Recent developments of cyclopropene chemistry

Preparation of Di-μ-chlorobis[π-1-chloro-1-aryl-2-(2′,2′-diarylvinyl)allyl]palladium(II) Complexes and a Novel Dehydrogenative Rearrangement of Arylvinylcyclopropenes for the Synthesis of 7H-Benzo[c]fluorene Derivatives

(2011) Zhi-Bin Zhu et al.   ORGANOMETALLICS

Rhodium-Catalyzed Cyclopropenation of Alkynes: Synthesis of Trifluoromethyl-Substituted Cyclopropenes

(2010) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homogeneous Gold Catalysis Beyond Assumptions and Proposals-Characterized Intermediates

(2010) A. Stephen K. Hashmi   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)-Catalyzed Cycloisomerization of Enynes Containing Cyclopropenes

(2010) Changkun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photochemical Triggering of the Bergman and Myers–Saito Cyclizations

(2010) Andrei Polukhtine et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Cyclopropenium ion catalysed Beckmann rearrangement

(2010) Vishnu P. Srivastava et al.   CHEMICAL COMMUNICATIONS

Chemistry of Vinylidenecyclopropanes

(2010) Min Shi et al.   CHEMICAL REVIEWS

Cu-free click cycloaddition reactions in chemical biology

(2010) John C. Jewett et al.   CHEMICAL SOCIETY REVIEWS

Stereospecific Synthesis of Alkylidenecyclopropanes via Sequential Cyclopropene Carbomagnesation/1,3-Carbon Shift

(2010) Xiaocong Xie et al.   JOURNAL OF ORGANIC CHEMISTRY

Threshold Photoelectron Spectroscopy of Cyclopropenylidene, Chlorocyclopropenylidene, and Their Deuterated Isotopomeres†

(2010) Patrick Hemberger et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation

(2010) Diem H. T. Phan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophilic Acyl Substitution via Aromatic Cation Activation of Carboxylic Acids: Rapid Generation of Acid Chlorides under Mild Conditions

(2010) David J. Hardee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular [1 + 2] and [3 + 2] Cycloaddition Reactions of Cyclopropenone Ketals

(2010) Paresma R. Patel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High Density Orthogonal Surface Immobilization via Photoactivated Copper-Free Click Chemistry

(2010) Sara V. Orski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclopropenation of Alkylidene Carbenes Derived from α-Silyl Ketones

(2010) Jingwei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Z-Selective and Syndioselective Ring-Opening Metathesis Polymerization (ROMP) Initiated by Monoaryloxidepyrrolide (MAP) Catalysts

(2010) Margaret M. Flook et al.   MACROMOLECULES

Gold(i)-catalysed alcohol additions to cyclopropenes

(2010) Maximillian S. Hadfield et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Intramolecular Diels−Alder Reactions of Cyclopropenone Ketals

(2010) Paresma R. Patel et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Tandem Ring-Opening/Ring-Closing/Cross-Metathesis of 1,6-Cyclopropene-ynes and Olefins for the Construction of the 3-Pyrroline Skeleton

(2010) Zhi-Bin Zhu et al.   ORGANIC LETTERS

Synthesis of 3-Oxa- and 3-Azabicyclo[4.1.0]heptanes by Gold-Catalyzed Cycloisomerization of Cyclopropenes

(2010) Frédéric Miege et al.   ORGANIC LETTERS

Experimental and Theoretical Investigation into the Gold-Catalyzed Reactivity of Cyclopropenylmethyl Acetates

(2010) Elaine Seraya et al.   ORGANIC LETTERS

Rh(I)-Catalyzed Carbonylative Carbocyclization of Tethered Ene− and Yne−cyclopropenes

(2010) Changkun Li et al.   ORGANIC LETTERS

Synthesis of 5-methylidenehexahydropyrrolo[l,2-a]imidazoles and 6-methylideneoctahydropyrrolo[l,2-a]pyrimidines by the reaction of 1-alkynyl-1-chlorocyclopropanes with lithium derivatives of 1,2- and 1,3-diaminoalkanes

(2010) K. N. Shavrin et al.   RUSSIAN CHEMICAL BULLETIN

Ring-retentive deprotonation of cyclopropene-3-carboxamides

(2010) Ryan Kim et al.   TETRAHEDRON

Mechanistic Insights on the Cycloisomerization of Polyunsaturated Precursors Catalyzed by Platinum and Gold Complexes

(2009) Elena Soriano et al.   ACCOUNTS OF CHEMICAL RESEARCH

Elementary Steps of Gold Catalysis: NMR Spectroscopy Reveals the Highly Cationic Character of a “Gold Carbenoid”

(2009) Günter Seidel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photolysis of diarylvinylcyclopropenes for the construction of 1-methylene-8a-aryl-1,8a-dihydroazulene skeletons

(2009) Fang-Fang Yu et al.   CHEMICAL COMMUNICATIONS

A computational study of the photosomerization reactions of bicyclic cyclopropene

(2009) Ming-Der Su   CHEMICAL PHYSICS LETTERS

Acid-Catalyzed Cascade Reactions of Arylvinylcyclopropenes with Acetals and Aldehydes for the Construction of Different Aromatic Systems

(2009) Zhi-Bin Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclopropenylcarbinol Derivatives as New Versatile Intermediates in Organic Synthesis: Application to the Formation of Enantiomerically Pure Alkylidenecyclopropane Derivatives

(2009) Samah Simaan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity of Cyclic (Alkyl)(amino)carbenes (CAACs) and Bis(amino)cyclopropenylidenes (BACs) with Heteroallenes: Comparisons with theirN-Heterocyclic Carbene (NHCs) Counterparts

(2009) Glenn Kuchenbeiser et al.   Chemistry-An Asian Journal

Rhodium-Catalyzed Intramolecular Cycloaddition of Cyclopropene-ynes Triggered by Carbon-Carbon Bond Cleavage

(2009) Takanori Shibata et al.   HETEROCYCLES

Triplet Photochemistry of Vinyl Cyclopropenes: Mechanistic and Exploratory Organic Photochemistry(1, 2)

(2009) Howard E. Zimmerman   JOURNAL OF ORGANIC CHEMISTRY

Acid-Catalyzed Cascade Ring-Opening and Addition Reactions of Arylvinylcyclopropenes with α,β-Unsaturated Substrates, Scope and Limitations

(2009) Zhi-Bin Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

An X−(X = I, Br)-Triggered Ring-Opening Cyclization of Cyclopropenyl-Substituted Alkyl Halides or Mesylates: An Efficient and Highly Regio- and Stereoselective Approach to (E)-Haloalkylidene 4−7-Membered Cyclic Compounds

(2009) Jie Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

The Crossed [2+2] Cycloaddition of 1-Phenylcyclopropene and 1-Bromo-2-phenylcyclopropene

(2009) Gon-Ann Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

Directed Carbozincation Reactions of Cyclopropene Derivatives

(2009) Vinod Tarwade et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Delocalized Triplet Carbene, 5-Methylhexa-1,2,4-triene-1,3-diyl: Matrix IR Identification, Structure, and Reactions

(2009) Sergey E. Boganov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

H-Bonding as a Control Element in Stereoselective Ru-Catalyzed Olefin Metathesis

(2009) Amir H. Hoveyda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic Cation Activation of Alcohols: Conversion to Alkyl Chlorides Using Dichlorodiphenylcyclopropene

(2009) Brendan D. Kelly et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Labeling of Living Cells by a Photo-Triggered Click Reaction

(2009) Andrei A. Poloukhtine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monitoring Block-Copolymer Crossover-Chemistry in ROMP: Catalyst Evaluation via Mass-Spectrometry (MALDI)

(2009) Wolfgang H. Binder et al.   MACROMOLECULES

Palladium(II) Acetate Catalyzed Tandem Cycloisomerization and Oxidation of Arylvinylcyclopropenes Usingp-Benzoquinone as Oxidant and Pro-nucleophile

(2009) Zhi-Bin Zhu et al.   ORGANIC LETTERS

Intramolecular Cyclopropene-Furan [2 + 4] Cycloaddition followed by a Cyclopropylcarbinyl Rearrangement to Synthesize the BCD Rings of Cortistatin A

(2009) Philip Magnus et al.   ORGANIC LETTERS

Highly Substituted 2-Amido-furans From Rh(II)-Catalyzed Cyclopropenations of Ynamides

(2009) Hongyan Li et al.   ORGANIC LETTERS

Ring-Rearrangement Metathesis of Cyclopropenes: Synthesis of Heterocycles

(2009) Frédéric Miege et al.   ORGANIC LETTERS

CpCo-Mediated Reactions of Cyclopropenones: A DFT Study

(2009) Daniel B. Werz et al.   ORGANOMETALLICS

Platinabenzenes: Synthesis, Properties, and Reactivity Studies of a Rare Class of Metalla-aromatics†

(2009) Volker Jacob et al.   ORGANOMETALLICS

Stereo- and regiocontrol in ene-dimerisation and trimerisation of 1-trimethylsilyl-3-phenylcyclopropene

(2009) Andrey E. Sheshenev et al.   TETRAHEDRON

A highly regioselective tandem 1,3-dipolar cycloaddition of cyclopropene 1,1-diesters and nitrile oxides: synthesis of highly functionalized isoxazoles

(2009) Shaojin Chen et al.   TETRAHEDRON

Synthesis of polyfunctionalized vinyl cyclopropanes via the NaI-catalyzed ring-opening cyclization of doubly activated cyclopropenes with 1,1-bis(phenylsulfonyl)ethylene

(2009) Jie Chen et al.   TETRAHEDRON LETTERS

Au-catalyzed isomerization of cyclopropenes: a novel approach to indene derivatives

(2009) Changkun Li et al.   TETRAHEDRON LETTERS

Eight-Step Synthesis of Routiennocin

(2008) Kenji Matsumoto et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Cyclopropanation of Alkenes with Dimethyl Diazomalonate

(2008) Francisco González-Bobes et al.   ADVANCED SYNTHESIS & CATALYSIS

The Joy and Challenge of Small Rings Metathesis

(2008) Karol Grela   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of Tri- and Tetrasubstituted Alkenes by Iron-Catalyzed Carbometalation Ring-Opening Reactions of Cyclopropenes

(2008) Yi Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Nature of the Reactive Intermediates in Gold-Catalyzed Cycloisomerization Reactions

(2008) Alois Fürstner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclopropenyllithiums as a new source of 1,1-bismetalated cyclopropyl derivatives

(2008) Anat Levin et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed silylation of cyclopropenes using (trifluoromethyl)trimethylsilane

(2008) Euan A. F. Fordyce et al.   CHEMICAL COMMUNICATIONS

Gold catalysed reactions with cyclopropenes

(2008) Jürgen T. Bauer et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed hydride transfer from LiAlH4 for the formation of alkylidenecyclopropane derivatives

(2008) Samah Simaan et al.   CHEMICAL COMMUNICATIONS

Ligand Effects in Homogeneous Au Catalysis

(2008) David J. Gorin et al.   CHEMICAL REVIEWS

Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

(2008) Eloísa Jiménez-Núñez et al.   CHEMICAL REVIEWS

Gold(I)-Catalyzed Cycloisomerization of Arylvinylcyclopropenes: An Efficient Synthetic Protocol for the Construction of Indene Skeletons

(2008) Zhi-Bin Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tuning the Nucleophilicity in Cyclopropenylidenes

(2008) Wolfgang W. Schoeller et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Developments in Enantioselective Gold(I) Catalysis

(2008) Ross A. Widenhoefer   CHEMISTRY-A EUROPEAN JOURNAL

Towards Photoswitchable Enediyne Antibiotics: Single and Two-Photon Triggering of Bergman Cyclization

(2008) Andrei Polukhtine et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Photoisomerization Reactions of Cyclopropene and 1,3,3-Trimethylcyclopropene: A Theoretical Study

(2008) Ming-Der Su   Journal of Chemical Theory and Computation

Tetramerization of 3-Methyl-cyclopropene-3-carbonitrile: A Novel CN-Alder-ene Reaction

(2008) Roman V. Ashirov et al.   JOURNAL OF ORGANIC CHEMISTRY

Co-Complexes Derived from Alkene Insertion to Alkyne-Dicobaltpentacarbonyl Complexes: Insight into the Regioselectivity of Pauson−Khand Reactions of Cyclopropenes

(2008) Mahesh K. Pallerla et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Stable Derivatives of Cycloprop-2-ene Carboxylic Acid

(2008) Ni Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

A Computational Study of Chlorocarbene Additions to Cyclooctyne

(2008) Xiao Yu Mo et al.   JOURNAL OF ORGANIC CHEMISTRY

Studies on the Stability of Cycloprop-2-ene Carboxylate Dianions and Reactions with Electrophiles

(2008) Laural A. Fisher et al.   JOURNAL OF ORGANIC CHEMISTRY

Nitrone Cycloadditions to 1,2-Diphenylcyclopropenes and Subsequent Transformations of the Isoxazolidine Cycloadducts

(2008) Vyacheslav V. Diev et al.   JOURNAL OF ORGANIC CHEMISTRY

The Curtius Rearrangement of Cyclopropyl and Cyclopropenoyl Azides. A Combined Theoretical and Experimental Mechanistic Study

(2008) Vinod Tarwade et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Formation of Alkenyl Halides via Magnesium Halide Promoted Ring Opening of Bis-Activated Cyclopropenes

(2008) Yi Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Carbocyclic carbene ligands in palladium-catalyzed C–N coupling reactions

(2008) Christian Taubmann et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Reaction of [M(CO)4]− (M=Ir, Rh) with cyclopropenyl tetrafluoroborate – Ring opening and coupling of cyclopropenyl ligands to form dinuclear metal complexes

(2008) Pek Ke Chan et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Topological and Orbital-Based Mechanisms of the Electronic Stabilization of Bis(Diisopropylamino)Cyclopropenylidene

(2008) Lucius E. Johnson et al.   JOURNAL OF PHYSICAL CHEMISTRY A

A Mechanistic Study on the Photoisomerizations of Spiro[2,4]hept-1-ene, Vinylidenecyclopentane, and Vinylidenecyclobutane Hydrocarbons

(2008) Ming-Der Su   JOURNAL OF PHYSICAL CHEMISTRY A

Rhodium-Catalyzed Hydroformylation of Cyclopropenes

(2008) William M. Sherrill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical Generation and Reversible Cycloaromatization of a Nine-Membered Ring Cyclic Enediyne

(2008) Dinesh R. Pandithavidana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Ring-Opening Metathesis Polymerization of 3-Methyl-3-phenylcylopropene by Molybdenum Alkylidene Initiators

(2008) Rojendra Singh et al.   MACROMOLECULES

Homologous Poly(isobutylene)s: Poly(isobutylene)/High-Density Poly(ethylene) Hybrid Polymers

(2008) Wolfgang H. Binder et al.   MACROMOLECULES

Palladium-Catalyzed Hydrophosphorylation and Hydrophosphinylation of Cyclopropenes

(2008) Bassam K. Alnasleh et al.   ORGANIC LETTERS

The General Synthesis and Trapping of 3-Substituted 1-Chlorocyclopropenes

(2008) Gon-Ann Lee et al.   ORGANIC LETTERS

Synthesis and Application of Alkenylstannanes Derived from Base-Sensitive Cyclopropenes

(2008) Euan A. F. Fordyce et al.   ORGANIC LETTERS

CpCo-Mediated Reactions of Cyclopropenones: Access to CpCo-Capped Benzoquinone Complexes

(2008) Andreea Schuster-Haberhauer et al.   ORGANOMETALLICS

Synthesizability of the Heavy Analogues of Disubstituted Cyclopropenylidene: A Theoretical Study

(2008) B. Pintér et al.   ORGANOMETALLICS

Heterocycles based on the chemistry of alkylidenecyclopropanes and (aza)-cyclopropenes

(2008) Shengming Ma   PURE AND APPLIED CHEMISTRY

Theoretical and experimental studies on the structure and isomerization of isocyano and cyano cyclopolyenes

(2008) O. I. Mikhailova et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Improved preparative route toward 3-arylcyclopropenes

(2008) William M. Sherrill et al.   TETRAHEDRON

Preparation and 13C NMR study on 1-aryl-3,3-difluoro-2-(phenylethynyl)cyclopropenes: long distance Hammett substituent effect

(2008) Shaw-Tao Lin et al.   TETRAHEDRON

A new and simple method for the synthesis of highly functionalised pyrrolizidines, indolizidines and pyrroloazepines

(2008) Paul A. O’Gorman et al.   TETRAHEDRON LETTERS

Chemistry of cyclopropenones: synthesis of new pyrrolo[2,1-b]-1,3,4-oxadiazoles

(2008) Ashraf A. Aly et al.   TETRAHEDRON LETTERS

Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle

(2007) Andrea Correa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the electron delocalization in cyclopropenylidenes – An experimental charge-density approach

(2007) Wolfgang Scherer et al.   INORGANICA CHIMICA ACTA

Facially Selective and Regioselective Carbometalation of Cyclopropenes by Aryl Grignard Reagents

(2007) Ni Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Stable bis(diisopropylamino)cyclopropenylidene (BAC) as ligand for transition metal complexes

(2007) Glenn Kuchenbeiser et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis and reactivity of ruthenium tetrazolate complexes containing a tris(pyrazolyl)borato (Tp) ligand

(2007) Yih-Hsing Lo et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY