Oxidative coupling reactions for the functionalisation of C–H bonds using oxygen

Ruthenium-Catalyzed Cross-Dehydrogenativeortho-N-Carbazolation of Diarylamines: Versatile Access to Unsymmetrical Diamines

(2014) Marie-Laure Louillat et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acid-Catalyzed Oxidative Radical Addition of Ketones to Olefins

(2014) Bertrand Schweitzer-Chaput et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Dehydrogenative Couplings between Indoles and β-Keto Esters: Ligand-Assisted Ligand Tautomerization and Dehydrogenation via a Proton-Assisted Electron Transfer to Pd(II)

(2014) Mikko V. Leskinen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling the Catalytic Aerobic Oxidation of Phenols

(2014) Kenneth Virgel N. Esguerra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Predictably Selective (sp3)C–O Bond Formation through Copper Catalyzed Dehydrogenative Coupling: Facile Synthesis of Dihydro-oxazinone Derivatives

(2014) Atanu Modak et al.   ORGANIC LETTERS

Enantioselective oxidative-coupling of polycyclic phenols

(2014) Shinobu Takizawa et al.   TETRAHEDRON

Iron-catalyzed/mediated oxidative transformation of C–H bonds

(2014) Fan Jia et al.   Organic Chemistry Frontiers

Synergistic Effect of Ketone and Hydroperoxide in Brønsted Acid Catalyzed Oxidative Coupling Reactions

(2013) Bertrand Schweitzer-Chaput et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Continuous-Flow Oxidative Cyanation of Primary and Secondary Amines Using Singlet Oxygen

(2013) Dmitry B. Ushakov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Comparison of Oxidative Aromatic Coupling and the Scholl Reaction

(2013) Marek Grzybowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Allylic Alkylation of Alkene through Direct C (sp3)-H Functionalization

(2013) Guihua Chen et al.   ChemCatChem

Scalable synthesis of quaterrylene: solution-phase 1H NMR spectroscopy of its oxidative dication

(2013) Rajesh Thamatam et al.   CHEMICAL COMMUNICATIONS

Aerobic Copper-Catalyzed Organic Reactions

(2013) Scott E. Allen et al.   CHEMICAL REVIEWS

Aerobic Iron-Based Cross-Dehydrogenative Coupling Enables Efficient Diversity-Oriented Synthesis of Coumestrol-Based Selective Estrogen Receptor Modulators

(2013) Umesh A. Kshirsagar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organometallic aspects of transition-metal catalysed regioselective C–H bond functionalisation of arenes and heteroarenes

(2013) Anant R. Kapdi   DALTON TRANSACTIONS

Cu(OTf)2-Catalyzed Dehydrogenative C-H Activation under Atmospheric Oxygen: An Expedient Approach to Pyrrolo[3,2-d]pyrimidine Derivatives

(2013) B. Roy et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cobalt(II)-Porphyrin-Catalyzed Aerobic Oxidation: Oxidative Coupling of Phenols

(2013) Qing Jiang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Manganese-catalyzed aerobic dehydrogenative cyclization toward ring-fused indole skeletons

(2013) Kounosuke Oisaki et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Aerobic C–H amination of tetrahydrocarbazole derivatives via photochemically generated hydroperoxides

(2013) Naeem Gulzar et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regio- and Stereoselective Direct N-Alkenylation of Indoles via Pd-Catalyzed Aerobic Oxidation

(2013) Ge Wu et al.   ORGANIC LETTERS

Hexachlorocyclohexa-2,5-dien-1-one

(2013) Zahra Tanbakouchian   SYNLETT

Catalytic asymmetric α-C(sp3)–H functionalization of amines

(2013) Yan Qin et al.   TETRAHEDRON LETTERS

Recent development of direct asymmetric functionalization of inert C–H bonds

(2013) Chao Zheng et al.   RSC Advances

Computational Studies on the Mechanism of the Copper-Catalyzed sp3-CH Cross-Dehydrogenative Coupling Reaction

(2013) Gui-Juan Cheng et al.   ChemPlusChem

Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)

(2012) Alison N. Campbell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Sulfonic Acid-Catalyzed Autoxidative Carbon-Carbon Coupling Reaction under Elevated Partial Pressure of Oxygen

(2012) Áron Pintér et al.   ADVANCED SYNTHESIS & CATALYSIS

Luminescent Organogold(III) Complexes with Long-Lived Triplet Excited States for Light-Induced Oxidative CH Bond Functionalization and Hydrogen Production

(2012) Wai-Pong To et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Dehydrogenative Cyclization of N-Methyl-N-phenylhydrazones: Synthesis of Cinnolines

(2012) Guangwu Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free TEMPO-catalyzed oxidative C–C bond formation from Csp3–H bonds using molecular oxygen as the oxidant

(2012) Bo Zhang et al.   CHEMICAL COMMUNICATIONS

Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

(2012) Zhuangzhi Shi et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Dehydrogenative β′-Arylation of β-Keto Esters under Aerobic Conditions: Interplay of Metal and Brønsted Acids

(2012) Kai-Tai Yip et al.   CHEMISTRY-A EUROPEAN JOURNAL

CDC Reactions of N-Aryl Tetrahydroisoquinolines Using Catalytic Amounts of DDQ: CH Activation under Aerobic Conditions

(2012) Kaliyamoorthy Alagiri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct α-Functionalization of Saturated Cyclic Amines

(2012) Emily A. Mitchell et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Coupling of Enolates, Enol Silanes, and Enamines: Methods and Natural Product Synthesis

(2012) Fenghai Guo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Metal/Organo-Catalyzed Aerobic Oxidative sp3C–H Olefination of Tertiary Amines Using Molecular Oxygen as the Sole Oxidant

(2012) Gen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Aerobic Oxidative Cyclization of N-Aryl Imines: Indole Synthesis from Anilines and Ketones

(2012) Ye Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric α-Acylation of Tertiary Amines Mediated by a Dual Catalysis Mode: N-Heterocyclic Carbene and Photoredox Catalysis

(2012) Daniel A. DiRocco et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Comparative Mechanistic Study of Cu-Catalyzed Oxidative Coupling Reactions with N-Phenyltetrahydroisoquinoline

(2012) Esther Boess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward Polynuclear Ru–Cu Catalytic Dehydrogenative C–N Bond Formation, on the Reactivity of Carbazoles

(2012) Marie-Laure Louillat et al.   ORGANIC LETTERS

Copper-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling of Amine and α-Carbonyl Aldehyde: A Practical and Efficient Approach to α-Ketoamides with Wide Substrate Scope

(2012) Chun Zhang et al.   ORGANIC LETTERS

Amberlyst-15-Catalyzed One-Pot Synthesis of 2-Aryltetrahydrofurans from Tetrahydrofuran

(2012) Naciye Talinli et al.   SYNLETT

Catalytic aerobic production of imines en route to mild, green, and concise derivatizations of amines

(2012) Toshiaki Sonobe et al.   Chemical Science

Asymmetric catalytic carbon–carbon coupling reactions via C–H bond activation

(2012) Lei Yang et al.   Catalysis Science & Technology

A Highly Efficient Gold-Catalyzed Oxidative CC Coupling from CH Bonds Using Air as Oxidant

(2011) Jin Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitroxides: Applications in Synthesis and in Polymer Chemistry

(2011) Ludger Tebben et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights

(2011) Alison E. Wendlandt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands

(2011) Alison N. Campbell et al.   CHEMICAL COMMUNICATIONS

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Dehydrogenative coupling reactions catalysed by Rose Bengal using visible light irradiation

(2011) Yuanhang Pan et al.   GREEN CHEMISTRY

Copper-Catalyzed Oxidative Cross-Coupling ofN,N-Dimethylanilines with Heteroarenes under Molecular Oxygen

(2011) Lehao Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Studies on a Cu-Catalyzed Aerobic Oxidative Coupling Reaction withN-Phenyl Tetrahydroisoquinoline: Structure of Intermediates and the Role of Methanol As a Solvent

(2011) Esther Boess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aerobic Pd-Catalyzed sp3C−H Olefination: A Route to Both N-Heterocyclic Scaffolds and Alkenes

(2011) Kara J. Stowers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H functionalization of tertiary amines by cross dehydrogenative coupling reactions: solvent-free synthesis of α-aminonitriles and β-nitroamines under aerobic condition

(2011) Kaliyamoorthy Alagiri et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organocatalytic Asymmetric Intermolecular Dehydrogenative α-Alkylation of Aldehydes Using Molecular Oxygen as Oxidant

(2011) Bo Zhang et al.   ORGANIC LETTERS

Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation

(2011) Durga Prasad Hari et al.   ORGANIC LETTERS

Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed CH Functionalization

(2010) Yusuke Izawa et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Intermolecular Amination of Acidic Aryl CH Bonds with Primary Aromatic Amines

(2010) Huaiqing Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Autoxidative Carbon-Carbon Bond Formation from Carbon-Hydrogen Bonds

(2010) Áron Pintér et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed direct oxidative Heck–Cassar–Sonogashira type alkynylation of indoles with alkynes under oxygen

(2010) Luo Yang et al.   CHEMICAL COMMUNICATIONS

Copper-Mediated Direct Cross-Coupling of 1,3,4-Oxadiazoles and Oxazoles with Terminal Alkynes

(2010) Masanori Kitahara et al.   CHEMISTRY-A EUROPEAN JOURNAL

Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction

(2010) Caroline J. Scheuermann   Chemistry-An Asian Journal

Recent advances in asymmetric oxidative coupling of 2-naphthol and its derivatives

(2010) Hui Wang   CHIRALITY

A Direct Intramolecular C−H Amination Reaction Cocatalyzed by Copper(II) and Iron(III) as Part of an Efficient Route for the Synthesis of Pyrido[1,2-a]benzimidazoles fromN-Aryl-2-aminopyridines

(2010) Honggen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light Photoredox Catalysis: Aza-Henry Reactions via C−H Functionalization

(2010) Allison G. Condie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allylic C−H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy To Achieve Aerobic Catalytic Turnover

(2010) Alison N. Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

First C−H Activation Route to Oxindoles using Copper Catalysis

(2010) Johannes E. M. N. Klein et al.   ORGANIC LETTERS

Nickel- and Copper-Catalyzed Direct Alkynylation of Azoles and Polyfluoroarenes with Terminal Alkynes under O2or Atmospheric Conditions

(2010) Naoto Matsuyama et al.   ORGANIC LETTERS

Copper-Catalyzed Oxidative Amination of Benzoxazoles via C−H and C−N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources

(2010) Shengmei Guo et al.   ORGANIC LETTERS

Catalytic Oxidative Coupling Reactions for the Formation of Carbon-Carbon Bonds without Carbon-Metal Intermediates

(2010) Martin Klussmann et al.   SYNTHESIS-STUTTGART

Iron-catalyzed oxidative homo-coupling of indoles via C–H cleavage

(2010) Tianmin Niu et al.   TETRAHEDRON LETTERS

Oxindole Synthesis by Direct Coupling of C sp 2H and C sp 3H Centers

(2009) Yi-Xia Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxindole synthesis by direct C–H, Ar–H coupling

(2009) Alexis Perry et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed aerobic phosphonation of sp3 C–H bonds

(2009) Olivier Baslé et al.   CHEMICAL COMMUNICATIONS

An efficient copper-catalyzed oxidative Mannich reaction between tertiary amines and methyl ketones

(2009) Youming Shen et al.   CHEMICAL COMMUNICATIONS

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

Intermolecular oxidative cross-coupling of arenes

(2009) James A. Ashenhurst   CHEMICAL SOCIETY REVIEWS

Green Chemistry: Principles and Practice

(2009) Paul Anastas et al.   CHEMICAL SOCIETY REVIEWS

Toward Efficient Palladium-Catalyzed Allylic CH Alkylation

(2009) Thomas Jensen et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Aromatic Glaser−Hay Reaction

(2009) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Olefination of Electron-Deficient Arenes Using 2,6-Dialkylpyridine Ligands

(2009) Yang-Hui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Amidation of Heterocyclic and Aromatic C−H Bonds

(2009) Qiu Wang et al.   ORGANIC LETTERS

Direct Amination of Azoles via Catalytic C−H, N−H Coupling

(2009) Daiki Monguchi et al.   ORGANIC LETTERS

Mechanisms of Mn(OAc)3-based oxidative free-radical additions and cyclizations

(2009) Barry B. Snider   TETRAHEDRON

Catalytic alkylation of benzylic C–H bonds with 1,3-dicarbonyl compounds utilizing oxygen as terminal oxidant

(2009) Camille A. Correia et al.   TETRAHEDRON LETTERS

CH Functionalization/CN Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines

(2008) Gordon Brasche et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Intermolecular Aerobic Oxidative Amination of Terminal Alkenes: Efficient Synthesis of Linear Allylamine Derivatives

(2008) Guosheng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Enolate Heterocoupling: Scope, Mechanism, and Application

(2008) Michael P. DeMartino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Twofold C−H Functionalization: Palladium-CatalyzedOrthoArylation of Anilides

(2008) Gordon Brasche et al.   ORGANIC LETTERS

Palladium-Catalyzed Intramolecular Coupling of Arenes and Unactivated Alkanes in Air

(2008) Benoît Liégault et al.   ORGANOMETALLICS

Highly efficient Cu-catalyzed oxidative coupling of tertiary amines and siloxyfurans

(2008) Youming Shen et al.   TETRAHEDRON

Multiple CH Activations To Construct Biologically Active Molecules in a Process Completely Free of Organohalogen and Organometallic Components

(2007) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION