Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges

(Enantio)selective Hydrogen Autotransfer: Ruthenium-Catalyzed Synthesis of Oxazolidin-2-ones from Urea and Diols

(2016) Miguel Peña-López et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Achievements in Enantioselective Borrowing Hydrogen by the Combination of Iron- and Organocatalysis

(2016) Mylène Roudier et al.   CHIMIA

Triple Iron/Copper/Iminium Activation for the Efficient Redox Neutral Catalytic Enantioselective Functionalization of Allylic Alcohols

(2016) Mylène Roudier et al.   ACS Catalysis

C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation

(2015) Fei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

The Golden Age of Transfer Hydrogenation

(2015) Dong Wang et al.   CHEMICAL REVIEWS

Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

(2015) Qin Yang et al.   CHEMICAL SOCIETY REVIEWS

Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation

(2015) Ryosuke Tsutsumi et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Step into an eco-Compatible Future: Iron- and Cobalt-catalyzed Borrowing Hydrogen Transformation

(2015) Adrien Quintard et al.   ChemSusChem

Ruthenium Catalyzed Diastereo- and Enantioselective Coupling of Propargyl Ethers with Alcohols: Siloxy-Crotylation via Hydride Shift Enabled Conversion of Alkynes to π-Allyls

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed C–C Coupling of a Simple Propargyl Ether with Primary Alcohols: Enantioselective Homoaldol Addition via Redox-Triggered (Z)-Siloxyallylation

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Ruthenium-Catalyzed Carbonyl Allylation via Alkyne–Alcohol C–C Bond-Forming Transfer Hydrogenation: Allene Hydrometalation vs Oxidative Coupling

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselective Iridium Catalyzed Coupling of Vinyl Aziridines with Alcohols: Site-Selective Modification of Unprotected Diols and Synthesis of Substituted Piperidines

(2015) Gang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Generation of Triketide Stereopolyads via Merged Redox-Construction Events: Total Synthesis of (+)-Zincophorin Methyl Ester

(2015) Zachary A. Kasun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Asymmetric Amination of Alcohols: From A Mixture of Four Isomers to Diastereo- and Enantiopure α-Branched Amines

(2015) Zi-Qiang Rong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemistry of the pheromones of mealybug and scale insects

(2015) Yunfan Zou et al.   NATURAL PRODUCT REPORTS

One-Pot Catalysis Using a Chiral Iridium Complex/Brønsted Base: Catalytic Asymmetric Synthesis of Catalponol

(2015) Takeyuki Suzuki et al.   ORGANIC LETTERS

Conversion of alcohols to enantiopure amines through dual-enzyme hydrogen-borrowing cascades

(2015) F. G. Mutti et al.   SCIENCE

Principles and Applications of Enantioselective Hydroformylation of Terminal Disubstituted Alkenes

(2015) Yuchao Deng et al.   ACS Catalysis

Iron Cyclopentadienone Complexes: Discovery, Properties, and Catalytic Reactivity

(2014) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective CH Functionalization of Alcohols by Redox-Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon

(2014) John M. Ketcham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-catalyzed asymmetric reductive allylation of aldehydes with allylic carbonates

(2014) Zhuozhen Tan et al.   CHEMICAL COMMUNICATIONS

Advances in Asymmetric Borrowing Hydrogen Catalysis

(2014) Dirk Hollmann   ChemSusChem

Tandem α-Alkylation/Asymmetric Transfer Hydrogenation of Acetophenones with Primary Alcohols

(2014) Oleksandr O. Kovalenko et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Redox-Economical Coupling of Alcohols and Alkynes to Form Allylic Alcohols

(2014) Kenichiro Nakai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Triggered C–C Coupling of Alcohols and Vinyl Epoxides: Diastereo- and Enantioselective Formation of All-Carbon Quaternary Centers via tert-(Hydroxy)-Prenylation

(2014) Jiajie Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Racemic Alcohols to Enantiopure Amines: Ru-Catalyzed Diastereoselective Amination

(2014) Nathan J. Oldenhuis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polyketide construction via hydrohydroxyalkylation and related alcohol C–H functionalizations: reinventing the chemistry of carbonyl addition

(2014) Anne-Marie R. Dechert-Schmitt et al.   NATURAL PRODUCT REPORTS

Preparation of Enantioenriched γ-Substituted Lactones via Asymmetric Transfer Hydrogenation of β-Azidocyclopropane Carboxylates Using the Ru-TsDPEN Complex

(2014) Yan Su et al.   ORGANIC LETTERS

Enantioselective Cascade Formal Reductive Insertion of Allylic Alcohols into the C(O)–C Bond of 1,3-Diketones: Ready Access to Synthetically Valuable 3-Alkylpentanol Units

(2014) Mylène Roudier et al.   ORGANIC LETTERS

Recent Advances in α-Alkylation Reactions using Alcohols with Hydrogen Borrowing Methodologies

(2014) Yasushi Obora   ACS Catalysis

An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols

(2013) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Amination of Alcohols by the Use of Borrowing Hydrogen Methodology: Cooperative Catalysis by Iridium and a Chiral Phosphoric Acid

(2013) Yao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Iron Catalysts for Asymmetric Synthesis

(2013) Kovuru Gopalaiah   CHEMICAL REVIEWS

Ruthenium-Catalyzed Enantioselective Synthesis of β-Amino Alcohols from 1,2-Diols by “Borrowing Hydrogen”

(2013) Anggi Eka Putra et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enzyme- and Ruthenium-Catalyzed Dynamic Kinetic Resolution of Functionalized Cyclic Allylic Alcohols

(2013) Richard Lihammar et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Ketone Hydroacylation Using Noyori’s Transfer Hydrogenation Catalyst

(2013) Stephen K. Murphy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

(2013) C. Gunanathan et al.   SCIENCE

Enantioselective Multicatalytic Synthesis of α-Benzyl-β-hydroxyindan-1-ones

(2013) Takeyuki Suzuki et al.   SYNTHESIS-STUTTGART

Regiodivergent reductive coupling of 2-substituted dienes to formaldehyde employing ruthenium or nickel catalyst: hydrohydroxymethylation via transfer hydrogenation

(2013) Alexander Köpfer et al.   Chemical Science

Dynamic Kinetic ResolutionviaHydrolase-Metal Combo Catalysis in Stereoselective Synthesis of Bioactive Compounds

(2012) Pilar Hoyos et al.   ADVANCED SYNTHESIS & CATALYSIS

Diastereo- and Enantioselective Iridium-Catalyzed Carbonyl Propargylation from the Alcohol or Aldehyde Oxidation Level: 1,3-Enynes as Allenylmetal Equivalents

(2012) Laina M. Geary et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Carbonyl Propargylation by Iridium-Catalyzed Transfer Hydrogenative Coupling of Alcohols and Propargyl Chlorides

(2012) Sang Kook Woo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient dynamic kinetic resolution of racemic secondary alcohols by a chemoenzymatic system using bifunctional iridium complexes with C–N chelate amido ligands

(2012) Yasuhiro Sato et al.   CHEMICAL COMMUNICATIONS

Consecutive iridium catalyzed C–C and C–H bond forming hydrogenations for the diastereo- and enantioselective synthesis of syn-3-fluoro-1-alcohols: C–H (2-fluoro)allylation of primary alcohols

(2012) Abbas Hassan et al.   CHEMICAL COMMUNICATIONS

Applied Hydroformylation

(2012) Robert Franke et al.   CHEMICAL REVIEWS

Combining transition metal catalysis and organocatalysis – an update

(2012) Zhenting Du et al.   CHEMICAL SOCIETY REVIEWS

Stereoselective Synthesis ofD- andL-Carbocyclic Nucleosides by Enzymatically Catalyzed Kinetic Resolution

(2012) Miriam Mahler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Evolution of asymmetric organocatalysis: multi- and retrocatalysis

(2012) Raffael C. Wende et al.   GREEN CHEMISTRY

Enantioselective Conversion of Primary Alcohols to α-exo-Methylene γ-Butyrolactones via Iridium-Catalyzed C–C Bond-Forming Transfer Hydrogenation: 2-(Alkoxycarbonyl)allylation

(2012) T. Patrick Montgomery et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Resolution of α-Keto Esters via Asymmetric Transfer Hydrogenation

(2012) Kimberly M. Steward et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nonenzymatic Dynamic Kinetic Resolution of Secondary Alcohols via Enantioselective Acylation: Synthetic and Mechanistic Studies

(2012) Sarah Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

(2012) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The progression of chiral anions from concepts to applications in asymmetric catalysis

(2012) Robert J. Phipps et al.   Nature Chemistry

Enantioselective Route to Ketones and Lactones from Exocyclic Allylic Alcohols via Metal and Enzyme Catalysis

(2012) Madeleine C. Warner et al.   ORGANIC LETTERS

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

(2012) J. R. Zbieg et al.   SCIENCE

Asymmetric total synthesis of 5′-epi-paecilomycin-F

(2012) Nandan Jana et al.   TETRAHEDRON-ASYMMETRY

Synergistic catalysis: A powerful synthetic strategy for new reaction development

(2012) Anna E. Allen et al.   Chemical Science

Iridium-Catalyzed anti-Diastereo- and Enantioselective Carbonyl (α-Trifluoromethyl)allylation from the Alcohol or Aldehyde Oxidation Level

(2011) Xin Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent Regioselectivity in the Synthesis of Trisubstituted Allylic Alcohols by Nickel- and Ruthenium-Catalyzed Alkyne Hydrohydroxymethylation with Formaldehyde

(2011) Cory C. Bausch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Iridium-Catalyzed Vinylogous Reformatsky-Aldol Reaction from the Alcohol Oxidation Level: Linear Regioselectivity by Way of Carbon-Bound Enolates

(2011) Abbas Hassan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis

(2011) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Catalytic Amination of Alcohols

(2011) Sebastian Bähn et al.   ChemCatChem

Catalytic enantioselective Grignard Nozaki–Hiyama methallylation from the alcohol oxidation level: chloride compensates for π-complex instability

(2011) Abbas Hassan et al.   CHEMICAL COMMUNICATIONS

Homogeneous catalysis using iron complexes: recent developments in selective reductions

(2011) Kathrin Junge et al.   CHEMICAL COMMUNICATIONS

Dynamic Kinetic Resolution of a Wide Range of Secondary Alcohols: Cooperation of Dicarbonylchlorido(pentabenzylcyclopentadienyl)ruthenium and CAL-B

(2011) Mari Päiviö et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Chemoenzymatic Dynamic Kinetic Resolution Approach to Enantiomerically Pure (R)- and (S)-Duloxetine

(2011) Annika Träff et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of β-Substituted Cyclic Ketones via Cobalt-Catalyzed Asymmetric Reductive Coupling of Alkynes with Alkenes

(2011) Chu-Hung Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Generation of Acyclic Polypropionate StereopolyadsviaDouble Diastereo- and Enantioselective Iridium-Catalyzed Crotylation of 1,3-Diols: Beyond Stepwise Carbonyl Addition in Polyketide Construction

(2011) Xin Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Bryostatin 7viaC–C Bond-Forming Hydrogenation

(2011) Yu Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polarity Inversion of Donor–Acceptor Cyclopropanes: Disubstituted δ-Lactones via Enantioselective Iridium Catalysis

(2011) Joseph Moran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselective Ruthenium-Catalyzed Hydrohydroxyalkylation of 2-Silyl-butadienes: Carbonylsyn-Crotylation from the Alcohol Oxidation Level

(2011) Jason R. Zbieg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric catalysis using iron complexes – ‘Ruthenium Lite’?

(2011) Muftah Darwish et al.   Catalysis Science & Technology

Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst

(2010) Brian L. Conley et al.   CHEMICAL REVIEWS

Enantioselective Synthesis of (R)-Bufuralol via Dynamic Kinetic Resolution in the Key Step

(2010) Eric V. Johnston et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoactivated Racemization Catalyst for Dynamic Kinetic Resolution of Secondary Alcohols

(2010) Youngshil Do et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzedanti-Diastereo- and Enantioselective Carbonyl (Trimethylsilyl)allylation from the Alcohol or Aldehyde Oxidation Level

(2010) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Nickel-Catalyzed Reductive Coupling of Alkynes and Imines

(2010) Chang-Yue Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of (+)-Roxaticin via C−C Bond Forming Transfer Hydrogenation: A Departure from Stoichiometric Chiral Reagents, Auxiliaries, and Premetalated Nucleophiles in Polyketide Construction

(2010) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

anti-Diastereo- and Enantioselective Carbonyl (Hydroxymethyl)allylation from the Alcohol or Aldehyde Oxidation Level: Allyl Carbonates as Allylmetal Surrogates

(2010) Yong Jian Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselectiveanti-Alkoxyallylation Employing Allylicgem-Dicarboxylates as Allyl Donors via Iridium-Catalyzed Transfer Hydrogenation

(2010) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Give and Take of Alcohol Activation

(2010) A. J. A. Watson et al.   SCIENCE

Highlights of the Rh-catalysed asymmetric hydroformylation of alkenes using phosphorus donor ligands

(2010) Aitor Gual et al.   TETRAHEDRON-ASYMMETRY

Enantioselective Allylation, Crotylation, and Reverse Prenylation of Substituted Isatins: Iridium-Catalyzed CC Bond-Forming Transfer Hydrogenation

(2009) Junji Itoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,n-Glycols as Dialdehyde Equivalents in Iridium-Catalyzed Enantioselective Carbonyl Allylation and Iterative Two-Directional Assembly of 1,3-Polyols

(2009) Yu Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox Economy in Organic Synthesis

(2009) Noah Z. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Autotransfer in theN-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

(2009) Gabriela Guillena et al.   CHEMICAL REVIEWS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

The economies of synthesis

(2009) Timothy Newhouse et al.   CHEMICAL SOCIETY REVIEWS

Chemoenzymatic Dynamic Kinetic Resolution of Alcohols and Amines

(2009) Jin Hee Lee et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enzyme- and Ruthenium-Catalyzed Dynamic Kinetic Asymmetric Transformation of 1,5-Diols. Application to the Synthesis of (+)-Solenopsin A

(2009) Karin Leijondahl et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of a Neonicotinoide Pesticide Derivative via Chemoenzymatic Dynamic Kinetic Resolution

(2009) Patrik Krumlinde et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Carbonyl Reverse Prenylation from the Alcohol or Aldehyde Oxidation Level Employing 1,1-Dimethylallene as the Prenyl Donor

(2009) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometallated Iridium Catalyst: α-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents

(2009) In Su Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed, Hydrogen-Mediated Reductive Cyclization of 1,6-Enynes and Diynes: Evidence for Bis(imino)pyridine Ligand Participation

(2009) Kevin T. Sylvester et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Synthesis of Chiral Phthalides by Efficient Reductive Cyclization of 2-Acylarylcarboxylates under Aqueous Transfer Hydrogenation Conditions

(2009) Bo Zhang et al.   ORGANIC LETTERS

Elongation of 1,3-Polyols via Iterative Catalyst-Directed Carbonyl Allylation from the Alcohol Oxidation Level

(2009) Abbas Hassan et al.   ORGANIC LETTERS

Enantioselective Syntheses of Both Enantiomers of Noranabasamine

(2009) Lei Miao et al.   ORGANIC LETTERS

Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

(2008) John F. Bower et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal catalysed reactions of alcohols using borrowing hydrogen methodology

(2008) Tracy D. Nixon et al.   DALTON TRANSACTIONS

Diastereo- and Enantioselective Hydrogenative Aldol Coupling of Vinyl Ketones:  Design of Effective Monodentate TADDOL-Like Phosphonite Ligands

(2008) Cisco Bee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Enantioselective Alkylative Coupling of Alkynes and Aldehydes: Synthesis of Chiral Allylic Alcohols with Tetrasubstituted Olefins

(2008) Yun Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

(2008) In Su Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Resolution of Racemic β-Haloalcohols: Direct Access to Enantioenriched Epoxides

(2008) Robert M. Haak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A convenient route to chiral γ-lactones via asymmetric hydrogenation of γ-ketoesters using the RuCl3–BINAP–HCl catalytic system

(2008) Eugenia V. Starodubtseva et al.   TETRAHEDRON