Catalytic Diastereo‐ and Enantioconvergent Synthesis of Vicinal Diamines from Diols through Borrowing Hydrogen

Asymmetric Guerbet Reaction to Access Chiral Alcohols

(2020) Kun Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Room‐Temperature Guerbet Reaction with Unprecedented Catalytic Efficiency and Enantioselectivity

(2020) Teng Wei Ng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Control of Absolute Stereochemistry in Transition‐Metal‐Catalyzed Hydrogen Borrowing Reactions

(2020) Timothy Kwok et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron

(2020) Mingkang Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Asymmetric Amination of Alcohols Assisted by Microwave: Stereoconvergent Access to Tetralin- and Indane-Derived Chiral Amines

(2020) Zi-Qiang Rong et al.   ACS Catalysis

Rhodium-Catalyzed Asymmetric Hydroamination of Allyl Amines

(2019) Evan P. Vanable et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Enantioselective Synthesis of 1,2-Diamine Derivatives by Copper-Catalyzed Hydroamination

(2019) Saki Ichikawa et al.   ORGANIC LETTERS

Stereoconvergent, Redox-Neutral Access to Tetrahydroquinoxalines through Relay Epoxide Opening/Amination of Alcohols

(2019) Guangda Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Hydrogen Autotransfer: Diastereoselective N-Alkylation of Amines with Racemic Alcohols

(2019) Miao Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Promoting Intermolecular C–N Bond Formation under the Auspices of Iodine(III)

(2018) Kilian Muñiz   ACCOUNTS OF CHEMICAL RESEARCH

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

(2018) Michael Holmes et al.   CHEMICAL REVIEWS

Advances in One-Pot Synthesis through Borrowing Hydrogen Catalysis

(2018) Avelino Corma et al.   CHEMICAL REVIEWS

3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer

(2018) Torsten Irrgang et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Enantioconvergent Isomerization of Homoallylic and Bishomoallylic Secondary Alcohols

(2018) Rui-Zhi Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Enantioselective Isomerization of Secondary Allylic Alcohols

(2017) Tang-Lin Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Diamination of Styrenes

(2017) Kilian Muñiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Radical Diamination of Alkenes

(2017) Fu-Li Wang et al.   Chem

(Enantio)selective Hydrogen Autotransfer: Ruthenium-Catalyzed Synthesis of Oxazolidin-2-ones from Urea and Diols

(2016) Miguel Peña-López et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Chiral Vicinal Diamines by Silver(I)-Catalyzed Enantioselective Aminolysis of N-Tosylaziridines

(2016) Zhuo Chai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges

(2016) Adrien Quintard et al.   CHEMICAL COMMUNICATIONS

Investigation and Application of Amphoteric α-Amino Aldehyde: An in Situ Generated Species Based on Heyns Rearrangement

(2016) Guangxun Li et al.   ORGANIC LETTERS

Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition

(2016) Khoa D. Nguyen et al.   SCIENCE

Acid-Assisted Ru-Catalyzed Enantioselective Amination of 1,2-Diols through Borrowing Hydrogen

(2016) Li-Cheng Yang et al.   ACS Catalysis

Pushing the Limits of Aminocatalysis: Enantioselective Transformations of α-Branched β-Ketocarbonyls and Vinyl Ketones by Chiral Primary Amines

(2015) Long Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed Hydrogen-Transfer Annulations: Access to Heterocyclic Scaffolds

(2015) Avanashiappan Nandakumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Mannich-Type Reaction ofN-Alkylidene-α-Aminoacetonitrile with Ketimines

(2015) Shaoquan Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile In Situ GeneratedN-Boc-Imines: Application to Phase-Transfer-Catalyzed Asymmetric Mannich-Type Reactions

(2015) Taichi Kano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation

(2015) Fei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

(2015) Qin Yang et al.   CHEMICAL SOCIETY REVIEWS

Chemoenzymatic Dynamic Kinetic Resolution: A Powerful Tool for the Preparation of Enantiomerically Pure Alcohols and Amines

(2015) Oscar Verho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Asymmetric Amination of Alcohols: From A Mixture of Four Isomers to Diastereo- and Enantiopure α-Branched Amines

(2015) Zi-Qiang Rong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(II)-Catalyzed Enantioselective Intramolecular Cyclization of N-Alkenylureas

(2015) Shaomin Fu et al.   ORGANIC LETTERS

A Survey of the Borrowing Hydrogen Approach to the Synthesis of some Pharmaceutically Relevant Intermediates

(2015) John Leonard et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Conversion of alcohols to enantiopure amines through dual-enzyme hydrogen-borrowing cascades

(2015) F. G. Mutti et al.   SCIENCE

Catalytic Diamination of Olefins via N–N Bond Activation

(2014) Yingguang Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Enantioselective CH Functionalization of Alcohols by Redox-Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon

(2014) John M. Ketcham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Diamination with Novel Chiral Hypervalent Iodine Catalysts

(2014) Pushpak Mizar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Advances in Asymmetric Borrowing Hydrogen Catalysis

(2014) Dirk Hollmann   ChemSusChem

From Racemic Alcohols to Enantiopure Amines: Ru-Catalyzed Diastereoselective Amination

(2014) Nathan J. Oldenhuis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed alkene diamination: synthesis of chiral 2-aminomethyl indolines and pyrrolidines

(2014) Benjamin W. Turnpenny et al.   Chemical Science

An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols

(2013) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Amination of Alcohols by the Use of Borrowing Hydrogen Methodology: Cooperative Catalysis by Iridium and a Chiral Phosphoric Acid

(2013) Yao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitro-Mannich Reaction

(2013) Adam Noble et al.   CHEMICAL REVIEWS

Ruthenium-Catalyzed Enantioselective Synthesis of β-Amino Alcohols from 1,2-Diols by “Borrowing Hydrogen”

(2013) Anggi Eka Putra et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Palladium-Catalyzed Diamination of Alkenes Using N-Fluorobenzenesulfonimide

(2013) Erica L. Ingalls et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

(2013) C. Gunanathan et al.   SCIENCE

Bimetallic catalysis in the highly enantioselective ring–opening reactions of aziridines

(2013) Bin Wu et al.   Chemical Science

Recent Advances in Iridium-Catalyzed Alkylation of C–H and N–H Bonds

(2013) Shiguang Pan et al.   ACS Catalysis

A Chiral Bis(betaine) Catalyst for the Mannich Reaction of Azlactones and Aliphatic Imines

(2012) Wen-Quan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereocontrolled Synthesis of Vicinal Diamines by Organocatalytic Asymmetric Mannich Reaction of N-Protected Aminoacetaldehydes: Formal Synthesis of (−)-Agelastatin A

(2012) Taichi Kano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Catalytic Amination of Alcohols

(2011) Sebastian Bähn et al.   ChemCatChem

Asymmetric Strecker Reactions

(2011) Jun Wang et al.   CHEMICAL REVIEWS

Copper-Promoted and Copper-Catalyzed Intermolecular Alkene Diamination

(2010) Fatima C. Sequeira et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Give and Take of Alcohol Activation

(2010) A. J. A. Watson et al.   SCIENCE

Titanium Binolate Catalyzed Aminolysis ofmeso Aziridines: A Highly Enantioselective and Direct Access to 1,2-Diamines

(2009) Saravanan Peruncheralathan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Autotransfer in theN-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

(2009) Gabriela Guillena et al.   CHEMICAL REVIEWS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

Catalytic asymmetric direct Mannich reaction: a powerful tool for the synthesis of α,β-diamino acids

(2009) Ramón Gómez Arrayás et al.   CHEMICAL SOCIETY REVIEWS

Metal-catalysed 1,2-diamination reactions

(2009) Francesca Cardona et al.   Nature Chemistry

Regiodivergent Ring Opening of Chiral Aziridines

(2009) B. Wu et al.   SCIENCE

The Fluorenone Imines of Glycine Esters and Their Phosphonic Acid Analogues

(2008) Shū Kobayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific Diaza-Cope Rearrangement Driven by Steric Strain

(2008) Hyunwoo Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Mannich Reaction of Glycinate Schiff Bases withN-(8-Quinolyl)sulfonyl Imines: A Catalytic Asymmetric Approach toanti-α,β-Diamino Esters

(2008) Jorge Hernández-Toribio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Allylic and Homoallylic Diamination of Terminal Olefins via Formal C−H Activation

(2008) Haifeng Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Tertiary Diamines in Asymmetric Synthesis

(2007) Jean-Claude Kizirian   CHEMICAL REVIEWS