Protodeboronation of (Hetero)Arylboronic Esters: Direct versus Prehydrolytic Pathways and Self-/Auto-Catalysis

Application of C–H Functionalization in the Development of a Concise and Convergent Route to the Phosphatidylinositol-3-kinase Delta Inhibitor Nemiralisib

(2021) Robert N. Bream et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Stopped‐Flow 19 F NMR Spectroscopic Analysis of a Protodeboronation Proceeding at the Sub‐Second Time‐Scale

(2021) Ran Wei et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Sequential Ir/Cu-Mediated Method for the Meta-Selective C–H Radiofluorination of (Hetero)Arenes

(2021) Jay S. Wright et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid Estimation of T1 for Quantitative NMR

(2021) Ran Wei et al.   JOURNAL OF ORGANIC CHEMISTRY

Equilibria in the 3-(trifluoromethyl)phenylboronic acid - boroxine system. Solubility of the acid and its cyclic esters in organic solvents

(2021) Paweł Leszczyński et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Reactivity of Boronic Acids toward Catechols in Aqueous Solution

(2020) Yota Suzuki et al.   JOURNAL OF ORGANIC CHEMISTRY

Arylboronic Acids and their Myriad of Applications Beyond Organic Synthesis

(2020) Noemi de Jesus Hiller et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The influence of ortho-substituents on the properties of phenylboronic acids

(2020) Agnieszka Adamczyk-Woźniak et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Boronic Ester-Based Self-Healing Hydrogels Formed by Using Intermolecular B-N Coordination

(2020) Yusheng Liu et al.   POLYMER

Design and discovery of boronic acid drugs

(2020) Jessica Plescia et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Borylative Heterocyclization without Air-Free Techniques

(2020) Chao Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Polyfluorinated arylboranes as catalysts in organic synthesis

(2020) Nicolay Yu. Adonin et al.   MENDELEEV COMMUNICATIONS

Self-healing polymers

(2020) Siyang Wang et al.   Nature Reviews Materials

The 2‐Pyridyl Problem: Challenging Nucleophiles in Cross‐Coupling Arylations

(2020) Michael C. Willis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How Big is the Pinacol Boronic Ester as a Substituent?

(2020) Valerio Fasano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoinduced Borylation Reactions: An Overview

(2020) B. Yadagiri et al.   Asian Journal of Organic Chemistry

Fluorinated Aryl Boronates as Building Blocks in Organic Synthesis

(2020) Yudha Budiman et al.   ADVANCED SYNTHESIS & CATALYSIS

Improvement in the Palladium-Catalyzed Miyaura Borylation Reaction by Optimization of the Base: Scope and Mechanistic Study

(2020) Santiago Barroso et al.   JOURNAL OF ORGANIC CHEMISTRY

Radiosynthesis of [ 18 F]ArylSCF 2 H Using Aryl Boronic Acids, S -(Chlorofluoromethyl)benzenesulfonothioate and [ 18 F]Fluoride

(2020) Qunchao Zhao et al.   CCS Chemistry

In vivo Mutagenicity Testing of Arylboronic Acids and Esters

(2019) Melisa J. Masuda‐Herrera et al.   ENVIRONMENTAL AND MOLECULAR MUTAGENESIS

Boronic acid‐functionalized agarose affinity chromatography for isolation of tropomyosin in fishes

(2019) Jialuo Yin et al.   JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE

Phenoxy-Dialkoxy Borates as a New Class of Readily Prepared Preactivated Reagents for Base-Free Cross-Coupling

(2019) Marco Paladino et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The mechanisms of boronate ester formation and fluorescent turn-on in ortho-aminomethylphenylboronic acids

(2019) Xiaolong Sun et al.   Nature Chemistry

Boron in drug design: Recent advances in the development of new therapeutic agents

(2019) Guilherme Felipe Santos Fernandes et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Kinetics and Mechanism of the Arase-Hoshi R2BH-Catalyzed Alkyne Hydroboration: Alkenylboronate Generation via B–H/C–B Metathesis

(2019) Eduardo Nieto-Sepulveda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki−Miyaura Cross-Coupling of Boronic Esters

(2019) Connor P. Delaney et al.   ACS Catalysis

Elucidating the Role of the Boronic Esters in the Suzuki–Miyaura Reaction: Structural, Kinetic, and Computational Investigations

(2018) Andy A. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of biologically active boron-containing compounds

(2018) Fei Yang et al.   MedChemComm

An “On-Cycle” Precatalyst Enables Room-Temperature Polyfluoroarylation Using Sensitive Boronic Acids

(2018) Liye Chen et al.   ACS Catalysis

Copper-boryl mediated organic synthesis

(2018) David Hemming et al.   CHEMICAL SOCIETY REVIEWS

Self-Healing Boronic Acid-Based Hydrogels for 3D Co-cultures

(2018) Megan E. Smithmyer et al.   ACS Macro Letters

Fluorinated Boronic Acids: Acidity and Hydrolytic Stability of Fluorinated Phenylboronic Acids

(2017) Dorota Zarzeczańska et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Boron acid complexation reactions with polyols and α-hydroxy carboxylic acids: Equilibria, reaction mechanisms, saccharide recognition

(2017) Richard Pizer   INORGANICA CHIMICA ACTA

Synthesis of Polyflourinated Biphenyls; Pushing the Boundaries of Suzuki–Miyaura Cross Coupling with Electron-Poor Substrates

(2017) David Bulfield et al.   JOURNAL OF ORGANIC CHEMISTRY

Triple responsive block copolymers combining pH-responsive, thermoresponsive, and glucose-responsive behaviors

(2017) William L. A. Brooks et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Spectroscopic Studies of the Chan–Lam Amination: A Mechanism-Inspired Solution to Boronic Ester Reactivity

(2017) Julien C. Vantourout et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Catalyzed Aryl-B(OH)2 Protodeboronation Revisited: From Concerted Proton Transfer to Liberation of a Transient Aryl Anion

(2017) Paul A. Cox et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective [2,3]-Rearrangements of Allylic Ammonium Ylides: A Mechanistic and Computational Study

(2017) Thomas H. West et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Doubly Dynamic Self-Healing Materials Based on Oxime Click Chemistry and Boronic Acids

(2017) Joe Collins et al.   MACROMOLECULAR RAPID COMMUNICATIONS

The versatility of boron in biological target engagement

(2017) Diego B. Diaz et al.   Nature Chemistry

Recent Developments in Organoboron Chemistry: Old Dogs, New Tricks

(2017) James W.B. Fyfe et al.   Chem

Borate esters: Simple catalysts for the sustainable synthesis of complex amides

(2017) Marco T. Sabatini et al.   Science Advances

Borinic Acid Catalyzed Stereo- and Regioselective Couplings of Glycosyl Methanesulfonates

(2016) Kyan A. D’Angelo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Protodeboronation of Heteroaromatic, Vinyl, and Cyclopropyl Boronic Acids: pH–Rate Profiles, Autocatalysis, and Disproportionation

(2016) Paul A. Cox et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

MIDA boronates are hydrolysed fast and slow by two different mechanisms

(2016) Jorge A. Gonzalez et al.   Nature Chemistry

Synthesis and polymerization of boronic acid containing monomers

(2016) Gertjan Vancoillie et al.   Polymer Chemistry

Responsive Boronic Acid-Decorated (Co)polymers: From Glucose Sensors to Autonomous Drug Delivery

(2016) Gertjan Vancoillie et al.   SENSORS

A Surprising Substituent Effect Provides a Superior Boronic Acid Catalyst for Mild and Metal-Free Direct Friedel-Crafts Alkylations and Prenylations of Neutral Arenes

(2015) Carolynne L. Ricardo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Harnessing C–H Borylation/Deborylation for Selective Deuteration, Synthesis of Boronate Esters, and Late Stage Functionalization

(2015) Venkata A Kallepalli et al.   JOURNAL OF ORGANIC CHEMISTRY

Organotrifluoroborates: Another Branch of the Mighty Oak

(2015) Gary A. Molander   JOURNAL OF ORGANIC CHEMISTRY

A modular synthesis of functionalised phenols enabled by controlled boron speciation

(2015) John J. Molloy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of [18F]Arenes via the Copper-Mediated [18F]Fluorination of Boronic Acids

(2015) Andrew V. Mossine et al.   ORGANIC LETTERS

A synthesis of abemaciclib utilizing a Leuckart–Wallach reaction

(2015) Michael O. Frederick et al.   TETRAHEDRON LETTERS

Lithiation–Borylation Methodology and Its Application in Synthesis

(2014) Daniele Leonori et al.   ACCOUNTS OF CHEMICAL RESEARCH

Fluorine-18 Radiochemistry, Labeling Strategies and Synthetic Routes

(2014) Orit Jacobson et al.   BIOCONJUGATE CHEMISTRY

Universal Reaction Mechanism of Boronic Acids with Diols in Aqueous Solution: Kinetics and the Basic Concept of a Conditional Formation Constant

(2014) Yuki Furikado et al.   CHEMISTRY-A EUROPEAN JOURNAL

Interactions between boric acid derivatives and saccharides in aqueous media: Structures and stabilities of resulting esters

(2014) Joop A. Peters   COORDINATION CHEMISTRY REVIEWS

Base-Promoted Protodeboronation of 2,6-Disubstituted Arylboronic Acids

(2014) Jerome Lozada et al.   JOURNAL OF ORGANIC CHEMISTRY

Selectivity and Isotope Effects in Hydronation of a Naked Aryl Anion

(2014) Charles L. Perrin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed C–H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism

(2014) Matthew A. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of hydroxyphthioceranic acid using a traceless lithiation–borylation–protodeboronation strategy

(2014) Ramesh Rasappan et al.   Nature Chemistry

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Selective sensing of saccharides using simple boronic acids and their aggregates

(2013) Xin Wu et al.   CHEMICAL SOCIETY REVIEWS

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Protodeboronation of ortho- and para-Phenol Boronic Acids and Application to ortho and meta Functionalization of Phenols Using Boronic Acids as Blocking and Directing Groups

(2013) Chun-Young Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

Organoboron Acids and Their Derivatives as Catalysts for Organic Synthesis

(2013) Elena Dimitrijević et al.   ACS Catalysis

A decade advancement of transition metal-catalyzed borylation of aryl halides and sulfonates

(2013) Wing Kin Chow et al.   RSC Advances

Exploiting the Reversible Covalent Bonding of Boronic Acids: Recognition, Sensing, and Assembly

(2012) Steven D Bull et al.   ACCOUNTS OF CHEMICAL RESEARCH

Supramolecular Binding Thermodynamics by Dispersion-Corrected Density Functional Theory

(2012) Stefan Grimme   CHEMISTRY-A EUROPEAN JOURNAL

A C–H Borylation Approach to Suzuki–Miyaura Coupling of Typically Unstable 2–Heteroaryl and Polyfluorophenyl Boronates

(2012) Daniel W. Robbins et al.   ORGANIC LETTERS

Mild boronic acid catalyzed Nazarov cyclization of divinyl alcohols in tandem with Diels–Alder cycloaddition

(2012) Hongchao Zheng et al.   TETRAHEDRON LETTERS

Susceptibility to hydrolysis of phenylboronic pinacol esters at physiological pH

(2012) Cesare Achilli et al.   Open Chemistry

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Regioselectivity of the borylation of alkanes and arenes

(2011) John F. Hartwig   CHEMICAL SOCIETY REVIEWS

Aryl Trihydroxyborate Salts: Thermally Unstable Species with Unusual Gelation Abilities

(2011) Cheryl L. Moy et al.   JOURNAL OF ORGANIC CHEMISTRY

Arylboronic acids: A diabetic eye on glucose sensing

(2011) Jon Stefan Hansen et al.   SENSORS AND ACTUATORS B-CHEMICAL

Aryl Trifluoroborates in Suzuki-Miyaura Coupling: The Roles of Endogenous Aryl Boronic Acid and Fluoride

(2010) Mike Butters et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The thermal and boron-catalysed direct amide formation reactions: mechanistically understudied yet important processes

(2010) Hayley Charville et al.   CHEMICAL COMMUNICATIONS

Boronic Acid Catalysis for Mild and Selective [3+2] Dipolar Cycloadditions to Unsaturated Carboxylic Acids

(2010) Hongchao Zheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Slow-Release Strategy in Suzuki-Miyaura Coupling

(2010) Alastair J. J. Lennox et al.   ISRAEL JOURNAL OF CHEMISTRY

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

(2010) Noriyuki Iwadate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C−H Arylation of Electron-Deficient Heterocycles with Arylboronic Acids

(2010) Ian B. Seiple et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids

(2010) Tom Kinzel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and efficient boronic acid catalysis of Diels–Alder cycloadditions to 2-alkynoic acids

(2010) Hongchao Zheng et al.   TETRAHEDRON LETTERS

Boronic acids in medicinal chemistry: anticancer, antibacterial and antiviral applications

(2010) Paul C. Trippier et al.   MedChemComm

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Easily Attachable and Detachableortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation

(2009) Hideki Ihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Density Functionals with Broad Applicability in Chemistry

(2008) Yan Zhao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct and Waste-Free Amidations and Cycloadditions by Organocatalytic Activation of Carboxylic Acids at Room Temperature

(2008) Raed M. Al-Zoubi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Kinetic Evidence for High Reactivity of 3-Nitrophenylboronic Acid Compared to Its Conjugate Boronate Ion in Reactions with Ethylene and Propylene Glycols

(2008) Chiaki Miyamoto et al.   INORGANIC CHEMISTRY