Ligand-enabled ortho-C–H olefination of phenylacetic amides with unactivated alkenes

Ligand-Enabled Pd(II)-Catalyzed Bromination and Iodination of C(sp3)–H Bonds

(2017) Ru-Yi Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed meta-C–H Olefination Directed by a Nitrile Template

(2017) Hua-Jin Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Detailed Mechanistic Studies on Palladium-Catalyzed Selective C–H Olefination with Aliphatic Alkenes: A Significant Influence of Proton Shuttling

(2017) Arghya Deb et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

P(O)R2-Directed Enantioselective C–H Olefination toward Chiral Atropoisomeric Phosphine–Olefin Compounds

(2017) Shi-Xia Li et al.   ORGANIC LETTERS

Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction

(2017) Soham Maity et al.   Chemical Science

Ligand-assisted palladium-catalyzed C–H alkenylation of aliphatic amines for the synthesis of functionalized pyrrolidines

(2017) Chuan He et al.   Chemical Science

Incorporating Unbiased, Unactivated Aliphatic Alkenes in Pd(II)-Catalyzed Olefination of Benzyl Phosphonamide

(2017) Kapileswar Seth et al.   ACS Catalysis

Syntheses and Transformations of α-Amino Acids via Palladium-Catalyzed Auxiliary-Directed sp3 C–H Functionalization

(2016) Gang He et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-catalyzed C–H olefination of aromatics with unactivated alkenes

(2016) Ramasamy Manoharan et al.   CHEMICAL COMMUNICATIONS

Cobalt-catalyzed chelation assisted C–H allylation of aromatic amides with unactivated olefins

(2016) Takuma Yamaguchi et al.   CHEMICAL COMMUNICATIONS

Palladium catalyzed selective distal C–H olefination of biaryl systems

(2016) Soham Maity et al.   CHEMICAL COMMUNICATIONS

Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation

(2016) David A. Petrone et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Emergence of Unactivated Olefins for the Synthesis of Olefinated Arenes

(2016) Arghya Deb et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ligand-Enabled γ-C(sp3)–H Olefination of Amines: En Route to Pyrrolidines

(2016) Heng Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heteroarene-Directed Oxidative sp2 C–H Bond Allylation with Aliphatic Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)rhodium(III) Complex

(2016) Yuji Takahama et al.   ORGANIC LETTERS

Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives

(2016) Shangda Li et al.   Nature Communications

Switch to Allylic Selectivity in Cobalt-Catalyzed Dehydrogenative Heck Reactions with Unbiased Aliphatic Olefins

(2016) Soham Maity et al.   ACS Catalysis

Rhodium(III)-Catalyzed Direct CH Olefination of Arenes with Aliphatic Olefins

(2015) Xiao Xue et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium(II)-Catalyzedmeta-CH Olefination: Constructing Multisubstituted Arenes through Homo-Diolefination and Sequential Hetero-Diolefination

(2015) Milan Bera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal-catalyzed ketone-directed or mediated C–H functionalization

(2015) Zhongxing Huang et al.   CHEMICAL SOCIETY REVIEWS

Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions

(2015) Yuji Takahama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Remote para-C–H Functionalization of Arenes by a D-Shaped Biphenyl Template-Based Assembly

(2015) Sukdev Bag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled Stereoselective β-C(sp3)–H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino Acids

(2015) Ru-Yi Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monoselective o-C–H Functionalizations of Mandelic Acid and α-Phenylglycine

(2015) Navid Dastbaravardeh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution of C–H Bond Functionalization from Methane to Methodology

(2015) John F. Hartwig   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-enabled meta-C–H activation using a transient mediator

(2015) Xiao-Chen Wang et al.   NATURE

Carboxylate-Directed CH Functionalization

(2014) Guangfa Shi et al.   ADVANCED SYNTHESIS & CATALYSIS

Weakly Coordinating Directing Groups for Ruthenium(II)- Catalyzed CH Activation

(2014) Suman De Sarkar et al.   ADVANCED SYNTHESIS & CATALYSIS

Remotemeta-CH Olefination of Phenylacetic Acids Directed by a Versatile U-Shaped Template

(2014) Youqian Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arene C–H functionalisation using a removable/modifiable or a traceless directing group strategy

(2014) Fengzhi Zhang et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Aryl C–H Olefination with Unactivated, Aliphatic Alkenes

(2014) Arghya Deb et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes

(2014) Joseph S. Bair et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Oxidative Olefination of Furans with Unactivated Alkenes

(2014) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conformation-induced remote meta-C–H activation of amines

(2014) Ri-Yuan Tang et al.   NATURE

Aerobic Direct C–H Arylation of Nonbiased Olefins

(2014) Nicolas Gigant et al.   ORGANIC LETTERS

Palladium-Catalyzed Aerobic Oxidative C–H Olefination with Removable 1,2,3-Triazole Directing Group

(2014) Xiaohan Ye et al.   ORGANIC LETTERS

Meta-Selective Arene C–H Bond Olefination of Arylacetic Acid Using a Nitrile-Based Directing Group

(2014) Milan Bera et al.   ORGANIC LETTERS

Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes through C-H Cleavage

(2013) Marvin Schinkel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Developing Ligands for Palladium(II)-Catalyzed C–H Functionalization: Intimate Dialogue between Ligand and Substrate

(2013) Keary M. Engle et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium(ii)-catalyzed cross-coupling of simple alkenes with acrylates: a direct approach to 1,3-dienes through C–H activation

(2013) Zhen-Kang Wen et al.   Chemical Science

Ether-Directedortho-C-H Olefination with a Palladium(II)/Monoprotected Amino Acid Catalyst

(2012) Gang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(II)-Catalyzed Ortho Trifluoromethylation of Arenes and Insights into the Coordination Mode of Acidic Amide Directing Groups

(2012) Xing-Guo Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Aspercyclides A and B via Intramolecular Oxidative Diaryl Ether Formation

(2012) Tatsuya Yoshino et al.   ORGANIC LETTERS

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Rh(III)-Catalyzed Oxidative Olefination ofN-(1-Naphthyl)sulfonamides Using Activated and Unactivated Alkenes

(2011) Xuting Li et al.   ORGANIC LETTERS

Constructing Multiply Substituted Arenes Using Sequential Palladium(II)-Catalyzed CH Olefination

(2010) Keary M. Engle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(II)-Catalyzed Hydroxyl-Directed C−H Activation/C−O Cyclization: Expedient Construction of Dihydrobenzofurans

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Hydroxyl-Directed C−H Olefination Enabled by Monoprotected Amino Acid Ligands

(2010) Yi Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism

(2010) Keary M. Engle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation

(2010) Andy S. Tsai et al.   ORGANIC LETTERS

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of the Aspercyclides

(2009) Jiří Pospíšil et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C−H Bond Activation Catalyzed by anin SituFormed Cationic Ruthenium Hydride Complex

(2009) Chae S. Yi et al.   ORGANOMETALLICS

Ligand-Enabled Reactivity and Selectivity in a Synthetically Versatile Aryl C-H Olefination

(2009) D.-H. Wang et al.   SCIENCE