Asymmetric Ruthenium‐Catalyzed Hydroalkylation of Racemic Allylic Alcohols for the Synthesis of Chiral Amino Acid Derivatives

Hydrogen‐Borrowing Alkylation of 1,2‐Amino Alcohols in the Synthesis of Enantioenriched γ‐Aminobutyric Acids

(2021) Christopher J. J. Hall et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Hydrogenation to Transfer Hydrogenation to Hydrogen Auto-Transfer in Enantioselective Metal-Catalyzed Carbonyl Reductive Coupling: Past, Present, and Future

(2021) Catherine Gazolla Santana et al.   ACS Catalysis

Tandem Catalytic Indolization/Enantioconvergent Substitution of Alcohols by Borrowing Hydrogen to Access Tricyclic Indoles

(2021) Guoqiang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Diastereo‐ and Enantioconvergent Synthesis of Vicinal Diamines from Diols through Borrowing Hydrogen

(2021) Hui‐Jie Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Pd/Amine-Catalyzed Stereodivergent Hydroalkylation of 1,3-Dienes with Aldehydes: Reaction Development, Mechanism, and Stereochemical Origins

(2021) Hongfa Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Asymmetric Hydroalkylation of 1,3-Dienes: Access to Unnatural α-Amino Acid Derivatives Containing Vicinal Quaternary and Tertiary Stereogenic Centers

(2020) Zongpeng Zhang et al.   ORGANIC LETTERS

Enantioselective Construction of Quaternary Stereogenic Centers by the Addition of an Acyl Anion Equivalent to 1,3-Dienes

(2020) Nathan J. Adamson et al.   ORGANIC LETTERS

Asymmetric Guerbet Reaction to Access Chiral Alcohols

(2020) Kun Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Room‐Temperature Guerbet Reaction with Unprecedented Catalytic Efficiency and Enantioselectivity

(2020) Teng Wei Ng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Control of Absolute Stereochemistry in Transition‐Metal‐Catalyzed Hydrogen Borrowing Reactions

(2020) Timothy Kwok et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dynamic Kinetic Asymmetric Amination of Alcohols Assisted by Microwave: Stereoconvergent Access to Tetralin- and Indane-Derived Chiral Amines

(2020) Zi-Qiang Rong et al.   ACS Catalysis

Anti‐Markovnikov Hydroamination of Racemic Allylic Alcohols to Access Chiral γ‐Amino Alcohols

(2020) Ruirui Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-Catalyzed Regiodivergent and Stereoselective Hydroalkylation of Acyclic Branched Dienes with Unstabilized C(sp3) Nucleophiles

(2020) Wen Shao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of γ-Secondary Amino Alcohols via a Borrowing-Hydrogen Cascade

(2020) Yupeng Pan et al.   ORGANIC LETTERS

Recent advances in nickel-catalyzed reductive hydroalkylation and hydroarylation of electronically unbiased alkenes

(2020) Xiao-Xu Wang et al.   Science China-Chemistry

Enantioselective C(sp3)–C(sp3) cross-coupling of non-activated alkyl electrophiles via nickel hydride catalysis

(2020) Srikrishna Bera et al.   Nature Chemistry

Stereoconvergent, Redox-Neutral Access to Tetrahydroquinoxalines through Relay Epoxide Opening/Amination of Alcohols

(2019) Guangda Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Hydrogen Autotransfer: Diastereoselective N-Alkylation of Amines with Racemic Alcohols

(2019) Miao Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Synthesis of Cyclohexanes by Hydrogen Borrowing Annulations

(2019) Roly Armstrong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Coupling of 1,3-Dienes with Aldimine Esters Enabled by Synergistic Pd and Cu Catalysis

(2019) Qinglong Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Anti-Markovnikov Hydroamination and Hydroamidation of Allylic Alcohols

(2019) Wei Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Advances in One-Pot Synthesis through Borrowing Hydrogen Catalysis

(2018) Avelino Corma et al.   CHEMICAL REVIEWS

Diastereoselective Iridium-Catalyzed Amination of Biosourced Isohexides Through Borrowing Hydrogen Methodology

(2018) Maïwenn Jacolot et al.   JOURNAL OF ORGANIC CHEMISTRY

Remote C–H Hydroxylation by an α-Ketoglutarate-Dependent Dioxygenase Enables Efficient Chemoenzymatic Synthesis of Manzacidin C and Proline Analogs

(2018) Christian R. Zwick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intermolecular Pd-Catalyzed Hydroalkylation of Acyclic 1,3-Dienes with Activated Pronucleophiles

(2018) Nathan J. Adamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoarrayed 2,3-Disubstituted 1-Indanols via Ruthenium(II)-Catalyzed Dynamic Kinetic Resolution–Asymmetric Transfer Hydrogenation

(2018) Andrej Emanuel Cotman et al.   ORGANIC LETTERS

Enantioselective Synthesis of a γ-Secretase Modulator via Vinylogous Dynamic Kinetic Resolution

(2018) Neil A. Strotman et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel(0)-Catalyzed Hydroalkylation of 1,3-Dienes with Simple Ketones

(2018) Lei Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Addition of Cyclic Ketones to Unactivated Alkenes Enabled by Amine/Pd(II) Cooperative Catalysis

(2018) Hong-Cheng Shen et al.   ACS Catalysis

Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

(2017) Junwon Choi et al.   SCIENCE

(Enantio)selective Hydrogen Autotransfer: Ruthenium-Catalyzed Synthesis of Oxazolidin-2-ones from Urea and Diols

(2016) Miguel Peña-López et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges

(2016) Adrien Quintard et al.   CHEMICAL COMMUNICATIONS

Recent Achievements in Enantioselective Borrowing Hydrogen by the Combination of Iron- and Organocatalysis

(2016) Mylène Roudier et al.   CHIMIA

Recent Advances in Dynamic Kinetic Resolution by Chiral Bifunctional (Thio)urea- and Squaramide-Based Organocatalysts

(2016) Pan Li et al.   MOLECULES

γ-Sultam-cored N,N-ligands in the ruthenium(ii)-catalyzed asymmetric transfer hydrogenation of aryl ketones

(2016) Slavko Rast et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Triple Iron/Copper/Iminium Activation for the Efficient Redox Neutral Catalytic Enantioselective Functionalization of Allylic Alcohols

(2016) Mylène Roudier et al.   ACS Catalysis

Acid-Assisted Ru-Catalyzed Enantioselective Amination of 1,2-Diols through Borrowing Hydrogen

(2016) Li-Cheng Yang et al.   ACS Catalysis

Iron-catalyzed amination of alcohols assisted by Lewis acid

(2015) Hui-Jie Pan et al.   CHEMICAL COMMUNICATIONS

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

(2015) Alan H. Cherney et al.   CHEMICAL REVIEWS

Chemoenzymatic Dynamic Kinetic Resolution: A Powerful Tool for the Preparation of Enantiomerically Pure Alcohols and Amines

(2015) Oscar Verho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control

(2015) Matthew N. Grayson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Asymmetric Amination of Alcohols: From A Mixture of Four Isomers to Diastereo- and Enantiopure α-Branched Amines

(2015) Zi-Qiang Rong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–N Bond Formation between Alcohols and Amines Using an Iron Cyclopentadienone Catalyst

(2015) Andrew J. Rawlings et al.   ORGANIC LETTERS

Advances in Asymmetric Borrowing Hydrogen Catalysis

(2014) Dirk Hollmann   ChemSusChem

Tandem α-Alkylation/Asymmetric Transfer Hydrogenation of Acetophenones with Primary Alcohols

(2014) Oleksandr O. Kovalenko et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Development of ProPhenol Ligands for the Diastereo- and Enantioselective Synthesis of β-Hydroxy-α-amino Esters

(2014) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Iron catalysed direct alkylation of amines with alcohols

(2014) Tao Yan et al.   Nature Communications

An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols

(2013) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Amination of Alcohols by the Use of Borrowing Hydrogen Methodology: Cooperative Catalysis by Iridium and a Chiral Phosphoric Acid

(2013) Yao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Enantioselective Synthesis of β-Amino Alcohols from 1,2-Diols by “Borrowing Hydrogen”

(2013) Anggi Eka Putra et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

EcdGHK Are Three Tailoring Iron Oxygenases for Amino Acid Building Blocks of the Echinocandin Scaffold

(2013) Wei Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

l-Leucine 5-hydroxylase of Nostoc punctiforme is a novel type of Fe(II)/α-ketoglutarate-dependent dioxygenase that is useful as a biocatalyst

(2012) Makoto Hibi et al.   APPLIED MICROBIOLOGY AND BIOTECHNOLOGY

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

(2012) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

(2012) J. R. Zbieg et al.   SCIENCE

Organocatalyzed Dynamic Kinetic Resolution

(2011) Hélène Pellissier   ADVANCED SYNTHESIS & CATALYSIS

Chiral Ruthenabicyclic Complexes: Precatalysts for Rapid, Enantioselective, and Wide-Scope Hydrogenation of Ketones

(2011) Kazuhiko Matsumura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The first example of the direct asymmetric conjugate addition of aldehydes to a methylenemalonate promoted by an axially chiral amino diol catalyst

(2011) Taichi Kano et al.   Chemical Science

Application of asymmetric phase-transfer catalysis in the enantioselective synthesis of cis-5-substituted proline esters

(2010) Barry Lygo et al.   TETRAHEDRON

Ruthenium-CatalyzedN-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

(2009) M. Haniti S. A. Hamid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rate Enhancement of Phase Transfer Catalyzed Conjugate Additions by CsCl

(2009) Taichi Kano et al.   ORGANIC LETTERS

Racemization catalysts for the dynamic kinetic resolution of alcohols and amines

(2007) Yangsoo Ahn et al.   COORDINATION CHEMISTRY REVIEWS