Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles

Diastereodivergent Asymmetric Carboamination/Annulation of Cyclopropenes with Aminoalkenes by Chiral Lanthanum Catalysts

(2017) Huai-Long Teng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Nitrone Synthesis via Ligand-Enabled Copper-Catalyzed Cope-Type Hydroamination of Cyclopropene with Oxime

(2017) Zhanyu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective Borocyclopropanation of Allylic Ethers Using a Boromethylzinc Carbenoid

(2017) Guillaume Benoit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis

(2017) Yong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched Vinylcyclopropane Derivatives

(2017) Daniel S. Müller et al.   ORGANIC LETTERS

Metalloradical activation of α-formyldiazoacetates for the catalytic asymmetric radical cyclopropanation of alkenes

(2017) Xue Xu et al.   Chemical Science

Synthesis of Chiral Aminocyclopropanes by Rare-Earth-Metal-Catalyzed Cyclopropene Hydroamination

(2016) Huai-Long Teng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C−H Bonds

(2016) Taegyo Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The “Cyclopropyl Fragment” is a Versatile Player that Frequently Appears in Preclinical/Clinical Drug Molecules

(2016) Tanaji T. Talele   JOURNAL OF MEDICINAL CHEMISTRY

Nickel-Catalyzed Suzuki-Miyaura Coupling of a Tertiary Iodocyclopropane with Wide Boronic Acid Substrate Scope: Coupling Reaction Outcome Depends on Radical Species Stability

(2015) Keisuke Yotsuji et al.   ADVANCED SYNTHESIS & CATALYSIS

Chiral γ-Lactams by Enantioselective Palladium(0)-Catalyzed Cyclopropane Functionalizations

(2015) Julia Pedroni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed Highly Enantioselective C–H Arylation of Cyclopropylmethylamines

(2015) Kelvin S. L. Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en Route to the Formation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanes

(2015) Daniel S. Müller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric C–H functionalization of cyclopropanes using an isoleucine-NH2 bidentate directing group

(2015) Jinhee Kim et al.   Chemical Science

Enantioselective palladium(0)-catalyzed intramolecular cyclopropane functionalization: access to dihydroquinolones, dihydroisoquinolones and the BMS-791325 ring system

(2015) J. Pedroni et al.   Chemical Science

Stereodivergent Synthesis of Arylcyclopropylamines by Sequential CH Borylation and Suzuki-Miyaura Coupling

(2014) Shin Miyamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine–Olefin Ligands Based on a Planar-Chiral (π-Arene)chromium Scaffold: Design, Synthesis, and Application in Asymmetric Catalysis

(2014) Masamichi Ogasawara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Diastereo- and Enantioselective Desymmetrization of Cyclopropenes: Synthesis of Cyclopropylboronates

(2014) Alejandro Parra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatility or Promiscuity: The Estrogen Receptors, Control of Ligand Selectivity and an Update on Subtype Selective Ligands

(2014) Hui Ng et al.   International Journal of Environmental Research and Public Health

Copper(i)-catalyzed enantioselective hydroboration of cyclopropenes: facile synthesis of optically active cyclopropylboronates

(2014) Bing Tian et al.   Organic Chemistry Frontiers

Design, synthesis, and biological evaluation of cyclopropyl analogues of stilbene with raloxifene side chain as subtype-selective ligands for estrogen receptor

(2013) Hye Lim Yeo et al.   ARCHIVES OF PHARMACAL RESEARCH

Cooperativity between steric repulsion and crossed diene coordination governs the enantioselectivity in rhodium(i)/chiral, 1,4- and 1,5-diene-catalysed 1,4-addition reaction: a DFT study

(2013) Eric Assen B. Kantchev   Chemical Science

Palladium(0)-Catalyzed Enantioselective CH Arylation of Cyclopropanes: Efficient Access to Functionalized Tetrahydroquinolines

(2012) Tanguy Saget et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

2,6-Dimethoxyphenyl-Substituted N-Heterocyclic Carbenes (NHCs): A Family of Highly Electron-Rich Organocatalysts

(2012) Michael Schedler et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Designing N-Heterocyclic Carbenes: Simultaneous Enhancement of Reactivity and Enantioselectivity in the Asymmetric Hydroacylation of Cyclopropenes

(2011) Fan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New and unusual scaffolds in medicinal chemistry

(2011) Charles M. Marson   CHEMICAL SOCIETY REVIEWS

Synopsis of Some Recent Tactical Application of Bioisosteres in Drug Design

(2011) Nicholas A. Meanwell   JOURNAL OF MEDICINAL CHEMISTRY

Pd(II)-Catalyzed Enantioselective C–H Activation of Cyclopropanes

(2011) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene (NHC)-Catalyzed Intermolecular Hydroacylation of Cyclopropenes

(2011) Xavier Bugaut et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Palladium-Catalyzed Carbozincation of Cyclopropenes

(2011) Katja Krämer et al.   ORGANIC LETTERS

Low-Valent Iron-Catalyzed C−C Bond Formation−Addition, Substitution, and C−H Bond Activation

(2010) Eiichi Nakamura et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation

(2010) Diem H. T. Phan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Enantio- and Diastereoselective Iodocyclopropanation of Allylic Alcohols by Using a Substituted Zinc Carbenoid

(2009) Louis-Philippe B. Beaulieu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantiomerically Pure Cyclopropylamines from Cyclopropylboronic Esters

(2009) J��rg Pietruszka et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Simmons–Smith Reaction of Allylic Alcohols with Al Lewis Acid/N Lewis Base Bifunctional Al(Salalen) Catalyst

(2008) Hiroaki Shitama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of cyclopropylcarboxamides using s-BuLi–sparteine-mediated metallation

(2008) Stephanie Lauru et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Hydroformylation of Cyclopropenes

(2008) William M. Sherrill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphine-free rhodium-catalyzed hydroarylation of diaryl acetylenes with boronic acids

(2008) Weiwei Zhang et al.   TETRAHEDRON LETTERS