Catalytic and catalyst-free diboration of alkynes

Gold-Nanoparticle-Catalyzed Mild Diboration and Indirect Silaboration of Alkynes without the Use of Silylboranes

(2017) Marios Kidonakis et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regioselective Synthesis of o-Benzenediboronic Acids via Ir-Catalyzed o-C–H Borylation Directed by a Pyrazolylaniline-Modified Boronyl Group

(2017) Takeshi Yamamoto et al.   ORGANIC LETTERS

An Alkyne Diboration/6π-Electrocyclization Strategy for the Synthesis of Pyridine Boronic Acid Derivatives

(2016) Helena Mora-Radó et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct and Base-Catalyzed Diboration of Alkynes Using the Unsymmetrical Diborane(4), pinB-BMes2

(2016) Chiemi Kojima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Additive- and Metal-Free, Predictably 1,2- and 1,3-Regioselective, Photoinduced Dual C–H/C–X Borylation of Haloarenes

(2016) Adelphe M. Mfuh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced metal-free diboration of alkynes in the presence of organophosphine catalysts

(2016) Aya Yoshimura et al.   TETRAHEDRON

Metal and Metal Oxide Nanoparticles: A Lever for C–H Functionalization

(2016) Daniel Pla et al.   ACS Catalysis

Activated nanostructured bimetallic catalysts for C–C coupling reactions: recent progress

(2016) Rohit Kumar Rai et al.   Catalysis Science & Technology

An experimental and theoretical study into the facile, homogenous (N-heterocyclic carbene)2-Pd(0) catalyzed diboration of internal and terminal alkynes

(2016) Melvyn B. Ansell et al.   Catalysis Science & Technology

Synthesis of Triborylalkenes from Terminal Alkynes by Iridium-Catalyzed Tandem CH Borylation and Diboration

(2015) Chun-I Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc-Catalyzed Dual C-X and C-H Borylation of Aryl Halides

(2015) Shubhankar Kumar Bose et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organosulfide-Catalyzed Diboration of Terminal Alkynes under Light

(2015) Aya Yoshimura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Diboration and Carboboration of Alkynes

(2015) Naohisa Nakagawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic stereoselective addition to alkynes. Borylation or silylation promoted by magnesia-supported iron oxide and cis-diboronation or silaboration by supported platinum nanoparticles

(2015) Anish Khan et al.   JOURNAL OF CATALYSIS

Identification of GDC-0810 (ARN-810), an Orally Bioavailable Selective Estrogen Receptor Degrader (SERD) that Demonstrates Robust Activity in Tamoxifen-Resistant Breast Cancer Xenografts

(2015) Andiliy Lai et al.   JOURNAL OF MEDICINAL CHEMISTRY

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Platinum(0)-Catalyzed Indolyne Insertion into Bis(pinacolato)diboron Followed by Site-Selective Suzuki–Miyaura Cross-Coupling

(2015) Manish Pareek et al.   ORGANIC LETTERS

Boronate ester post-functionalization of PPEs: versatile building blocks for poly(2,2′-(1-(4-(1,2-di(thiophen-2-yl)vinyl)phenyl)-2-(2,5-dioctylphenyl)ethene-1,2-diyl)dithiophene) and application in field effect transistors

(2015) Junwei Yang et al.   Journal of Materials Chemistry C

Solvent- and Ligand-free Diboration of Alkynes and Alkenes Catalyzed by Platinum Nanoparticles on Titania

(2014) Francisco Alonso et al.   ChemCatChem

Glucocorticoid Receptor Modulators Informed by Crystallography Lead to a New Rationale for Receptor Selectivity, Function, and Implications for Structure-Based Design

(2014) Matthew W. Carson et al.   JOURNAL OF MEDICINAL CHEMISTRY

Trans-Diborylation of Alkynes: Pseudo-Intramolecular Strategy Utilizing a Propargylic Alcohol Unit

(2014) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borylation of Propargylic Substrates by Bimetallic Catalysis. Synthesis of Allenyl, Propargylic, and Butadienyl Bpin Derivatives

(2014) Tony S. N. Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of most polyene natural product motifs using just 12 building blocks and one coupling reaction

(2014) Eric M. Woerly et al.   Nature Chemistry

Influence of Fluorination and Boronic Group Synergy on the Acidity and Structural Behavior of o-Phenylenediboronic Acids

(2014) Krzysztof Durka et al.   ORGANOMETALLICS

Insertion Reactions into the Boron–Boron Bonds of Barrelene-Type 1,2-Diaminodiboranes(4)

(2014) Steffen Pospiech et al.   ORGANOMETALLICS

High-Yield Syntheses and Reactivity Studies of 1,2-Diborylated and 1,2,4,5-Tetraborylated Benzenes

(2014) Ömer Seven et al.   ORGANOMETALLICS

Borylated Dibenzoborepin: Synthesis by Skeletal Rearrangement and Photochromism Based on Bora-Nazarov Cyclization

(2013) Azusa Iida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PSiP-Pincer Type Palladium-Catalyzed Dehydrogenative Borylation of Alkenes and 1,3-Dienes

(2013) Naohiro Kirai et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts

(2013) Fu-She Han   CHEMICAL SOCIETY REVIEWS

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Conversion oftrans-Diboran(4)yl Platinum Complexes into Theircis-Bisboryl Analogues

(2013) Holger Braunschweig et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nanotubular Hydrogen-Bonded Organic Framework Architecture of 1,2-Phenylenediboronic Acid Hosting Ice Clusters

(2013) Krzysztof Durka et al.   CRYSTAL GROWTH & DESIGN

Hydroboration of Alkyne-Functionalized 1,3,2-Benzodiazaboroles

(2013) Lothar Weber et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis, Photophysics, and Electrochemistry of Tetra(2-thienyl)ethylene (TTE) Derivatives

(2013) Alessandro Bolzoni et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The Influence of Boronate Groups on the Selectivity of the Br-Li Exchange in Model Dibromoaryl Boronates

(2013) Krzysztof Durka et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Selective Synthesis of Multisubstituted Olefins Utilizing gem- and vic-Diborylated Vinylsilanes Prepared by Silylborylation of an Alkynylboronate and Diborylation of Alkynylsilanes

(2013) Jiao Jiao et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Dehydrogenative Borylation of Terminal Alkynes by a SiNN Pincer Complex of Iridium

(2013) Chun-I Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploration of 1,2-phenylenediboronic esters as potential bidentate catalysts for organic synthesis

(2013) Samuel L. Bader et al.   MONATSHEFTE FUR CHEMIE

Diborylation of Alkynyl MIDA Boronates and Sequential Chemoselective Suzuki–Miyaura Couplings: A Formal Carboborylation of Alkynes

(2013) Keita Hyodo et al.   ORGANIC LETTERS

Remarkable Catalytic Property of Nanoporous Gold on Activation of Diborons for Direct Diboration of Alkynes

(2013) Qiang Chen et al.   ORGANIC LETTERS

Concise synthesis of tylophorine

(2013) Qi-Xian Lin et al.   TETRAHEDRON

Oxidative Heck Arylation for the Stereoselective Synthesis of Tetrasubstituted Olefins Using Nitroxides as Oxidants

(2012) Zhiheng He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1H-Phosphindoles as Structural Units in the Synthesis of Chiral Helicenes

(2012) Keihann Yavari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Coupling, and Condensation Reactions of 1,2-Diborylated Benzenes: An Experimental and Quantum-Chemical Study

(2012) Ömer Seven et al.   CHEMISTRY-A EUROPEAN JOURNAL

Low driving voltage characteristics of triphenylene derivatives as electron transport materials in organic light-emitting diodes

(2012) Kazunori Togashi et al.   JOURNAL OF MATERIALS CHEMISTRY

Decorating BODIPY with Three- and Four-Coordinate Boron Groups

(2012) Jia-sheng Lu et al.   ORGANIC LETTERS

Enantioselective Total Synthesis of (+)-Lithospermic Acid

(2012) Arun K. Ghosh et al.   ORGANIC LETTERS

Catalytic, Direct Synthesis of Bis(boronate) Compounds

(2012) Jun Takaya et al.   ACS Catalysis

Nickel Nanoparticles in Hydrogen Transfer Reactions

(2011) Francisco Alonso et al.   ACCOUNTS OF CHEMICAL RESEARCH

Three-Component Coupling of Arynes and Organic Bromides

(2011) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Borylation Reactions of Alkynes and Arynes

(2011) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Single (Copper) or Double (Platinum) Boronation of Alkynes Catalyzed by Magnesia-Supported Copper Oxide or Platinum Nanoparticles

(2011) Abdessamad Grirrane et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkynylboronates and -boramides in CoI- and RhI-Catalyzed [2+2+2] Cycloadditions: Construction of Oligoaryls through Selective Suzuki Couplings

(2011) Laura Iannazzo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Efficient Synthesis of Diborylalkenes from Alkenes and Diboron by a New PSiP-Pincer Palladium-Catalyzed Dehydrogenative Borylation

(2011) Jun Takaya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diboration of Dialkynes with [2]Boraferrocenophanes

(2011) Florian Bauer et al.   ORGANOMETALLICS

Palladium-catalyzed double cross-coupling reaction of 1,2-bis(pinacolatoboryl)alkenes and -arenes with 2,2′-dibromobiaryls: annulative approach to functionalized polycyclic aromatic hydrocarbons

(2011) Masaki Shimizu et al.   TETRAHEDRON

Selective CH Borylation of Alkenes by Palladium Pincer Complex Catalyzed Oxidative Functionalization

(2010) Nicklas Selander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes

(2010) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Boronic Acids and Esters in the Petasis-Borono Mannich Multicomponent Reaction

(2010) Nuno R. Candeias et al.   CHEMICAL REVIEWS

Synthesis and Reactivity of Boron-, Silicon-, and Tin-Bridged ansa-Cyclopentadienyl-Cycloheptatrienyl Titanium Complexes (Troticenophanes)

(2010) Holger Braunschweig et al.   CHEMISTRY-A EUROPEAN JOURNAL

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

(2010) Noriyuki Iwadate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Switching from Dimerization to Cyclotrimerization Selectivity by FeCl3in the Y[N(TMS)2]3-Catalyzed Transformation of Terminal Alkynes: A New Strategy for Controlling the Selectivity of Organolanthanide-Based Catalysis

(2010) Xiuli Bu et al.   ORGANOMETALLICS

Ethynyl MIDA boronate: a readily accessible and highly versatile building block for small molecule synthesis

(2010) Justin R. Struble et al.   TETRAHEDRON

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Double Cross-Coupling Reaction of vic-Diborylalkenes and -arenes with vic-Bromo(bromomethyl)arenes

(2009) Masaki Shimizu et al.   SYNLETT

Microwave enhanced synthesis

(2009) Stephen Caddick et al.   TETRAHEDRON

Palladium-Catalyzed Annulation ofvic-Bis(pinacolatoboryl)alkenes and -phenanthrenes with 2,2′-Dibromobiaryls: Facile Synthesis of Functionalized Phenanthrenes and Dibenzo[g,p]chrysenes

(2008) Masaki Shimizu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diels–Alder Reaction of 2,3-Bis(pinacolatoboryl)-1,3-butadiene: Facile Preparation of 1,2-Bis(pinacolatoboryl)cyclohexenes and -1,4-cyclohexadiene

(2008) Masaki Shimizu et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Synthesis, Reactivity, and Electronic Structure of [n]Vanadoarenophanes: An Experimental and Theoretical Study

(2008) Holger Braunschweig et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentially Protected Benzenediboronic Acids:  Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

(2008) Hiroyoshi Noguchi et al.   ORGANIC LETTERS

An Intra/Intermolecular Suzuki Sequence to Benzopyridyloxepines Containing Geometrically Pure Exocyclic Tetrasubstituted Alkenes

(2008) Matthew W. Carson et al.   ORGANIC LETTERS

Polyborylated reagents for modern organic synthesis

(2008) Masaki SHIMIZU et al.   PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES

Microwave-assisted one-pot diboration/Suzuki cross-couplings. A rapid route to tetrasubstituted alkenes

(2008) Hana Prokopcová et al.   TETRAHEDRON LETTERS

Simple, Efficient, and Modular Syntheses of Polyene Natural Products via Iterative Cross-Coupling

(2007) Suk Joong Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY