Catalytic Asymmetric Allylic Substitution with Copper(I) Homoenolates Generated from Cyclopropanols

Copper-Catalyzed Enantiotopic-Group-Selective Allylation of gem-Diborylalkanes

(2021) Minjae Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjugate Addition of Catalytically Generated Zinc Homoenolate

(2021) Yoshiya Sekiguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Ring-Opening Allylation of Cyclopropanols via Homoenolate

(2021) Yoshiya Sekiguchi et al.   ORGANIC LETTERS

Enantioselective Copper‐Catalyzed Radical Ring‐Opening Cyanation of Cyclopropanols and Cyclopropanone Acetals

(2020) Lianqian Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Brønsted Base-Catalyzed Transformation of α,β-Epoxyketones Utilizing [1,2]-Phospha-Brook Rearrangement for the Synthesis of Allylic Alcohols Having a Tetrasubstituted Alkene Moiety

(2020) Azusa Kondoh et al.   ORGANIC LETTERS

Enantioselective Copper-Catalyzed Trifluoromethylation of Benzylic Radicals via Ring Opening of Cyclopropanols

(2020) Chao Jiang et al.   Chem

Cobalt‐Catalyzed Diastereo‐ and Enantioselective Hydroalkylation of Cyclopropenes with Cobalt‐Homoenolates

(2020) Wei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Carbon–Carbon Bond Cleavage of Cyclopropanols

(2020) Tyler R. McDonald et al.   CHEMICAL REVIEWS

Copper-Catalyzed Aerobic Oxidative Cyclization Cascade to Construct Bridged Skeletons: Total Synthesis of (−)-Suaveoline

(2019) Qiuyuan Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Enantioselective and Chemodivergent Addition of Cyclopropanols to Oxabicyclic Alkenes

(2019) Junfeng Yang et al.   ACS Catalysis

Copper–Hydride-Catalyzed Enantioselective Processes with Allenyl Boronates. Mechanistic Nuances, Scope, and Utility in Target-Oriented Synthesis

(2019) Yu Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral N-heterocyclic carbene ligands with additional chelating group(s) applied to homogeneous metal-mediated asymmetric catalysis

(2019) Christophe Fliedel et al.   COORDINATION CHEMISTRY REVIEWS

Copper-Catalyzed Enantioselective Allylboration of Alkynes: Synthesis of Highly Versatile Multifunctional Building Blocks

(2019) Eva Rivera-Chao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Coupling between Allyl­boronates and Phosphates Using a Phenol–Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes

(2018) Hirohisa Ohmiya et al.   SYNTHESIS-STUTTGART

Catalytic Cyclopropanol Ring Opening for Divergent Syntheses of γ-Butyrolactones and δ-Ketoesters Containing All-Carbon Quaternary Centers

(2018) Zhishi Ye et al.   ACS Catalysis

Modern Developments in the Chemistry of Homoenolates

(2018) Leo Reginald Mills et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Total syntheses via cyclopropanols

(2018) Xinpei Cai et al.   TETRAHEDRON

Cu-Mediated Rearrangements of Allenylcyclopropanols to Cyclopentenones: Two Divergent Pathways

(2017) Naresh Tumma et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides

(2017) Kentaro Hojoh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre

(2017) Jaehee Lee et al.   Nature Chemistry

Copper(i)-catalyzed ring-opening cyanation of cyclopropanols

(2017) Yi-Si Feng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Asymmetric Borylallylation of Vinyl Arenes

(2017) Namhyeon Kim et al.   ORGANIC LETTERS

NHC-Copper-Catalyzed Tandem Hydrocupration and Allylation of Alkenyl Boronates

(2017) Jaesook Yun et al.   SYNTHESIS-STUTTGART

Catalytic SN 2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis

(2016) Ying Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles

(2016) Hirohisa Ohmiya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand

(2016) Yuto Yasuda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Homoallylic Boronates by Chemo-, SN2′-, Diastereo- and Enantioselective Catalytic Sequence of Cu−H Addition to Vinyl-B(pin)/Allylic Substitution

(2016) Jaehee Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Borylalkanes via Copper-Catalyzed Enantioselective Hydroallylation

(2016) Jung Tae Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed SN2′-Selective Allylic Substitution Reaction of gem-Diborylalkanes

(2016) Zhen-Qi Zhang et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed C–C and C–X Bond-Forming Reactions Using Cyclopropanols

(2016) Arturo Orellana et al.   SYNTHESIS-STUTTGART

Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes

(2015) Yuto Yasuda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Concise Synthesis of Alkaloid (−)-205B

(2015) Nagavaram Narsimha Rao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-value alcohols and higher-oxidation-state compounds by catalytic Z-selective cross-metathesis

(2015) Ming Joo Koh et al.   NATURE

Copper-catalysed ring-opening trifluoromethylation of cyclopropanols

(2015) Xia-Ping He et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

An Umpolung Strategy for the Synthesis of β-Aminoketones via Copper-Catalyzed Electrophilic Amination of Cyclopropanols

(2015) Zhishi Ye et al.   ORGANIC LETTERS

Copper-Catalyzed Cyclopropanol Ring Opening Csp3–Csp3 Cross-Couplings with (Fluoro)Alkyl Halides

(2015) Zhishi Ye et al.   ORGANIC LETTERS

C-Alkynylation of Cyclopropanols

(2015) R. V. N. S. Murali et al.   ORGANIC LETTERS

Efficient Synthesis of β-CF3/SCF3-Substituted Carbonyls via Copper-Catalyzed Electrophilic Ring-Opening Cross-Coupling of Cyclopropanols

(2015) Yong Li et al.   ORGANIC LETTERS

Copper-catalyzed enantioselective allylic cross-coupling with alkylboranes

(2015) Kentaro Hojoh et al.   TETRAHEDRON

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes

(2014) Kentaro Hojoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multicomponent Synthesis of Chiral Bidentate Unsymmetrical UnsaturatedN-Heterocyclic Carbenes: Copper-Catalyzed Asymmetric CC Bond Formation

(2014) Claire Jahier-Diallo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Quaternary Carbon Stereocenters by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Arylboronates

(2014) Momotaro Takeda et al.   JOURNAL OF ORGANIC CHEMISTRY

A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis

(2014) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles

(2014) Ayumi Harada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling of Cyclopropanols: Concise Syntheses of Indolizidine 223AB and Congeners

(2014) Nagavaram Narsimha Rao et al.   ORGANIC LETTERS

Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes

(2013) Yusuke Makida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Allylic Substitution with Readily Accessible Carbonyl- and Acetal-Containing Vinylboron Reagents

(2012) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SN2′ Alkylation of Cyclopropanols via Homoenolates

(2012) Pragna Pratic Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation

(2012) Yusuke Makida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bidentate Hydroxyalkyl NHC Ligands for the Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Grignard Reagents

(2012) Magaly Magrez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes

(2012) Yoshinori Shido et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible 1,3-anti/syn-Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl–Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes

(2012) Kazunori Nagao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Preparation of β-Branched γ,δ-Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal

(2012) Hirohisa Ohmiya et al.   SYNTHESIS-STUTTGART

Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

(2011) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed γ-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals

(2011) Dong Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Enantioselective Allylic Substitutions with Readily Accessible Aryl- or Heteroaryllithium Reagents and Aluminum Chlorides

(2010) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed γ-Selective and Stereospecific Allyl−Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates

(2010) Hirohisa Ohmiya et al.   ORGANIC LETTERS

Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

(2008) Syuzanna R. Harutyunyan et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

Copper-Catalyzed Asymmetric Allylic Alkylation

(2008) Caroline A. Falciola et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY