Construction of N-containing heterocycles via oxidative intramolecular N–H/X–H coupling

Indole Synthesis Based On A Modified Koser Reagent

(2014) Laura Fra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intramolecular C(sp3)H and C(sp2)H Amidation by Oxidative Cyclization

(2014) Zhen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Site-Selective Intramolecular Amidation of Unactivated C(sp3)H Bonds

(2014) Xuesong Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Coupling Reactions

(2014) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Dormant versus Evolving Aminopalladated Intermediates: Toward a Unified Mechanistic Scenario in PdII-Catalyzed Aminations

(2014) Jamshid Rajabi et al.   CHEMISTRY-A EUROPEAN JOURNAL

PhI(OCOCF3)2-Mediated Intramolecular Oxidative N–N Bond Formation: Metal-Free Synthesis of 1,2,4-Triazolo[1,5-a]pyridines

(2014) Zisheng Zheng et al.   JOURNAL OF ORGANIC CHEMISTRY

Construction of 1,4-Benzodiazepine Skeleton from 2-(Arylamino)benzamides through PhI(OAc)2-Mediated Oxidative C–N Bond Formation

(2014) Xuming Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-catalysed C–H activation of aliphatic amines to give strained nitrogen heterocycles

(2014) Andrew McNally et al.   NATURE

Copper-Catalyzed Synthesis of N-Aryl and N-Sulfonyl Indoles from 2-Vinyl­anilines with O2 as Terminal Oxidant and TEMPO as Cocatalyst

(2014) Sherry Chemler et al.   SYNLETT

Silver-catalysed direct amination of unactivated C–H bonds of functionalized molecules

(2014) Mingyu Yang et al.   Nature Communications

Oxidative coupling reactions for the functionalisation of C–H bonds using oxygen

(2014) Naeem Gulzar et al.   Catalysis Science & Technology

Hypervalent iodine(iii) catalyzed oxidative C–N bond formation in water: synthesis of benzimidazole-fused heterocycles

(2014) D. Nageswar Rao et al.   RSC Advances

Stereoselective Synthesis of Chiral α-Amino-β-Lactams through Palladium(II)-Catalyzed Sequential Monoarylation/Amidation of C(sp3)H Bonds

(2013) Qi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Catalytic Coupling Reactions: Selective Formation of CC and CX Bonds Using Radical Processes

(2013) Qiang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Use of a Readily Removable Auxiliary Group for the Synthesis of Pyrrolidones by the Palladium-Catalyzed Intramolecular Amination of Unactivated γ C(sp3)H Bonds

(2013) Gang He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H cycloamination of N-aryl-2-aminopyridines and N-arylamidines catalyzed by an in situ generated hypervalent iodine(iii) reagent

(2013) Yimiao He et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles

(2013) Anton V. Gulevich et al.   CHEMICAL REVIEWS

Oxidative C–H amination reactions

(2013) Marie-Laure Louillat et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Oxidative Amination and Allylic Amination of Alkenes

(2013) Timothy W. Liwosz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of 10-Methylacridin-9(10H)-ones through Cu-Catalyzed Intramolecular Oxidative C(sp2)-H Amination of 2-(Methylamino)benzophenones

(2013) Jinbo Huang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Intramolecular N–S Bond Formation by Oxidative Dehydrogenative Cyclization

(2013) Zhen Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Indolines via Pd(II)-Catalyzed Amination of C–H Bonds Using PhI(OAc)2 as the Bystanding Oxidant

(2013) Tian-Sheng Mei et al.   ORGANIC LETTERS

Iodobenzene Catalyzed C–H Amination of N-Substituted Amidines Using m-Chloroperbenzoic Acid

(2013) Santhosh Kumar Alla et al.   ORGANIC LETTERS

One-pot synthesis of isoxazoles from enaminones: an application of Fe(II) as the catalyst for ring expansion of 2H-azirine intermediates

(2013) Yunhui Zheng et al.   TETRAHEDRON LETTERS

1,2,3-Triazoles as versatile directing group for selective sp2 and sp3 C–H activation: cyclization vs substitution

(2013) Xiaohan Ye et al.   Chemical Science

A Visible-Light-Mediated Oxidative CN Bond Formation/Aromatization Cascade: Photocatalytic Preparation of N-Arylindoles

(2012) Soumitra Maity et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Stereoselective Metal-Free Oxyaminations Using Chiral Hypervalent Iodine Reagents

(2012) Umar Farid et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed intramolecular direct amination of sp2 C–H bonds for the synthesis of N-aryl acridones

(2012) Wang Zhou et al.   CHEMICAL COMMUNICATIONS

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Intramolecular Oxidative CH Functionalization and CN Formation of 2-Aminobenzophenones: Unusual Pseudo-1,2-Shift of the Substituent on the Aryl Ring

(2012) Pang-Chi Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Intramolecular Allylic C–H Amination

(2012) Shauna M. Paradine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of carbazolones and 3-acetylindoles via oxidative C–N bond formation through PIFA-mediated annulation of 2-aryl enaminones

(2012) Xu Ban et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Synthesis of Purine-Fused Polycyclics

(2012) Gui-Rong Qu et al.   ORGANIC LETTERS

Copper-Catalyzed Aliphatic C–H Amination with an Amidine Moiety

(2012) Hui Chen et al.   ORGANIC LETTERS

Chan–Lam coupling reactions: synthesis of heterocycles

(2012) Kodepelly Sanjeeva Rao et al.   TETRAHEDRON

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Transition-metal catalyzed oxidative cross-coupling reactions to form C–C bonds involving organometallic reagents as nucleophiles

(2011) Wei Shi et al.   CHEMICAL SOCIETY REVIEWS

Intramolecular Oxidative C−N Bond Formation for the Synthesis of Carbazoles: Comparison of Reactivity between the Copper-Catalyzed and Metal-Free Conditions

(2011) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterocycle Synthesis via Direct C–H/N–H Coupling

(2011) Enrico T. Nadres et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Syntheses of Azetidines, Pyrrolidines, and Indolines via Palladium Catalyzed Intramolecular Amination of C(sp3)–H and C(sp2)–H Bonds at γ and δ Positions

(2011) Gang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Aerobic Synthesis of 3-Azabicyclo[3.1.0]hex-2-enes and 4-Carbonylpyrroles fromN-Allyl/Propargyl Enamine Carboxylates

(2011) Kah Kah Toh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Aerobic Oxidative Intramolecular Alkene C–H Amination Leading toN-Heterocycles

(2011) Juyou Lu et al.   ORGANIC LETTERS

Pd-Catalyzed C−H Activation/C−N Bond Formation: A New Route to 1-Aryl-1H-benzotriazoles

(2011) Rapolu Kiran Kumar et al.   ORGANIC LETTERS

Pd-Catalyzed Intramolecular Oxidative C–H Amination: Synthesis of Carbazoles

(2011) So Won Youn et al.   ORGANIC LETTERS

Copper-Catalyzed Aerobic Oxidative Intramolecular C–H Amination Leading to Imidazobenzimidazole Derivatives

(2011) Xiaoqiang Wang et al.   ORGANIC LETTERS

A Divergent and Selective Synthesis of Isomeric Benzoxazoles from a Single N–Cl Imine

(2011) Cheng-yi Chen et al.   ORGANIC LETTERS

Efficient Synthesis of Pyrazoles: Oxidative CC/NN Bond-Formation Cascade

(2010) Julia J. Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Direct Intramolecular C−H Amination Reaction Cocatalyzed by Copper(II) and Iron(III) as Part of an Efficient Route for the Synthesis of Pyrido[1,2-a]benzimidazoles fromN-Aryl-2-aminopyridines

(2010) Honggen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Heterocycles via Pd-Ligand Controlled Cyclization of 2-Chloro-N-(2-vinyl)aniline: Preparation of Carbazoles, Indoles, Dibenzazepines, and Acridines

(2010) Dmitry Tsvelikhovsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diversification of a β-lactam pharmacophore via allylic C–H amination: accelerating effect of Lewis acid co-catalyst

(2010) Xiangbing (Ben) Qi et al.   TETRAHEDRON

Intramolecular diamination and alkoxyamination of alkenes with N-sulfonyl ureas employing N-iodosuccinimide

(2010) Hao Li et al.   TETRAHEDRON

Palladium-Catalyzed Amidation of Unactivated C(sp3)H Bonds: from Anilines to Indolines

(2009) Julia J. Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum-catalysed aerobic 1,2-aminooxygenation of alkenes

(2009) Kilian Muñiz et al.   CHEMICAL COMMUNICATIONS

Direct Imidation to Construct 1H-Benzo[d]imidazole through PdII-Catalyzed CH Activation Promoted by Thiourea

(2009) Qing Xiao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iodobenzene Diacetate–Promoted N–N and N–O Bond Formation for Pyrazolo- and Isoxazolopyrimidine Syntheses

(2009) Hironao Sajiki et al.   HETEROCYCLES

A Convenient Approach to Fused Indeno-1,4-diazepinones through Hypervalent Iodine Chemistry

(2009) Elizabeth Malamidou-Xenikaki et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed Amination of C−H Bonds Using Single-Electron or Two-electron Oxidants

(2009) Tian-Sheng Mei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allylic C−H Amination for the Preparation ofsyn-1,3-Amino Alcohol Motifs

(2009) Grant T. Rice et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes: Formation of Seven-Membered Amides and Evidence for Allylic C−H Activation

(2009) Liang Wu et al.   ORGANIC LETTERS

PIFA-Mediated Oxidative Cyclization of 1-Carbamoyl-1-oximylcycloalkanes: Synthesis of Spiro-Fused Pyrazolin-5-oneN-Oxides

(2009) Kewei Wang et al.   ORGANIC LETTERS

Synthesis of Tetrahydropyrroloiminoquinone Alkaloids Based on Electrochemically Generated Hypervalent Iodine Oxidative Cyclization

(2009) Keisuke Inoue et al.   ORGANIC LETTERS

Synthesis of Indolines and Tetrahydroisoquinolines from Arylethylamines by PdII-Catalyzed CH Activation Reactions

(2008) Jiao-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Functionalization/CN Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines

(2008) Gordon Brasche et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

(2008) Claas H. Hövelmann et al.   CHEMICAL COMMUNICATIONS

Intramolecular Diamination of Alkenes with Palladium(II)/Copper(II) Bromide and IPy2BF4: The Role of Halogenated Intermediates

(2008) Kilian Muñiz et al.   Chemistry-An Asian Journal

Synthesis of Diamino Carboxylic Esters by Palladium-Catalyzed Oxidative Intramolecular Diamination of Acrylates

(2008) Kilian Muñiz et al.   Chemistry-An Asian Journal

Palladium-Catalyzed Method for the Synthesis of Carbazoles via Tandem C−H Functionalization and C−N Bond Formation

(2008) W. C. Peter Tsang et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic C−H Amination for the Preparation of Substituted 1,2-Diamines

(2008) David E. Olson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of β-, γ-, and δ-Lactams via Pd(II)-Catalyzed C−H Activation Reactions

(2008) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Pd(II)-Catalyzed C−H Bond Amination to Carbazole at Ambient Temperature

(2008) James A. Jordan-Hore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Oxidative Cyclization of Urea-Tethered Alkenes with Hypervalent Iodine

(2008) Brian M. Cochran et al.   ORGANIC LETTERS

Oxidative Diamination of Alkenes with Ureas as Nitrogen Sources:  Mechanistic Pathways in the Presence of a High Oxidation State Palladium Catalyst

(2007) Kilian Muñiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY