Photoinduced Transition-Metal-Free Chan–Evans–Lam-Type Coupling: Dual Photoexcitation Mode with Halide Anion Effect

Access to β-Lactams via Iron-Catalyzed Olefin Oxyamidation Enabled by the π-Accepting Phthalocyanine Ligand

(2022) Jeonguk Kweon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroamination, Aminoboration, and Carboamination with Electrophilic Amination Reagents: Umpolung-Enabled Regio- and Stereoselective Synthesis of N-Containing Molecules from Alkenes and Alkynes

(2022) Koji Hirano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Origin of Rh-Catalyzed Selective Ring-Opening Amidation of Substituted Cyclopropanols to Access β2-Amino Ketones

(2022) Minhan Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C2-Selective, Functional-Group-Divergent Amination of Pyrimidines by Enthalpy-Controlled Nucleophilic Functionalization

(2022) Won Seok Ham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlled Relay Process to Access N-Centered Radicals for Catalyst-free Amidation of Aldehydes under Visible Light

(2021) Wongyu Lee et al.   Chem

Tuning Orbital Symmetry of Iridium Nitrenoid Enables Catalytic Diastereo- and Enantioselective Alkene Difunctionalizations

(2021) Suhyeon Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism-Guided Development of Transition-Metal-Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source

(2021) Seung Youn Hong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Electrophilic Aminating Agents in Total Synthesis

(2021) Lauren O'Neil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Interweaving Visible‐Light and Iron Catalysis for Nitrene Formation and Transformation with Dioxazolones

(2021) Jing‐Jing Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Access to Spirolactams via Nitrenoid Transfer Enabled by Enhanced Noncovalent Interactions

(2021) Euijae Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging NiH Catalysis and Inner-Sphere Metal-Nitrenoid Transfer for Hydroamidation of Alkynes

(2021) Xiang Lyu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrene-mediated intermolecular N–N coupling for efficient synthesis of hydrazides

(2021) Hao Wang et al.   Nature Chemistry

Thioether-Directed NiH-Catalyzed Remote γ-C(sp3)–H Hydroamidation of Alkenes by 1,4,2-Dioxazol-5-ones

(2021) Bingnan Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A cross-dehydrogenative C(sp3)−H heteroarylation via photo-induced catalytic chlorine radical generation

(2021) Chia-Yu Huang et al.   Nature Communications

Rh(III)-Catalyzed Three-Component Syn-Carboamination of Alkenes Using Arylboronic Acids and Dioxazolones

(2021) Sumin Lee et al.   ACS Catalysis

Diastereoselective Three-Component 3,4-Amino Oxygenation of 1,3-Dienes Catalyzed by a Cationic Heptamethylindenyl Rhodium(III) Complex

(2021) Finn Burg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Promoted Iron-Catalyzed N-Arylation of Dioxazolones with Arylboronic Acids

(2021) Jing-Jing Tang et al.   ACS Catalysis

Light-Driven N-Heterocyclic Carbene Catalysis Using Alkylborates

(2021) Yukiya Sato et al.   ACS Catalysis

Visible-Light-Driven Strain-Increase Ring Contraction Allows the Synthesis of Cyclobutyl Boronic Esters

(2020) Raffael Davenport et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Improved PIII/PV═O-Catalyzed Reductive C–N Coupling of Nitroaromatics and Boronic Acids by Mechanistic Differentiation of Rate- and Product-Determining Steps

(2020) Gen Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dioxazolones: Stable Substrates for the Catalytic Transfer of Acyl Nitrenes

(2020) Kaj M. van Vliet et al.   ACS Catalysis

A Review on the Latest Progress of Chan‐Lam Coupling Reaction

(2020) Jin‐Quan Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible-Light-Driven C4-Selective Alkylation of Pyridinium Derivatives with Alkyl Bromides

(2020) Sungwoo Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Designing a Planar Chiral Rhodium Indenyl Catalyst for Regio- and Enantioselective Allylic C–H Amidation

(2020) Caitlin M. B. Farr et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A site-selective amination catalyst discriminates between nearly identical C–H bonds of unsymmetrical disubstituted alkenes

(2020) Honghui Lei et al.   Nature Chemistry

Dual-Ligand-Enabled Ir(III)-Catalyzed Enantioselective C–H Amidation for the Synthesis of Chiral Sulfoxides

(2020) Wentan Liu et al.   ACS Catalysis

P(III)/P(V)-Catalyzed Methylamination of Arylboronic Acids and Esters: Reductive C–N Coupling with Nitromethane as a Methylamine Surrogate

(2020) Gen Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation

(2020) Wei Wang et al.   Chem

Photocatalytic decarboxylative alkylations mediated by triphenylphosphine and sodium iodide

(2019) Ming-Chen Fu et al.   SCIENCE

Ruthenium(II)-Catalyzed Enantioselective γ-Lactams Formation by Intramolecular C–H Amidation of 1,4,2-Dioxazol-5-ones

(2019) Qi Xing et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir-Catalyzed Intermolecular Branch-Selective Allylic C–H Amidation of Unactivated Terminal Olefins

(2019) Honghui Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular, Branch-Selective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C-H Amidation

(2019) Tobias Knecht et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox-Catalyzed Cyclobutane Synthesis by a Deboronative Radical Addition-Polar Cyclization Cascade

(2019) Chao Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid Assessment of the Reaction-Condition-Based Sensitivity of Chemical Transformations

(2019) Lena Pitzer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Addition to Strained σ-Bonds Enables the Stereocontrolled Synthesis of Cyclobutyl Boronic Esters

(2019) Mattia Silvi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Enantioselective C(sp3)–H Amidation Controlled by Attractive Noncovalent Interactions

(2019) Hao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III) and Ir(III)Cp* Complexes Provide Complementary Regioselectivity Profiles in Intermolecular Allylic C–H Amidation Reactions

(2019) Jacob S. Burman et al.   ACS Catalysis

The Buchwald-Hartwig Amination after 25 Years

(2019) Ruth Dorel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodefined Access to Lactams via Olefin Difunctionalization: Iridium Nitrenoids as a Motif of LUMO-Controlled Dipoles

(2019) Seung Youn Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Copper-Catalyzed Multicomponent Synthesis of N-Acyl Amidines via Acyl Nitrenes

(2019) Kaj M. van Vliet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Harnessing Secondary Coordination Sphere Interactions That Enable the Selective Amidation of Benzylic C–H Bonds

(2019) Hoimin Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Branched amines by catalytic 1,1-addition of C–H bonds and aminating agents to terminal alkenes

(2019) Soham Maity et al.   Nature Catalysis

Cobalt(III)-Catalyzed C−H Amidation of Dehydroalanine for the Site-Selective Structural Diversification of Thiostrepton

(2019) Ryan J. Scamp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Development and Recent Applications of the Chan–Lam Amination

(2019) Matthew J. West et al.   CHEMICAL REVIEWS

Non-C2-Symmetric Chiral-at-Ruthenium Catalyst for Highly Efficient Enantioselective Intramolecular C(sp3)–H Amidation

(2019) Zijun Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aminoazanium of DABCO: An Amination Reagent for Alkyl and Aryl Pinacol Boronates

(2019) Xingxing Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CuH-Catalyzed Asymmetric Hydroamidation of Vinylarenes

(2018) Yujing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal- and Base-Free Room-Temperature Amination of Organoboronic Acids with N -Alkyl Hydroxylamines

(2018) Hong-Bao Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

(2018) Seung Youn Hong et al.   SCIENCE

Ir(III)-Catalyzed Stereoselective Haloamidation of Alkynes Enabled by Ligand Participation

(2018) Seung Youn Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic applications and methodology development of Chan–Lam coupling: a review

(2018) Iqra Munir et al.   MOLECULAR DIVERSITY

Enantioselective C(sp3 )-H Amidation of Thioamides Catalyzed by a CobaltIII /Chiral Carboxylic Acid Hybrid System

(2018) Seiya Fukagawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Reductive C–N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV═O Catalysis

(2018) Trevor V. Nykaza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Photoredox with 1,2-Metallate Rearrangements: The Photochemical Alkylation of Vinyl Boronate Complexes

(2017) Mattia Silvi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanochemical Rhodium(III)-Catalyzed C–H Bond Amidation of Arenes with Dioxazolones under Solventless Conditions in a Ball Mill

(2017) Gary N. Hermann et al.   ACS Catalysis

Simple and Clean Photo-induced Methylation of Heteroarenes with MeOH

(2017) Wenbo Liu et al.   Chem

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

(2016) Paula Ruiz-Castillo et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed Electrophilic Amination: Application of O -Benzoylhydroxylamines in the Construction of the C−N Bond

(2016) Xu Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Why is the Ir(III)-Mediated Amido Transfer Much Faster Than the Rh(III)-Mediated Reaction? A Combined Experimental and Computational Study

(2016) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxazolinyl-Assisted C–H Amidation by Cobalt(III) Catalysis

(2016) Ruhuai Mei et al.   ACS Catalysis

Comparative Catalytic Activity of Group 9 [Cp*MIII] Complexes: Cobalt-Catalyzed CH Amidation of Arenes with Dioxazolones as Amidating Reagents

(2015) Juhyeon Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Access to Primary Anilines from Boronic Acids and a Common +NH2 Equivalent.

(2015) Samantha Voth et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Studies on the Rh(III)-Mediated Amido Transfer Process Leading to Robust C–H Amination with a New Type of Amidating Reagent

(2015) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterizing chain processes in visible light photoredox catalysis

(2015) Megan A. Cismesia et al.   Chemical Science

Light-Induced Ruthenium-Catalyzed Nitrene Transfer Reactions: A Photochemical Approach towards N-Acyl Sulfimides and Sulfoximines

(2014) Vincent Bizet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Robust and low cost uniform 15N-labeling of proteins expressed in Drosophila S2 cells and Spodoptera frugiperda Sf9 cells for NMR applications

(2014) Annalisa Meola et al.   JOURNAL OF STRUCTURAL BIOLOGY

Recent Advances in Electrophilic Amination Reactions

(2014) Corinne Gosmini et al.   SYNTHESIS-STUTTGART

Transition-Metal-Free Amination of Aryl boronic Acids and Their Derivatives

(2013) Vincent Coeffard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elusive Metal-Free Primary Amination of Arylboronic Acids: Synthetic Studies and Mechanism by Density Functional Theory

(2012) Chen Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Stereospecific Amination of Alkyl and Aryl Pinacol Boronates

(2012) Scott N. Mlynarski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free Electrophilic Amination of Arylboroxines

(2012) Qing Xiao et al.   ORGANIC LETTERS

Intramolecular Oxidative Diamination and Aminohydroxylation of Olefins under Metal-Free Conditions

(2012) Hyun Jin Kim et al.   ORGANIC LETTERS

A Metal-Free Route to 2-Aminooxazoles by Taking Advantage of the Unique Ring Opening of Benzoxazoles and Oxadiazoles with Secondary Amines

(2011) Jomy Joseph et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Medicinal Chemist’s Toolbox: An Analysis of Reactions Used in the Pursuit of Drug Candidates

(2011) Stephen D. Roughley et al.   JOURNAL OF MEDICINAL CHEMISTRY

Intramolecular Oxidative C−N Bond Formation for the Synthesis of Carbazoles: Comparison of Reactivity between the Copper-Catalyzed and Metal-Free Conditions

(2011) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp2and Benzylic sp3C–H Bond Imidation

(2011) Hyun Jin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free carbon–nitrogen bond-forming coupling reaction between arylboronic acids and organic azides

(2010) Lili Ou et al.   TETRAHEDRON LETTERS

Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis

(2008) Gwilherm Evano et al.   CHEMICAL REVIEWS

Photocatalytic Degradation of Dichloromethane by Chlorocuprate(II) Ions

(2008) Kevin J. Doyle et al.   INORGANIC CHEMISTRY