Well-defined nickel and palladium precatalysts for cross-coupling

Mechanistic Study of an Improved Ni Precatalyst for Suzuki–Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species

(2017) Megan Mohadjer Beromi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp3–sp2 Cross-Coupling

(2016) John C. Tellis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Biaryls through Nickel-Catalyzed Suzuki-Miyaura Coupling of Amides by Carbon-Nitrogen Bond Cleavage

(2016) Shicheng Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Which Metals are Green for Catalysis? Comparison of the Toxicities of Ni, Cu, Fe, Pd, Pt, Rh, and Au Salts

(2016) Ksenia S. Egorova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

(2016) Paula Ruiz-Castillo et al.   CHEMICAL REVIEWS

Palladium-Catalyzed N-Arylation of Iminodibenzyls and Iminostilbenes with Aryl- and Heteroaryl Halides

(2016) Wenliang Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd-PEPPSI-IHeptCl: A General-Purpose, Highly Reactive Catalyst for the Selective Coupling of Secondary Alkyl Organozincs

(2016) Bruce Atwater et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Synthesis of Diaryl Ketones by Nickel-Catalyzed Negishi Cross-Coupling of Amides by Carbon-Nitrogen Bond Cleavage at Room Temperature Accelerated by a Solvent Effect

(2016) Shicheng Shi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Cross-Electrophile Coupling with Organic Reductants in Non-Amide Solvents

(2016) Lukiana L. Anka-Lufford et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparing (Multi)Fluoroarenes as Building Blocks for Synthesis: Nickel-Catalyzed Borylation of Polyfluoroarenes via C–F Bond Cleavage

(2016) Jing Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Cross-Electrophile Coupling of N-Hydroxyphthalimide Esters with Aryl Iodides

(2016) Kierra M. M. Huihui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Suzuki–Miyaura and Hiyama–Denmark Couplings of Aryl Sulfamates

(2016) Patrick R. Melvin et al.   ORGANIC LETTERS

Development of a Method for the N-Arylation of Amino Acid Esters with Aryl Triflates

(2016) Sandra M. King et al.   ORGANIC LETTERS

Benchtop Delivery of Ni(cod)2 using Paraffin Capsules

(2016) Jacob E. Dander et al.   ORGANIC LETTERS

Regioselective 2-Amination of Polychloropyrimidines

(2016) Sean M. Smith et al.   ORGANIC LETTERS

Dicumyl Peroxide as a Methylating Reagent in the Ni-Catalyzed Methylation of Ortho C–H Bonds in Aromatic Amides

(2016) Teruhiko Kubo et al.   ORGANIC LETTERS

Recyclable NHC Catalyst for the Development of a Generalized Approach to Continuous Buchwald–Hartwig Reaction and Workup

(2016) Anthony Chartoire et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

A Comparative Reactivity Survey of Some Prominent Bisphosphine Nickel(II) Precatalysts in C–N Cross-Coupling

(2016) Jillian S. K. Clark et al.   ORGANOMETALLICS

Aryl amination using ligand-free Ni(II) salts and photoredox catalysis

(2016) Emily B. Corcoran et al.   SCIENCE

NiIICl(1-Naphthyl)(PCy3)2, An Air-Stable σ-NiII Precatalyst for Quantitative Cross-Coupling of Aryl C–O Electrophiles with Aryl Neopentylglycolboronates

(2016) Virgil Percec et al.   SYNTHESIS-STUTTGART

An Indefinitely Air-Stable σ-NiII Precatalyst for Quantitative Cross-Coupling of Unreactive Aryl Halides and Mesylates with Aryl Neopentylglycolboronates

(2016) Virgil Percec et al.   SYNTHESIS-STUTTGART

Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design

(2016) Christopher M. Lavoie et al.   Nature Communications

Catalytic α-Arylation of Imines Leading to N-Unprotected Indoles and Azaindoles

(2016) Enrico Marelli et al.   ACS Catalysis

Continuous flow Negishi cross-couplings employing silica-supported Pd-PEPPSI–IPr precatalyst

(2016) Gregory A. Price et al.   Catalysis Science & Technology

Methods and Mechanisms for Cross-Electrophile Coupling of Csp2 Halides with Alkyl Electrophiles

(2015) Daniel J. Weix   ACCOUNTS OF CHEMICAL RESEARCH

Inside Cover: CN Coupling of Indoles and Carbazoles with Aromatic Chlorides Catalyzed by a Single-Component NHC-Nickel(0) Precursor (Adv. Synth. Catal. 5/2015)

(2015) Silvia G. Rull et al.   ADVANCED SYNTHESIS & CATALYSIS

Dialkyl Ether Formation by Nickel-Catalyzed Cross-Coupling of Acetals and Aryl Iodides

(2015) Kevin M. Arendt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Comparison of dppf-Supported Nickel Precatalysts for the Suzuki-Miyaura Reaction: The Observation and Activity of Nickel(I)

(2015) Louise M. Guard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Monoarylation of Primary Amines Using the Pd-PEPPSI-IPentClPrecatalyst

(2015) Sepideh Sharif et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Selective Cross-Coupling of Secondary Alkyl Zinc Reagents to Five-Membered-Ring Heterocycles Using Pd-PEPPSI-IHeptCl

(2015) Bruce Atwater et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylthiolation of Aryl Iodides and Bromides Enabled by a Bench-Stable and Easy-To-Recover Dinuclear Palladium(I) Catalyst

(2015) Guoyin Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Improved System for the Aqueous Lipshutz-Negishi Cross-Coupling of Alkyl Halides with Aryl Electrophiles

(2015) Vasudev R. Bhonde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of New Ligands for the Palladium-Catalyzed Arylation of α-Branched Secondary Amines

(2015) Nathaniel H. Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arylation of Amines in Alkane Solvents by using Well-Defined Palladium-N-Heterocyclic Carbene Complexes

(2015) Enrico Marelli et al.   ChemCatChem

General and Mild Ni0-Catalyzed α-Arylation of Ketones Using Aryl Chlorides

(2015) José A. Fernández-Salas et al.   CHEMISTRY-A EUROPEAN JOURNAL

Generating Active “L-Pd(0)” via Neutral or Cationic π-Allylpalladium Complexes Featuring Biaryl/Bipyrazolylphosphines: Synthetic, Mechanistic, and Structure–Activity Studies in Challenging Cross-Coupling Reactions

(2015) A. J. DeAngelis et al.   JOURNAL OF ORGANIC CHEMISTRY

A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides

(2015) Aaron C. Sather et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Virtually Instantaneous, Room-Temperature [11C]-Cyanation Using Biaryl Phosphine Pd(0) Complexes

(2015) Hong Geun Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rational Ligand Design for the Arylation of Hindered Primary Amines Guided by Reaction Progress Kinetic Analysis

(2015) Paula Ruiz-Castillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dosage delivery of sensitive reagents enables glove-box-free synthesis

(2015) Aaron C. Sather et al.   NATURE

A Modular, Air-Stable Nickel Precatalyst

(2015) Jason D. Shields et al.   ORGANIC LETTERS

Mild Palladium-Catalyzed Cyanation of (Hetero)aryl Halides and Triflates in Aqueous Media

(2015) Daniel T. Cohen et al.   ORGANIC LETTERS

Air-Stable Dinuclear Iodine-Bridged Pd(I) Complex - Catalyst, Precursor, or Parasite? The Additive Decides. Systematic Nucleophile-Activity Study and Application as Precatalyst in Cross-Coupling

(2015) Marialuisa Aufiero et al.   ORGANOMETALLICS

Reactions of the 21st Century: Two Decades of Innovative Catalyst Design for Palladium-Catalyzed Cross-Couplings

(2015) Peter G. Gildner et al.   ORGANOMETALLICS

Synthesis of an Intermediate of Nafoxidine via Nickel-Catalyzed Ketone Arylation

(2015) Steven Nolan et al.   SYNTHESIS-STUTTGART

Understanding Precatalyst Activation in Cross-Coupling Reactions: Alcohol Facilitated Reduction from Pd(II) to Pd(0) in Precatalysts of the Type (η3-allyl)Pd(L)(Cl) and (η3-indenyl)Pd(L)(Cl)

(2015) Patrick R. Melvin et al.   ACS Catalysis

Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling

(2015) Javier Magano et al.   ACS Catalysis

A Meeting of Metals—A Joint Virtual Issue between Organometallics and ACS Catalysis on First-Row Transition Metal Complexes

(2015) Paul J. Chirik et al.   ACS Catalysis

Design of a Versatile and Improved Precatalyst Scaffold for Palladium-Catalyzed Cross-Coupling: (η3-1-tBu-indenyl)2(μ-Cl)2Pd2

(2015) Patrick R. Melvin et al.   ACS Catalysis

Nickel: The “Spirited Horse” of Transition Metal Catalysis

(2015) Valentine P. Ananikov   ACS Catalysis

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents and Identification of Selective Anti-Breast-Cancer Agents

(2014) Ivelina M. Yonova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Room-Temperature Amination of Deactivated Aniline and Aryl Halide Partners with Carbonate Base Using a Pd-PEPPSI-IPentCl-o-Picoline Catalyst

(2014) Matthew Pompeo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, mechanism of formation, and catalytic activity of Xantphos nickel π-complexes

(2014) Nicholas D. Staudaher et al.   CHEMICAL COMMUNICATIONS

Nickel-catalysed carboxylation of organoboronates

(2014) Yusuke Makida et al.   CHEMICAL COMMUNICATIONS

[(IPent)PdCl2(morpholine)]: A Readily Activated Precatalyst for Room-Temperature, Additive-Free Carbon-Sulfur Coupling

(2014) Jennifer L. Farmer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient C-N and C-S Bond Formation Using the Highly Active [Ni(allyl)Cl(IPr*OMe)] Precatalyst

(2014) Anthony R. Martin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Structure and reactivity of [(L·Pd) n ·(1,5-cyclooctadiene)] ( n = 1–2) complexes bearing biaryl phosphine ligands

(2014) Hong Geun Lee et al.   INORGANICA CHIMICA ACTA

Kinetic and Computational Studies on Pd(I) Dimer-Mediated Halogen Exchange of Aryl Iodides

(2014) Indrek Kalvet et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Hydroxylation of Aryl and Heteroaryl Halides Enabled by the Use of a Palladacycle Precatalyst

(2014) Chi Wai Cheung et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Substituted 2-Aminobiphenylpalladium Methanesulfonate Precatalysts and Their Use in C–C and C–N Cross-Couplings

(2014) Nicholas C. Bruno et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides

(2014) Hong Geun Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insight into the Efficiency of Cinnamyl-Supported Precatalysts for the Suzuki–Miyaura Reaction: Observation of Pd(I) Dimers with Bridging Allyl Ligands During Catalysis

(2014) Damian P. Hruszkewycz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiospecific Intramolecular Heck Reactions of Secondary Benzylic Ethers

(2014) Michael R. Harris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Cross-Coupling Reactions of Aryl-Substituted Tetrahydrofurans, Tetrahydropyrans, and Lactones

(2014) Emily J. Tollefson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst

(2014) Stig D. Friis et al.   ORGANIC LETTERS

Air-Stable Nickel Precatalysts for Fast and Quantitative Cross-Coupling of Aryl Sulfamates with Aryl Neopentylglycolboronates at Room Temperature

(2014) Ryan L. Jezorek et al.   ORGANIC LETTERS

Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides

(2014) Yang Yang et al.   ORGANIC LETTERS

Statistical DoE Approach to the Removal of Palladium from Active Pharmaceutical Ingredients (APIs) by Functionalized Silica Adsorbents

(2014) Jan Recho et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

[Pd(IPr*OMe)(cin)Cl] (cin = Cinnamyl): A Versatile Catalyst for C–N and C–C Bond Formation

(2014) Gulluzar Bastug et al.   ORGANOMETALLICS

Effect of 2-Substituents on Allyl-Supported Precatalysts for the Suzuki–Miyaura Reaction: Relating Catalytic Efficiency to the Stability of Palladium(I) Bridging Allyl Dimers

(2014) Damian P. Hruszkewycz et al.   ORGANOMETALLICS

A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

(2014) Eric A. Standley et al.   ORGANOMETALLICS

Merging photoredox with nickel catalysis: Coupling of  -carboxyl sp3-carbons with aryl halides

(2014) Z. Zuo et al.   SCIENCE

Nickel-catalyzed cross-coupling of carboxylic anhydrides with arylboronic acids

(2014) Qiang Chen et al.   RSC Advances

Palladium-Catalyzed Completely Linear-Selective Negishi Cross-Coupling of Allylzinc Halides with Aryl and Vinyl Electrophiles

(2013) Yang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General, Practical Palladium-Catalyzed Cyanation of (Hetero)Aryl Chlorides and Bromides

(2013) Todd D. Senecal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts

(2013) Fu-She Han   CHEMICAL SOCIETY REVIEWS

Sulfination by Using Pd-PEPPSI Complexes: Studies into Precatalyst Activation, Cationic and Solvent Effects and the Role of Butoxide Base

(2013) Mahmoud Sayah et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbon–Sulfur Bond Formation Catalyzed by [Pd(IPr*OMe)(cin)Cl] (cin = cinnamyl)

(2013) Gulluzar Bastug et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B2(OH)4]

(2013) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation

(2013) M. Alexander Düfert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations

(2013) Susan L. Zultanski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Direct Carboxylation of Benzyl Halides with CO2

(2013) Thierry León et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simplifying Nickel(0) Catalysis: An Air-Stable Nickel Precatalyst for the Internally Selective Benzylation of Terminal Alkenes

(2013) Eric A. Standley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Carboxylation of C(sp2)– and C(sp3)–O Bonds with CO2

(2013) Arkaitz Correa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates

(2013) Nathaniel H. Park et al.   ORGANIC LETTERS

Mild and General Palladium-Catalyzed Synthesis of Methyl Aryl Ethers Enabled by the Use of a Palladacycle Precatalyst

(2013) Chi Wai Cheung et al.   ORGANIC LETTERS

Synthesis of Solid 2-Pyridylzinc Reagents and Their Application in Negishi Reactions

(2013) James R. Colombe et al.   ORGANIC LETTERS

Nickel-Catalyzed Suzuki–Miyaura Couplings in Green Solvents

(2013) Stephen D. Ramgren et al.   ORGANIC LETTERS

An Improved Catalyst System for the Pd-Catalyzed Fluorination of (Hetero)Aryl Triflates

(2013) Hong Geun Lee et al.   ORGANIC LETTERS

Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands

(2013) Nicholas C. Bruno et al.   ORGANIC LETTERS

Enhanced Activity of [Ni(NHC)CpCl] Complexes in Arylamination Catalysis

(2013) Anthony R. Martin et al.   ORGANOMETALLICS

Dinuclear Pd(i) complexes—solely precatalysts? Demonstration of direct reactivity of a Pd(i) dimer with an aryl iodide

(2013) Karl J. Bonney et al.   Chemical Science

Direct S-Arylation of Unactivated Arylsulfoxides Using [Pd(IPr*)(cin)Cl]

(2013) Frédéric Izquierdo et al.   ACS Catalysis

An Efficient Palladium-NHC (NHC=N-Heterocyclic Carbene) and Aryl Amination Pre-Catalyst: [Pd(IPr*)(cinnamyl)Cl]

(2012) Anthony Chartoire et al.   ADVANCED SYNTHESIS & CATALYSIS

Pd-PEPPSI-IPentCl: A Highly Effective Catalyst for the Selective Cross-Coupling of Secondary Organozinc Reagents

(2012) Matthew Pompeo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions

(2012) Cory Valente et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Reactive, Single-Component Nickel Catalyst Precursor for Suzuki-Miyuara Cross-Coupling of Heteroaryl Boronic Acids with Heteroaryl Halides

(2012) Shaozhong Ge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-PEPPSI-IPentCl: An Effective Catalyst for the Preparation of Triarylamines

(2012) Ka Hou Hoi et al.   CHEMISTRY-A EUROPEAN JOURNAL

[Pd(IPr*)(cinnamyl)Cl]: An Efficient Pre-catalyst for the Preparation of Tetra-ortho-substituted Biaryls by Suzuki-Miyaura Cross-Coupling

(2012) Anthony Chartoire et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Efficient Suzuki-Miyaura Coupling of Aryl Sulfamates and Boronic Acids Catalyzed by NiCl2(dppp)

(2012) Guo-Jun Chen et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

trans-Chloro(1-Naphthyl)bis(triphenylphosphine)nickel(II)/PCy3 Catalyzed Cross-Coupling of Aryl and Heteroaryl Neopentylglycolboronates with Aryl and Heteroaryl Mesylates and Sulfamates at Room Temperature

(2012) Pawaret Leowanawat et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, To Generate Carbon–Boron Bonds

(2012) Alexander S. Dudnik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A

(2012) Kazuma Amaike et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni- and Fe-Catalyzed Cross-Coupling Reactions of Phenol Derivatives

(2012) Tehetena Mesganaw et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2 in the Amination of Aryl Tosylates

(2012) María José Iglesias et al.   ORGANOMETALLICS

Design and preparation of new palladium precatalysts for C–C and C–N cross-coupling reactions

(2012) Nicholas C. Bruno et al.   Chemical Science

Development of Preformed Pd Catalysts for Cross-Coupling Reactions, Beyond the 2010 Nobel Prize

(2012) Hongbo Li et al.   ACS Catalysis

A Highly Practical and Reliable Nickel Catalyst for Suzuki-Miyaura Coupling of Aryl Halides

(2011) Yu-Long Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Efficient Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates Catalyzed by Stable, Cost-Effective [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride [Ni(dppp)Cl2] with only 1 mol% Loading

(2011) Han Gao et al.   ADVANCED SYNTHESIS & CATALYSIS

Arylation of α-pivaloxyl ketones with arylboronic reagents via Ni-catalyzed sp3 C–O activation

(2011) Kun Huang et al.   CHEMICAL COMMUNICATIONS

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Cross-coupling in flow

(2011) Timothy Noël et al.   CHEMICAL SOCIETY REVIEWS

Amination with PdNHC Complexes: Rate and Computational Studies Involving Substituted Aniline Substrates

(2011) Ka Hou Hoi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Cross-Coupling of Phenols and Arylboronic Acids Through an In Situ Phenol Activation Mediated by PyBroP

(2011) Guo-Jun Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Room-Temperature Nickel-Catalysed Suzuki-Miyaura Reactions of Aryl Sulfonates/Halides with Arylboronic Acids

(2011) Xin-Heng Fan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Cross-Coupling of Aryl Phosphates with Arylboronic Acids

(2011) Hu Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Air-Stable Pd(R-allyl)LCl (L= Q-Phos, P(t-Bu)3, etc.) Systems for C–C/N Couplings: Insight into the Structure–Activity Relationship and Catalyst Activation Pathway

(2011) Carin C. C. Johansson Seechurn et al.   JOURNAL OF ORGANIC CHEMISTRY

Reactivity and Stability of Dinuclear Pd(I) Complexes: Studies on the Active Catalytic Species, Insights into Precatalyst Activation and Deactivation, and Application in Highly Selective Cross-Coupling Reactions

(2011) Fabien Proutiere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Suzuki−Miyaura Cross-Coupling of Aryl Carbamates and Sulfamates: Experimental and Computational Studies

(2011) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene Bound Nickel(I) Complexes and Their Roles in Catalysis

(2011) Kainan Zhang et al.   ORGANOMETALLICS

Carbon Halide Bond Activation of Benzyl Chloride and Benzyl Bromide Using An NHC-Stabilized Nickel(0) Complex

(2011) Thomas Zell et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

(2010) Brad M. Rosen et al.   CHEMICAL REVIEWS

Construction of Polysubstituted Olefins through Ni-Catalyzed Direct Activation of Alkenyl CO of Substituted Alkenyl Acetates

(2010) Chang-Liang Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

NiII-(σ-Aryl) Complex Catalyzed Suzuki Reaction of Aryl Tosylates with Arylboronic Acids

(2010) Xin-Heng Fan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis and X-ray Structure Determination of Highly Active Pd(II), Pd(I), and Pd(0) Complexes of Di(tert-butyl)neopentylphosphine (DTBNpP) in the Arylation of Amines and Ketones

(2010) Lensey L. Hill et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Efficient and Practical Suzuki−Miyaura Coupling of Alkenyl and Aryl Carbamates with Aryl Boroxines

(2010) Li Xu et al.   ORGANIC LETTERS

Suzuki−Miyaura Coupling of Aryl Carbamates, Carbonates, and Sulfamates

(2009) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N,N-DiethylO-Carbamate: Directed Metalation Group and Orthogonal Suzuki−Miyaura Cross-Coupling Partner

(2009) Aurora Antoft-Finch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon−Carbon Formation via Ni-Catalyzed Suzuki−Miyaura Coupling through C−CN Bond Cleavage of Aryl Nitrile

(2009) Da-Gang Yu et al.   ORGANIC LETTERS

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)3and PCy3as Ligands

(2008) Gregory C. Fu   ACCOUNTS OF CHEMICAL RESEARCH

Well-Defined N-Heterocyclic Carbenes−Palladium(II) Precatalysts for Cross-Coupling Reactions

(2008) Nicolas Marion et al.   ACCOUNTS OF CHEMICAL RESEARCH

Surveying Sterically Demanding N-Heterocyclic Carbene Ligands with Restricted Flexibility for Palladium-catalyzed Cross-Coupling Reactions

(2008) Sebastian Würtz et al.   ACCOUNTS OF CHEMICAL RESEARCH

Methylation of arenes via Ni-catalyzed aryl C–O/F activation

(2008) Bing-Tao Guan et al.   CHEMICAL COMMUNICATIONS

Nickel-Catalyzed Amination of Aryl Tosylates

(2008) Cai-Yan Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

A New Class of Easily Activated Palladium Precatalysts for Facile C−N Cross-Coupling Reactions and the Low Temperature Oxidative Addition of Aryl Chlorides

(2008) Mark R. Biscoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biaryl Construction via Ni-Catalyzed C−O Activation of Phenolic Carboxylates

(2008) Bing-Tao Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Benzylic Alkylation via Ni-Catalyzed Selective Benzylic sp3C−O Activation

(2008) Bing-Tao Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequential Ni-Catalyzed Borylation and Cross-Coupling of Aryl Halides via in Situ Prepared Neopentylglycolborane

(2008) Brad M. Rosen et al.   ORGANIC LETTERS

Pd-NHC (PEPPSI) Complexes: Synthetic Utility and Computational Studies into Their Reactivity

(2008) Michael Organ et al.   SYNTHESIS-STUTTGART