis of Tetracyclic Oxindoles from Isatin Containing Baylis-Hillman Adducts via Pd-Catalyzed Aryl-Aryl Coupling and Reduction with NaBH4

(2010) Hyun-Seung Lee et al.   BULLETIN OF THE KOREAN CHEMICAL SOCIETY

Recent Contributions from the Baylis−Hillman Reaction to Organic Chemistry

(2010) Deevi Basavaiah et al.   CHEMICAL REVIEWS

PdII-Catalyzed Highly Selective Arylation of Allyl Esters via CH Functionalization of Unreactive Arenes with Retention of the Traditional Leaving Group

(2010) Delin Pan et al.   Chemistry-An Asian Journal

Palladium-Catalyzed Direct Oxidative Alkenylation of Azoles

(2010) Mitsuru Miyasaka et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates

(2010) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselective Oxidative Arylation of Indoles BearingN-Alkyl Protecting Groups: Dual C−H Functionalization via a Concerted Metalation−Deprotonation Mechanism

(2010) Shathaverdhan Potavathri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins

(2010) Yasushi Obora et al.   MOLECULES

Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)2/HPMoV/O2 system

(2010) Yasushi Obora et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Pd-Catalyzed Reaction of Sterically Hindered Hydrazones with Aryl Halides: Synthesis of Tetra-Substituted Olefins Related toiso-Combretastatin A4

(2010) Etienne Brachet et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Oxidative Heck Reactions

(2010) Babak Karimi et al.   SYNTHESIS-STUTTGART

Alkenylation Reactions of Heteroarenes by Transition-Metal Catalysts

(2010) Renzo Rossi et al.   SYNTHESIS-STUTTGART

Heck Reactions with Palladium Nanoparticles in Ionic Liquids: Coupling of Aryl Chlorides with Deactivated Olefins

(2009) Vincenzo Calò et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(ii)-catalyzed coupling reactions with a chelating vinyl ether and arylboronic acids: a new Heck/Suzuki domino diarylation reaction

(2009) Alejandro Trejos et al.   CHEMICAL COMMUNICATIONS

aza-Baylis−Hillman Reaction

(2009) Valérie Declerck et al.   CHEMICAL REVIEWS

Pd(II)-Catalyzed Olefination of Electron-Deficient Arenes Using 2,6-Dialkylpyridine Ligands

(2009) Yang-Hui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Control of Chemo-, Regio-, and Stereoselectivities in Ligand-Free Pd-Catalyzed Oxidative Heck Reactions of Arylboronic Acids or Alkenylboronate with Allyl Esters

(2009) Yijin Su et al.   ORGANIC LETTERS

Highly Regio- and Stereoselective Heck Reaction of Allylic Esters with Arenediazonium Salts: Application to the Synthesis of Kavalactones

(2009) Angélica Venturini Moro et al.   ORGANIC LETTERS

Stereoselective Synthesis of (E)-(Trisubstituted alkenyl)borinic Esters: Stereochemistry Reversed by Ligand in the Palladium-Catalyzed Reaction of Alkynylborates with Aryl Halides

(2009) Naoki Ishida et al.   ORGANIC LETTERS

Recent advances in the Pd-catalyzed chemical transformations of Baylis–Hillman adducts

(2009) Saravanan Gowrisankar et al.   TETRAHEDRON

Ligand-Free Pd-Catalyzed Highly Selective Arylation of Allylic Esters with Retention of the Traditional Leaving Group

(2008) Delin Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular Pd(II)-Catalyzed Oxidative Biaryl Synthesis Under Air: Reaction Development and Scope

(2008) Benoît Liégault et al.   JOURNAL OF ORGANIC CHEMISTRY

Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles

(2008) Nathalie Lebrasseur et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 1,2- and 1,3-Dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of Aryl and Vinyl C−H Bonds

(2008) Ramesh Giri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General and Highly Selective Chelate-Controlled Intermolecular Oxidative Heck Reaction

(2008) Jared H. Delcamp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A simple method to prepare single isomer tetrasubstituted olefins by successive Suzuki–Miyaura cross-couplings of E-β-chloro-α-iodo-α,β-unsaturated esters

(2008) Julie Simard-Mercier et al.   TETRAHEDRON

Palladium-mediated synthesis of poly-fused heterocycles from Baylis–Hillman adducts

(2008) Hyun Seung Lee et al.   TETRAHEDRON

Advances in the Baylis–Hillman reaction-assisted synthesis of cyclic frameworks

(2008) Vijay Singh et al.   TETRAHEDRON

Enantiopure 2-aryl-2-methyl cyclopentanones by an asymmetric chelation-controlled Heck reaction using aryl bromides: increased preparative scope and effect of ring size on reactivity and selectivity

(2008) Gopal K. Datta et al.   TETRAHEDRON-ASYMMETRY