A site-selective amination catalyst discriminates between nearly identical C–H bonds of unsymmetrical disubstituted alkenes

Site-selective and versatile aromatic C−H functionalization by thianthrenation

(2019) Florian Berger et al.   NATURE

Ir-Catalyzed Intermolecular Branch-Selective Allylic C–H Amidation of Unactivated Terminal Olefins

(2019) Honghui Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular, Branch-Selective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C-H Amidation

(2019) Tobias Knecht et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(III) and Ir(III)Cp* Complexes Provide Complementary Regioselectivity Profiles in Intermolecular Allylic C–H Amidation Reactions

(2019) Jacob S. Burman et al.   ACS Catalysis

Site-specific allylic C–H bond functionalization with a copper-bound N-centred radical

(2019) Jiayuan Li et al.   NATURE

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Asymmetric Allylic C–H Alkylation via Palladium(II)/cis-ArSOX Catalysis

(2018) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C–H Activation Reactions: An Experimental and Computational Study

(2017) Tiffany Piou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic allylic oxidation of internal alkenes to a multifunctional chiral building block

(2017) Liela Bayeh et al.   NATURE

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

(2016) Tim Cernak et al.   CHEMICAL SOCIETY REVIEWS

Dirhodium-catalyzed C-H arene amination using hydroxylamines

(2016) M. P. Paudyal et al.   SCIENCE

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Metal-catalysed azidation of tertiary C–H bonds suitable for late-stage functionalization

(2015) Ankit Sharma et al.   NATURE

The direct arylation of allylic sp3 C–H bonds via organic and photoredox catalysis

(2015) James D. Cuthbertson et al.   NATURE

Site-selective arene C-H amination via photoredox catalysis

(2015) N. A. Romero et al.   SCIENCE

Site-Selective Aliphatic C–H Bromination Using N-Bromoamides and Visible Light

(2014) Valerie A. Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Regioselective Intermolecular Benzylic and Allylic CH Bond Amination

(2013) Yota Nishioka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Functionalization of Allylic C–H Bonds Following a Strategy of Functionalization and Diversification

(2013) Ankit Sharma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular C–H Amination of Complex Molecules: Insights into the Factors Governing the Selectivity

(2012) Camille Lescot et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective Allylic Amination of Unactivated Terminal Olefins via an Ene Reaction/[2,3]-Rearrangement

(2012) Hongli Bao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Intermolecular Aerobic Oxidative Amination of Terminal Alkenes: Efficient Synthesis of Linear Allylamine Derivatives

(2008) Guosheng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Intermolecular Linear Allylic C−H Amination via Heterobimetallic Catalysis

(2008) Sean A. Reed et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward a Synthetically Useful Stereoselective C−H Amination of Hydrocarbons

(2007) Chungen Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY