Diastereodivergent Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides and β-Fluoroalkyl Vinylsulfones: Low Copper(II) Catalyst Loading and Theoretical Studies

Organocatalytic Asymmetric Synthesis of Cyclic Compounds Bearing a Trifluoromethylated Stereogenic Center: Recent Developments

(2019) Xiang-Hong He et al.   ADVANCED SYNTHESIS & CATALYSIS

Umpolung of Imines Enables Catalytic Asymmetric Regio-reversed [3+2] Cycloadditions of Iminoesters with Nitroolefins

(2018) Bin Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of the Spirotropanyl Oxindole Scaffold through Bimetallic Relay Catalysis

(2018) Zhi-Jun Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Catalysis

(2018) Irina P. Beletskaya et al.   CHEMICAL REVIEWS

Modern Approaches for Asymmetric Construction of Carbon–Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs

(2018) Yi Zhu et al.   CHEMICAL REVIEWS

Enantioselective Regiodivergent Synthesis of Chiral Pyrrolidines with Two Quaternary Stereocenters via Ligand-Controlled Copper(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloadditions

(2018) Shan Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Construction of Axially Chiral Sulfone-Containing Styrenes

(2018) Shiqi Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic asymmetric construction of spiropyrrolidines via 1,3-dipolar cycloaddition of azomethine ylides

(2018) Xin Fang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-Catalyzed Highly Regio- and Enantioselective Hydrogenation of Tetrasubstituted Allenyl Sulfones: An Efficient Access to Chiral Allylic Sulfones

(2018) Jiao Long et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Tetrahydroindolizines by Bimetallic Relay Catalyzed Cycloaddition of Pyridinium Ylides

(2018) Dong Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of new fluorinated proline analogues from polyfluoroalkyl β-ketoacetals and ethyl isocyanoacetate

(2018) Nataliya A. Tolmachova et al.   CHEMICAL COMMUNICATIONS

2-Azaallyl Anions, 2-Azaallyl Cations, 2-Azaallyl Radicals, and Azomethine Ylides

(2018) Shaojian Tang et al.   CHEMICAL REVIEWS

Well-Designed Phosphine–Urea Ligand for Highly Diastereo- and Enantioselective 1,3-Dipolar Cycloaddition of Methacrylonitrile: A Combined Experimental and Theoretical Study

(2018) Yang Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergence in Asymmetric Catalysis

(2017) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Fluoropyrrolidines and (Fluoroalkyl)pyrrolidines

(2017) Thierry Lequeux et al.   SYNTHESIS-STUTTGART

Alkenyl Arenes as Dipolarophiles in Catalytic Asymmetric 1,3-Dipolar Cycloaddition Reactions of Azomethine Ylides

(2016) Ana Pascual-Escudero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantiodivergent Combination of Natural Product Scaffolds Enabled by Catalytic Enantioselective Cycloaddition

(2016) Hao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo- and Enantioselective Copper(I)-Catalyzed Intermolecular [3+2] Cycloaddition of Azomethine Ylides with β-Trifluoromethyl β,β-Disubstituted Enones

(2016) Zhan-Ming Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfur Containing Scaffolds in Drugs: Synthesis and Application in Medicinal Chemistry

(2016) Minghao Feng et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Recent Advances in the Synthesis of Sulfones

(2016) Georg Manolikakes et al.   SYNTHESIS-STUTTGART

Catalytic Enantioselective Construction of Sulfur-Containing Tetrasubstituted Carbon Stereocenters

(2016) Jin-Sheng Yu et al.   ACS Catalysis

Aromatic Amide-Derived Non-Biaryl Atropisomers as Highly Efficient Ligands in Silver-Catalyzed Asymmetric Cycloaddition Reactions

(2015) Xing-Feng Bai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions

(2015) Takuya Hashimoto et al.   CHEMICAL REVIEWS

Catalytic Asymmetric Synthesis of Enantioenriched Heterocycles Bearing a CCF3Stereogenic Center

(2015) Yi-Yong Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective 1,3-Dipolar Cycloadditions of Azomethine Ylides for Biology-Oriented Synthesis

(2014) Rishikesh Narayan et al.   ACCOUNTS OF CHEMICAL RESEARCH

PyBidine/Copper Catalyst: Asymmetricexo′-Selective [3+2] Cycloaddition using Imino Ester and Electrophilic Indole

(2014) Atsuko Awata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in the catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides

(2014) Javier Adrio et al.   CHEMICAL COMMUNICATIONS

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

The influence of fluorine in asymmetric catalysis

(2013) Dominique Cahard et al.   CHEMICAL SOCIETY REVIEWS

Phosphoramidite–Cu(OTf)2 Complexes as Chiral Catalysts for 1,3-Dipolar Cycloaddition of Iminoesters and Nitroalkenes

(2013) Luis M. Castelló et al.   ORGANIC LETTERS

Catalytic Asymmetric Synthesis of α-Quaternary Proline Derivatives by 1,3-Dipolar Cycloaddition of α-Silylimines

(2012) Jorge Hernández-Toribio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Partially saturated fluorinated heterocycles: diastereo- and enantioselective synthesis of β-trifluoromethyl-pyrroline carboxylates

(2012) Hiroyuki Kawai et al.   CHEMICAL COMMUNICATIONS

Cu(I)/DTBM-BIPHEP-catalyzed exo-selective 1,3-dipolar cycloaddition of azomethine ylides with cis-trifluorocrotonate for asymmetric construction of trifluoromethylated pyrrolidines

(2012) Qing-Hua Li et al.   TETRAHEDRON LETTERS

An exo- and Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides with Alkylidene Malonates Catalyzed by a N,O-Ligand/Cu(OAc)2-Derived Chiral Complex

(2011) Ming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Organocatalytic Cyclization and Cycloaddition Reactions

(2011) Albert Moyano et al.   CHEMICAL REVIEWS

Fluorinated amino acids: compatibility with native protein structures and effects on protein–protein interactions

(2011) Mario Salwiczek et al.   CHEMICAL SOCIETY REVIEWS

Unusual Ester-Directed Regiochemical Control in endo-Selective Asymmetric 1,3-Dipolar Cycloadditions of Azomethine Ylides with β-Sulfonyl Acrylates

(2011) Min-Chao Tong et al.   CHEMISTRY-A EUROPEAN JOURNAL

NCIPLOT: A Program for Plotting Noncovalent Interaction Regions

(2011) Julia Contreras-García et al.   Journal of Chemical Theory and Computation

Stereodivergency in Catalytic Asymmetric Conjugate Addition Reactions of Glycine (Ket)imines

(2011) Hun Young Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of β-Trifluoromethylated Δ1-Pyrrolines

(2010) Olivier Marrec et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Asymmetric exo′-Selective [3+2] Cycloaddition of Iminoesters with Nitroalkenes

(2010) Takayoshi Arai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cycloadditions and Cyclizations of Acetylenic, Allenic, and Conjugated Dienyl Sulfones†

(2010) Thomas G. Back et al.   CHEMICAL REVIEWS

Asymmetric Construction of Stereogenic Carbon Centers Featuring a Trifluoromethyl Group from Prochiral Trifluoromethylated Substrates

(2010) Jing Nie et al.   CHEMICAL REVIEWS

Chiral Bis(imidazolidine)pyridine−Cu(OTf)2: Catalytic Asymmetric Endo-Selective [3 + 2] Cycloaddition of Imino Esters with Nitroalkenes

(2010) Takayoshi Arai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Silver Amide-Catalyzed Enantioselective [3 + 2] Cycloaddition of α-Aminophosphonates with Olefins

(2010) Yasuhiro Yamashita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Revealing Noncovalent Interactions

(2010) Erin R. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly enantioselective synthesis and cellular evaluation of spirooxindoles inspired by natural products

(2010) Andrey P. Antonchick et al.   Nature Chemistry

Evolving Organic Synthesis Fostered by the Pluripotent Phenylsulfone Moiety

(2009) Ahmad El-Awa et al.   CHEMICAL REVIEWS

Convenient Synthesis ofN-Terminal Tfm-Dipeptides from Unprotected Enantiopure α-Tfm-Proline and α-Tfm-Alanine

(2009) Grégory Chaume et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

An efficient approach to chiral fullerene derivatives by catalytic enantioselective 1,3-dipolar cycloadditions

(2009) Salvatore Filippone et al.   Nature Chemistry

The Phenylsulfonyl Group as a Temporal Regiochemical Controller in the Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides

(2008) Ana López-Pérez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions

(2008) Levi M. Stanley et al.   CHEMICAL REVIEWS

Role of Sulfonamide Group in Matrix Metalloproteinase Inhibitors

(2008) Xian-Chao Cheng et al.   CURRENT MEDICINAL CHEMISTRY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS