Regio‐Divergent C—H Alkynylation with Janus Directing Strategy via Ir( III ) Catalysis

Distal Alkenyl C–H Functionalization via the Palladium/Norbornene Cooperative Catalysis

(2020) Zhao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt(III)-Catalyzed [4 + 2] Annulation of N-Chlorobenzamides with Maleimides

(2019) Nachimuthu Muniraj et al.   ORGANIC LETTERS

Chiral Cyclopentadienyl Cobalt(III) Complexes Enable Highly Enantioselective 3d-Metal-Catalyzed C–H Functionalizations

(2019) Kristers Ozols et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Development on Cp*Ir(III)‐Catalyzed C−H Bond Functionalization

(2019) Xianwei Li et al.   ChemCatChem

Iridium-Catalyzed Aerobic α,β-Dehydrogenation of γ,δ-Unsaturated Amides and Acids: Activation of Both α- and β-C–H bonds through an Allyl–Iridium Intermediate

(2018) Zhen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multi-Metal-Catalyzed Oxidative Radical Alkynylation with Terminal Alkynes: A New Strategy for C(sp3)–C(sp) Bond Formation

(2018) Shan Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-enabled ortho-C–H olefination of phenylacetic amides with unactivated alkenes

(2018) Ming-Zhu Lu et al.   Chemical Science

sp3 C–H activation via exo-type directing groups

(2018) Yan Xu et al.   Chemical Science

Co(iii)-Catalyzed N-chloroamide-directed C–H activation for 3,4-dihydroisoquinolone synthesis

(2018) Xiaolong Yu et al.   Organic Chemistry Frontiers

Regioselective C–H Bond Alkynylation of Carbonyl Compounds through Ir(III) Catalysis

(2017) Xianwei Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Access to Cobaltacycles via C–H Activation: N-Chloroamide-Enabled Room-Temperature Synthesis of Heterocycles

(2017) Xiaolong Yu et al.   ORGANIC LETTERS

Catalytic C(sp3)−H Arylation of Free Primary Amines with anexoDirecting Group Generated In Situ

(2016) Yan Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Hydrazone-Based exo -Directing-Group Strategy for β C−H Oxidation of Aliphatic Amines

(2016) Zhongxing Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Advances in the development of catalytic tethering directing groups for C–H functionalization reactions

(2016) Huan Sun et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cu-Catalyzed Alkynylation of Unactivated C(sp3)–X Bonds with Terminal Alkynes through Directing Strategy

(2016) Fei-Xian Luo et al.   ORGANIC LETTERS

Silver-Free Palladium-Catalyzed sp3 and sp2 C–H Alkynylation Promoted by a 1,2,3-Triazole Amine Directing Group

(2016) Xiaohan Ye et al.   ORGANIC LETTERS

Nickel-Catalyzed Oxidative Coupling of Unactivated C(sp3)–H Bonds in Aliphatic Amides with Terminal Alkynes

(2016) Fei-Xian Luo et al.   ORGANOMETALLICS

β-Arylation of oxime ethers using diaryliodonium salts through activation of inert C(sp)–H bonds using a palladium catalyst

(2016) Jing Peng et al.   Chemical Science

Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes

(2016) Shan Tang et al.   Nature Communications

Transition metal-catalyzed C–H functionalization of N-oxyenamine internal oxidants

(2015) Huawen Huang et al.   CHEMICAL SOCIETY REVIEWS

Iridium(III)-Catalyzed Direct Arylation of C–H Bonds with Diaryliodonium Salts

(2015) Pan Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclic Ether Synthesis via Palladium-Catalyzed Directed Dehydrogenative Annulation at Unactivated Terminal Positions

(2015) Samuel J. Thompson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-enabled meta-C–H activation using a transient mediator

(2015) Xiao-Chen Wang et al.   NATURE

Synthesis of β-alkynyl α-amino acids via palladium-catalyzed alkynylation of unactivated C(sp3)-H bonds

(2015) Bo Wang et al.   Science China-Chemistry

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Haloalkynes: A Powerful and Versatile Building Block in Organic Synthesis

(2014) Wanqing Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Aerobic Oxidative Transformation of Ketone-DerivedN-Tosyl Hydrazones: An Entry to Alkynes

(2014) Xianwei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Aryl C–H Olefination with Unactivated, Aliphatic Alkenes

(2014) Arghya Deb et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Intermolecular Amidation of sp3 C–H Bonds: Late-Stage Functionalization of an Unactivated Methyl Group

(2014) Taek Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Stereoretentive Olefination of Unactivated C(sp3)–H Bonds with Vinyl Iodides at Room Temperature: Synthesis of β-Vinyl α-Amino Acids

(2014) Bo Wang et al.   ORGANIC LETTERS

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(ii)-catalyzed decarboxylative acylation of phenylacetamides with α-oxocarboxylic acids via C–H bond activation

(2013) Jihye Park et al.   CHEMICAL COMMUNICATIONS

Palladium(0)-Catalyzed Alkynylation of C(sp3)–H Bonds

(2013) Jian He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Electrophilic alkynylation: the dark side of acetylene chemistry

(2012) Jonathan P. Brand et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Functionalization of Unactivated sp3 C–H Bonds via exo-Directing Groups: Synthesis of Chemically Differentiated 1,2-Diols

(2012) Zhi Ren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidizing Directing Groups Enable Efficient and Innovative CH Activation Reactions

(2011) Frederic W. Patureau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in Sonogashira reactions

(2011) Rafael Chinchilla et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Direct Ethynylation of C(sp3)–H Bonds in Aliphatic Carboxylic Acid Derivatives

(2011) Yusuke Ano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-catalyzed ortho-arylation of phenylacetamides, benzamides, and anilides with simple arenes using sodium persulfate

(2010) Charles S. Yeung et al.   Chemical Science