Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 10, Pages 3093-3102Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00078e
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Funding
- EPSRC
- GlaxoSmithKline
- Engineering and Physical Sciences Research Council [1574591, 1628052] Funding Source: researchfish
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A modular synthesis of functionalised biaryl phenols from two boronic acid derivatives has been developed via one-pot Suzuki-Miyaura cross-coupling, chemoselective control of boron solution speciation to generate a reactive boronic ester in situ, and oxidation. The utility of this method has been further demonstrated by application in the synthesis of drug molecules and components of organic electronics, as well as within iterative cross-coupling.
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