Bidentate Hydroxyalkyl NHC Ligands for the Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Grignard Reagents

Synthesis of Enantioenriched Triarylmethanes by Stereospecific Cross-Coupling Reactions

(2012) Buck L. H. Taylor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Cross-Coupling of Functionalized Alkyl Halides and Tosylates with Secondary and Tertiary Alkyl Grignard Reagents

(2012) Peng Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Cross-Coupling of N-Heterocyclic Chlorides and Bromides with Arylmagnesium Reagents

(2012) Olesya M. Kuzmina et al.   ORGANIC LETTERS

Furanoside phosphite–phosphoroamidite and diphosphoroamidite ligands applied to asymmetric Cu-catalyzed allylic substitution reactions

(2012) Marc Magre et al.   TETRAHEDRON-ASYMMETRY

Enyne Chlorides: Substrates for Copper-Catalyzed Asymmetric Allylic Alkylation

(2011) Hailing Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning Chemoselectivity in Iron-Catalyzed Sonogashira-Type Reactions Using a Bisphosphine Ligand with Peripheral Steric Bulk: Selective Alkynylation of Nonactivated Alkyl Halides

(2011) Takuji Hatakeyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed 1,4-Addition of Organoboronates to Alkylidene Cyanoacetates: Mechanistic Insight and Application to Asymmetric Catalysis

(2011) Keishi Takatsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

(2011) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanisms of Nucleophilic Organocopper(I) Reactions

(2011) Naohiko Yoshikai et al.   CHEMICAL REVIEWS

Iron-Catalyzed Stereospecific Activation of Olefinic C–H Bonds with Grignard Reagent for Synthesis of Substituted Olefins

(2011) Laurean Ilies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers through NHC−Cu-Catalyzed Allylic Substitution Reactions with (i-Bu)2(Alkynyl)aluminum Reagents

(2011) Jennifer A. Dabrowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Cross-Coupling of CH Bonds with Grignard Reagents through Cobalt Catalysis

(2010) Bin Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Enantioselective Allylic Substitutions with Readily Accessible Aryl- or Heteroaryllithium Reagents and Aluminum Chlorides

(2010) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Free Asymmetric Allylic Alkylation with Grignard Reagents

(2010) Olivier Jackowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates

(2010) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Formation of Quaternary Chiral Centers by N-Heterocyclic Carbene-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Trisubstituted Cyclic Enones

(2010) Stefan Kehrli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Convergent and stereospecific synthesis of complex skipped polyenes and polyunsaturated fatty acids

(2010) Todd K. Macklin et al.   Nature Chemistry

Enantioselective Copper-Catalyzed Allylic Substitution Reaction with Aminohydroxyphosphine Ligand

(2009) Naohiko Yoshikai et al.   ADVANCED SYNTHESIS & CATALYSIS

Stereoisomerically Pure Trisubstituted Vinylaluminum Reagents and their Utility in Copper-Catalyzed Enantioselective Synthesis of 1,4-Dienes Containing Z or E Alkenes

(2009) Katsuhiro Akiyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis and Structure Elucidation of (+)-Phorbasin C

(2009) Todd K. Macklin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Grignard Reagents

(2009) Dietmar Seyferth   ORGANOMETALLICS

Cross-Coupling Reaction of Alkyl Halides with Grignard Reagents Catalyzed by Ni, Pd, or Cu Complexes with π-Carbon Ligand(s)

(2008) Jun Terao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Regiodivergent 1,4 versus 1,6 Asymmetric Copper-Catalyzed Conjugate Addition

(2008) Hélène Hénon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

(2008) Syuzanna R. Harutyunyan et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

Development of Biisoquinoline-Based Chiral Diaminocarbene Ligands:  Enantioselective SN2‘ Allylic Alkylation Catalyzed by Copper−Carbene Complexes

(2008) Hwimin Seo et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Site- and Enantioselective Cu-Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents

(2007) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY