Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling Facilitated by a Weak Amine Base with Water as a Cosolvent

Nickel and Palladium Catalysis: Stronger Demand than Ever

(2022) Victor M. Chernyshev et al.   ACS Catalysis

Cobalt-Catalyzed Coupling of Aryl Chlorides with Aryl Boron Esters Activated by Alkoxides

(2021) Sanita B. Tailor et al.   ACS Catalysis

Synthesis of Arylpalladium(II) Boronates: Confirming the Structure of Pre‐transmetalation Intermediates in the Suzuki–Miyaura Reaction Crystallographically

(2021) Angus Olding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advancing Base-Metal Catalysis: Development of a Screening Method for Nickel-Catalyzed Suzuki–Miyaura Reactions of Pharmaceutically Relevant Heterocycles

(2021) Matthew J. Goldfogel et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Diboron-Promoted Reduction of Ni(II) Salts: Precatalyst Activation Studies Relevant to Ni-Catalyzed Borylation Reactions

(2021) Matthew V. Joannou et al.   ORGANOMETALLICS

Stereoconvergent and -divergent Synthesis of Tetrasubstituted Alkenes by Nickel-Catalyzed Cross-Couplings

(2021) Daniel Zell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rational Design of an Iron-Based Catalyst for Suzuki-Miyaura Cross-Couplings Involving Heteroaromatic Boronic Esters and Tertiary Alkyl Electrophiles

(2020) Michael P. Crockett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Impact of Cross-Coupling Reactions in Drug Discovery and Development

(2020) Melissa J. Buskes et al.   MOLECULES

Discovery of CC-90011: A Potent and Selective Reversible Inhibitor of Lysine Specific Demethylase 1 (LSD1)

(2020) Toufike Kanouni et al.   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Amidation and Amination of (Hetero)aryl Chlorides under Homogeneous Conditions Enabled by a Soluble DBU/NaTFA Dual-Base System

(2019) Gregory L. Beutner et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

An air-stable binary Ni(0)–olefin catalyst

(2019) Lukas Nattmann et al.   Nature Catalysis

Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: A Mechanistic Focus on Boron-to-Nickel Transmetalation

(2018) Pierre-Adrien Payard et al.   ACS Catalysis

Advances in Base-Metal Catalysis: Development of a Screening Platform for Nickel-Catalyzed Borylations of Aryl (Pseudo)halides with B2(OH)4

(2018) John R. Coombs et al.   ORGANOMETALLICS

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki–Miyaura Reaction

(2017) Andy A. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Study of an Improved Ni Precatalyst for Suzuki–Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species

(2017) Megan Mohadjer Beromi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of a Kilogram-Scale Process for the Enantioselective Synthesis of 3-Isopropenyl-cyclohexan-1-one via Rh/DTBM-SEGPHOS-Catalyzed Asymmetric Hayashi Addition Enabled by 1,3-Diol Additives

(2017) Eric M. Simmons et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Cobalt-Catalyzed Cross-Coupling Reactions of Arylboronic Esters and Aryl Halides

(2017) Hung A. Duong et al.   ORGANOMETALLICS

Oxidative Addition of Aryl Electrophiles to a Prototypical Nickel(0) Complex: Mechanism and Structure/Reactivity Relationships

(2017) Sonia Bajo et al.   ORGANOMETALLICS

Development of Robust, Scaleable Catalytic Processes through Fundamental Understanding of Reaction Mechanisms

(2017) Carolyn S. Wei et al.   TOPICS IN CATALYSIS

Well-defined nickel and palladium precatalysts for cross-coupling

(2017) Nilay Hazari et al.   Nature Reviews Chemistry

A Quantitative Scale of Oxophilicity and Thiophilicity

(2016) Kasper P. Kepp   INORGANIC CHEMISTRY

Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki–Miyaura Cross Coupling

(2016) Jamie M. Neely et al.   ACS Central Science

Copper-catalysed cross-couplings of arylboronate esters with aryl and heteroaryl iodides and bromides

(2015) Santosh K. Gurung et al.   Organic Chemistry Frontiers

Copper-Catalyzed Cross-Coupling of Boronic Esters with Aryl Iodides and Application to the Carboboration of Alkynes and Allenes

(2014) Yiqing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Air-Stable Nickel Precatalysts for Fast and Quantitative Cross-Coupling of Aryl Sulfamates with Aryl Neopentylglycolboronates at Room Temperature

(2014) Ryan L. Jezorek et al.   ORGANIC LETTERS

Nickel Hydroxo Complexes as Intermediates in Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling

(2014) Alec H. Christian et al.   ORGANOMETALLICS

A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

(2014) Eric A. Standley et al.   ORGANOMETALLICS

Transmetalation in the Suzuki-Miyaura Coupling: The Fork in the Trail

(2013) Alastair J. J. Lennox et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts

(2013) Fu-She Han   CHEMICAL SOCIETY REVIEWS

Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B2(OH)4]

(2013) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates

(2013) Nathaniel H. Park et al.   ORGANIC LETTERS

Nickel-Catalyzed Suzuki–Miyaura Couplings in Green Solvents

(2013) Stephen D. Ramgren et al.   ORGANIC LETTERS

Highly Reactive, Single-Component Nickel Catalyst Precursor for Suzuki-Miyuara Cross-Coupling of Heteroaryl Boronic Acids with Heteroaryl Halides

(2012) Shaozhong Ge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

trans-Chloro(1-Naphthyl)bis(triphenylphosphine)nickel(II)/PCy3 Catalyzed Cross-Coupling of Aryl and Heteroaryl Neopentylglycolboronates with Aryl and Heteroaryl Mesylates and Sulfamates at Room Temperature

(2012) Pawaret Leowanawat et al.   JOURNAL OF ORGANIC CHEMISTRY

A Highly Practical and Reliable Nickel Catalyst for Suzuki-Miyaura Coupling of Aryl Halides

(2011) Yu-Long Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Cross-Coupling Reaction of Organoboron Compounds with Primary Alkyl Halides and Pseudohalides

(2011) Chu-Ting Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base

(2011) Christian Amatore et al.   CHEMISTRY-A EUROPEAN JOURNAL

Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids

(2011) Xin-Heng Fan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The Medicinal Chemist’s Toolbox: An Analysis of Reactions Used in the Pursuit of Drug Candidates

(2011) Stephen D. Roughley et al.   JOURNAL OF MEDICINAL CHEMISTRY

Distinguishing Between Pathways for Transmetalation in Suzuki−Miyaura Reactions

(2011) Brad P. Carrow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Factors Determining the Selection of Organic Reactions by Medicinal Chemists and the Use of These Reactions in Arrays (Small Focused Libraries)

(2010) Tony W. J. Cooper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NiII-(σ-Aryl) Complex Catalyzed Suzuki Reaction of Aryl Tosylates with Arylboronic Acids

(2010) Xin-Heng Fan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Suzuki−Miyaura Coupling of Alkyl Halides

(2010) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY