Recent Synthesis Developments of Organoboron Compounds via Metal-Free Catalytic Borylation of Alkynes and Alkenes

Electron-Catalyzed Cross-Coupling of Arylboron Compounds with Aryl Iodides

(2018) Keisho Okura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu/Pd cooperatively catalyzed tandem intramolecular anti-Markovnikov hydroarylation of unsaturated amides: facile construction of 3,4-dihydroquinolinones via borylation/intramolecular C(sp3)–C(sp2) cross coupling

(2018) Zhijie Kuang et al.   CHEMICAL COMMUNICATIONS

Transition-metal-free stereoselective borylation of allenamides

(2018) Elena Fernández et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalyst-free chemoselective conjugate addition and reduction of α,β-unsaturated carbonyl compounds via a controllable boration/protodeboronation cascade pathway

(2018) Xi Huang et al.   GREEN CHEMISTRY

Transition-Metal-Free Suzuki-Type Cross-Coupling Reaction of Benzyl Halides and Boronic Acids via 1,2-Metalate Shift

(2018) Zhiqi He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free borylative dearomatization of indoles: exploring the divergent reactivity of aminoborane C–H borylation catalysts

(2018) Arumugam Jayaraman et al.   Chemical Science

Efficient Synthesis of Aryl Boronates via Cobalt-Catalyzed Borylation of Aryl Chlorides and Bromides

(2018) Piyush Kumar Verma et al.   ACS Catalysis

Functionalized geminal-diborylalkanes from various electron-deficient alkynes and B2pin2

(2018) Guoliang Gao et al.   Organic Chemistry Frontiers

Transition-Metal-Free Borylation of Alkynes and Alkenes

(2018) Chun M. Deng et al.   ChemistrySelect

Transition-metal-free synthesis of vicinal triborated compounds and selective functionalisation of the internal C–B bond

(2018) Elliot Davenport et al.   CHEMICAL COMMUNICATIONS

Base-Catalyzed Borylation/B–O Elimination of Propynols and B2pin2 Delivering Tetrasubstituted Alkenylboronates

(2018) Zhijie Kuang et al.   ORGANIC LETTERS

Metal-Free Borylation of Heteroarenes Using Ambiphilic Aminoboranes: On the Importance of Sterics in Frustrated Lewis Pair C–H Bond Activation

(2017) Julien Légaré Lavergne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal-Free trans-Selective Alkynylboration of Alkynes

(2017) Marina Nogami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-metal-free synthesis of 1,1-diboronate esters with a fully substituted benzylic center via diborylation of lithiated carbamates

(2017) Haonan Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Formal nucleophilic borylation and borylative cyclization of organic halides

(2017) K. Kubota et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition-Metal-Free Homologative Cross-Coupling of Aldehydes and Ketones with Geminal Bis(boron) Compounds

(2017) Thomas C. Stephens et al.   ORGANIC LETTERS

Recent Advances in Transition-Metal-Free Aryl C–B Bond Formation

(2017) Ge Meng et al.   SYNTHESIS-STUTTGART

Recent advances in catalytic C−H borylation reactions

(2017) Liang Xu et al.   TETRAHEDRON

Borylation of aryldiazonium salts at room temperature in an aqueous solution under catalyst-free conditions

(2017) Xinxin Qi et al.   TETRAHEDRON LETTERS

Iron-Catalyzed Borylation of Aryl Chlorides in the Presence of Potassium t-Butoxide

(2017) Takumi Yoshida et al.   ACS Catalysis

Catalytic and catalyst-free diboration of alkynes

(2017) Fei Zhao et al.   Organic Chemistry Frontiers

An Alkyne Diboration/6π-Electrocyclization Strategy for the Synthesis of Pyridine Boronic Acid Derivatives

(2016) Helena Mora-Radó et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Borylation of Allylic and Propargylic Alcohols

(2016) Núria Miralles et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes

(2016) Kai Yang et al.   GREEN CHEMISTRY

Direct and Base-Catalyzed Diboration of Alkynes Using the Unsymmetrical Diborane(4), pinB-BMes2

(2016) Chiemi Kojima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbohydrate-Catalyzed Enantioselective Alkene Diboration: Enhanced Reactivity of 1,2-Bonded Diboron Complexes

(2016) Lichao Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective Coupling of 1,1-Bis[(pinacolato)boryl]alkanes for the Transition-Metal-Free Borylation of Aryl and Vinyl Halides: A Combined Experimental and Theoretical Investigation

(2016) Yeosan Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-metal-free hydroboration of terminal alkynes activated by base

(2016) Shibin Hong et al.   TETRAHEDRON LETTERS

Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

(2016) Kohei Harada et al.   Organic Chemistry Frontiers

Synthesis of 1,1-Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

(2015) Akira Morinaga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A mild carbon–boron bond formation from diaryliodonium salts

(2015) N. Miralles et al.   CHEMICAL COMMUNICATIONS

Mixed diboration of alkenes in a metal-free context

(2015) Nuria Miralles et al.   CHEMICAL COMMUNICATIONS

Selective Synthesis of Alkylboronates by Copper(I)-Catalyzed Borylation of Allyl or Vinyl Arenes

(2015) Yanmei Wen et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt Catalyzed Z-Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity

(2015) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric metal free β-boration of α,β-unsaturated imines assisted by (S)-MeBoPhoz

(2015) Enrico La Cascia et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis and application of a dual chiral [2.2]paracyclophane-based N-heterocyclic carbene in enantioselective β-boration of acyclic enones

(2015) Lei Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Enantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones

(2014) Suttipol Radomkit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Clear-Cut Example of Selective BpinBdan Activation and Precise Bdan Transfer on Boron Conjugate Addition

(2014) Jessica Cid et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trans-Diborylation of Alkynes: Pseudo-Intramolecular Strategy Utilizing a Propargylic Alcohol Unit

(2014) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyl-Directed Stereoselective Diboration of Alkenes

(2014) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes

(2014) Hiroto Yoshida et al.   ORGANIC LETTERS

Insertion Reactions into the Boron–Boron Bonds of Barrelene-Type 1,2-Diaminodiboranes(4)

(2014) Steffen Pospiech et al.   ORGANOMETALLICS

Copper-Catalyzed Regioselective Formation of Tri- and Tetrasubstituted Vinylboronates in Air

(2014) Yannick D. Bidal et al.   ACS Catalysis

Cesium Carbonate Mediated Borylation of Aryl Iodides with Diboron in Methanol

(2013) Jieming Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Petasis Reactions of Vinylboronates

(2013) Xianglin Shi et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal free catalytic hydroboration of multiple bonds in methanol using N-heterocyclic carbenes under open atmosphere

(2013) Kun Wen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Increasing the Efficiency of the Transannular Diels–Alder Strategy via Palladium(II)-Catalyzed Macrocyclizations

(2013) Robert G. Iafe et al.   ORGANIC LETTERS

Diborylation of Alkynyl MIDA Boronates and Sequential Chemoselective Suzuki–Miyaura Couplings: A Formal Carboborylation of Alkynes

(2013) Keita Hyodo et al.   ORGANIC LETTERS

Remarkable Catalytic Property of Nanoporous Gold on Activation of Diborons for Direct Diboration of Alkynes

(2013) Qiang Chen et al.   ORGANIC LETTERS

Transition-Metal-Free Synthesis of Pinacol Alkylboronates from Tosylhydrazones

(2012) Huan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Heck Arylation for the Stereoselective Synthesis of Tetrasubstituted Olefins Using Nitroxides as Oxidants

(2012) Zhiheng He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Three-Component Highly Selective Synthesis of Homoallylboronates by Using Metal-Free Catalysis

(2012) Ismail Ibrahem et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems

(2012) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric organocatalytic diboration of alkenes

(2012) Amadeu Bonet et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Essential role of phosphines in organocatalytic β-boration reaction

(2012) Cristina Pubill-Ulldemolins et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

CuCl–K2CO3-catalyzed highly selective borylcupration of internal alkynes – ligand effect

(2012) Weiming Yuan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates

(2012) Mingyu Yang et al.   ORGANIC LETTERS

Transition-Metal-Free Borylation of Aryltriazene Mediated by BF3·OEt2

(2012) Chuan Zhu et al.   ORGANIC LETTERS

Copper-Catalyzed Double Borylation of Silylacetylenes: Highly Regio- and Stereoselective Synthesis of Syn-Vicinal Diboronates

(2012) Ho-Young Jung et al.   ORGANIC LETTERS

Transition-Metal-Free Diboration Reaction by Activation of Diboron Compounds with Simple Lewis Bases

(2011) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of Diboron Reagents with Brønsted Bases and Alcohols: An Experimental and Theoretical Perspective of the Organocatalytic Boron Conjugate Addition Reaction

(2011) Cristina Pubill-Ulldemolins  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spectroscopic and Structural Characterization of the CyNHC Adduct of B2pin2 in Solution and in the Solid State

(2011) Christian Kleeberg et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-catalyzed boration of activated alkynes. Chiral boranes via a one-pot copper-catalyzed boration and reduction protocol

(2011) Ho-Young Jung et al.   TETRAHEDRON

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Opportunity for Mg-Catalyzed Grignard-Type Reactions: Direct Coupling of Benzylic Halides with Pinacolborane with 10 mol % of Magnesium

(2010) Christine Pintaric et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Origins of the Selectivity for Borylation of Primary over Secondary C−H Bonds Catalyzed by Cp*-Rhodium Complexes

(2010) Carolyn S. Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2009) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Theoretical Study of the Asymmetric Conjugate Alkenylation of Enones Catalyzed by Binaphthols

(2008) Robert S. Paton et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereoselective Addition of Zincated Hydrazones to Alkenylboronates and Stereospecific Trapping of Boron/Zinc Bimetallic Intermediates by Carbon Electrophiles

(2008) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Intra/Intermolecular Suzuki Sequence to Benzopyridyloxepines Containing Geometrically Pure Exocyclic Tetrasubstituted Alkenes

(2008) Matthew W. Carson et al.   ORGANIC LETTERS