Organosulfide-Catalyzed Diboration of Terminal Alkynes under Light

Asymmetric metal free β-boration of α,β-unsaturated imines assisted by (S)-MeBoPhoz

(2015) Enrico La Cascia et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones

(2014) Suttipol Radomkit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Synthesis of Quinolines and Indoles: Sulfur-Assisted or Selenium-Catalyzed Reaction of β-(2-Nitrophenyl)-α,β-unsaturated Ketones with Carbon Monoxide

(2014) Rui Umeda et al.   HETEROATOM CHEMISTRY

Sequential One-Pot Access to Molecular Diversity through Aniline Aqueous Borylation

(2014) William Erb et al.   JOURNAL OF ORGANIC CHEMISTRY

Trans-Diborylation of Alkynes: Pseudo-Intramolecular Strategy Utilizing a Propargylic Alcohol Unit

(2014) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes

(2014) Kazunori Nagao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Arylboronic Pinacol Esters from Corresponding Arylamines

(2014)   ORGANIC SYNTHESES

Direct synthesis of arylboronic pinacol esters from arylamines

(2014) Di Qiu et al.   Organic Chemistry Frontiers

Haloboration of Internal Alkynes with Boronium and Borenium Cations as a Route to Tetrasubstituted Alkenes

(2013) James R. Lawson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Characterization of Boron Complexes of Imidazo[1,5-a]pyridylalkyl Alcohols

(2013) Toshiaki Murai et al.   CHEMISTRY LETTERS

Site-Selective CH Borylation of Quinolines at the C8 Position Catalyzed by a Silica-Supported Phosphane-Iridium System

(2013) Shota Konishi et al.   Chemistry-An Asian Journal

Metal-free borylative ring-opening of vinyl epoxides and aziridines

(2013) Xavier Sanz et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Metal free catalytic hydroboration of multiple bonds in methanol using N-heterocyclic carbenes under open atmosphere

(2013) Kun Wen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Formal Carbon Insertion of N-Tosylhydrazone into B–B and B–Si Bonds: gem-Diborylation and gem-Silylborylation of sp3 Carbon

(2013) Huan Li et al.   ORGANIC LETTERS

Metal-Free, Visible Light-Induced Borylation of Aryldiazonium Salts: A Simple and Green Synthetic Route to Arylboronates

(2012) Jian Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition-Metal-Free Synthesis of Pinacol Alkylboronates from Tosylhydrazones

(2012) Huan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

(2012) Kazuyuki Oshima et al.   CHEMICAL COMMUNICATIONS

Asymmetric synthesis of α-amino boronate esters via organocatalytic pinacolboryl addition to tosylaldimines

(2012) Cristina Solé et al.   CHEMICAL COMMUNICATIONS

Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation

(2012) Di Qiu et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems

(2012) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies into Amine-Mediated Electrophilic Arene Borylation and Its Application in MIDA Boronate Synthesis

(2012) Viktor Bagutski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Ortho C–H Borylation of 2-Phenoxypyridines under Mild Conditions

(2012) Liting Niu et al.   ORGANIC LETTERS

Transition-Metal-Free Borylation of Aryltriazene Mediated by BF3·OEt2

(2012) Chuan Zhu et al.   ORGANIC LETTERS

Catalytic, Direct Synthesis of Bis(boronate) Compounds

(2012) Jun Takaya et al.   ACS Catalysis

Transition-Metal-Free Diboration Reaction by Activation of Diboron Compounds with Simple Lewis Bases

(2011) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Organocatalytic Applications of Imidazol(in)ium-2-thiocarboxylates

(2011) Morgan Hans et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Selenium-catalyzed reductive cyclization and carbocyclization of 2,2′-dinitrostilbenes with carbon monoxide: One-shot synthesis of indolo[1,2-c]quinazolinones

(2011) Rui Umeda et al.   HETEROATOM CHEMISTRY

Synthesis of BN-Fused Polycyclic Aromatics via Tandem Intramolecular Electrophilic Arene Borylation

(2011) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Conversion of Arylamines to Pinacol Boronates: A Metal-Free Borylation Process

(2010) Fanyang Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2009) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Photoinduced highly selective thiophosphination of alkynes using a (PhS)2/(Ph2P)2 binary system

(2008) Takamune Shirai et al.   TETRAHEDRON LETTERS