Enantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Basic CuCO3/ligand as a new catalyst for 'on water' borylation of Michael acceptors, alkenes and alkynes: application to the efficient asymmetric synthesis of β-alcohol type sitagliptin side chain

(2013) Gaj Stavber et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective One-pot Aminoborylation of Aldehydes: A Strategy for Construction of Nonracemic α-Amino Boronates

(2013) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NHC–Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism

(2013) Fanke Meng et al.   ORGANIC LETTERS

Chiral NHC/Cu(I)-Catalyzed Asymmetric Hydroboration of Aldimines: Enantioselective Synthesis of α-Amido Boronic Esters

(2013) Ping Tian et al.   SYNLETT

Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron

(2012) Weiming Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Chiral Copper(II)-Catalyzed Enantioselective Boron Conjugate Additions to α,β-Unsaturated Carbonyl Compounds in Water

(2012) Shū Kobayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iterative Asymmetric Allylic Substitutions: syn- and anti-1,2-Diols through Catalyst Control

(2012) Jin Kyoon Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric synthesis of α-amino boronate esters via organocatalytic pinacolboryl addition to tosylaldimines

(2012) Cristina Solé et al.   CHEMICAL COMMUNICATIONS

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiocontrolled CuI-Catalyzed Borylation of Propargylic-Functionalized Internal Alkynes

(2012) Abraham L. Moure et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Catalytic Hydroboration of Propargylic Species Using Cu(I)-NHC Complexes

(2012) Jin Kyoon Park et al.   ORGANIC LETTERS

Catalytic, Direct Synthesis of Bis(boronate) Compounds

(2012) Jun Takaya et al.   ACS Catalysis

Modular Monodentate Oxaphospholane Ligands: Utility in Highly Efficient and Enantioselective 1,4-Diboration of 1,3-Dienes

(2011) Christopher H. Schuster et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Construction of Quaternary Stereogenic Centers from Tertiary Boronic Esters: Methodology and Applications

(2011) Ravindra P. Sonawane et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective 1,2-Diboration of 1,3-Dienes: Versatile Reagents for Stereoselective Allylation

(2011) Laura T. Kliman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic asymmetric conjugate boration of α,β-unsaturated sulfones

(2011) Abraham L. Moure et al.   CHEMICAL COMMUNICATIONS

Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles

(2011) Eduard Hartmann et al.   CHEMICAL COMMUNICATIONS

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Metal-Free Catalytic C–Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2011) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoconvergent Synthesis of Chiral Allylboronates from anE/ZMixture of Allylic Aryl Ethers Using a 6-NHC−Cu(I) Catalyst

(2011) Jin Kyoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Enantioselective total synthesis and absolute configuration of the alleged structure of crassinervic acid

(2011) Jyotsna N. Chakor et al.   TETRAHEDRON

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conjugate Boration of β,β-Disubstituted Unsaturated Esters: Asymmetric Synthesis of Functionalized Chiral Tertiary Organoboronic Esters

(2010) Xinhui Feng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters

(2010) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

(2010) Hajime Ito et al.   Nature Chemistry

Synthesis of the Tetracyclic Core of Tetrapetalone A Enabled by a Pyrrole Reductive Alkyation

(2010) Andrew P. Marcus et al.   ORGANIC LETTERS

Copper(I)−Secondary Diamine Complex-Catalyzed Enantioselective Conjugate Boration of Linear β,β-Disubstituted Enones

(2010) I-Hon Chen et al.   ORGANIC LETTERS

A Chiral 6-MemberedN-Heterocyclic Carbene Copper(I) Complex That Induces High Stereoselectivity

(2010) Jin Kyoon Park et al.   ORGANIC LETTERS

Copper-Catalyzed Conjugate Addition of Diboron Reagents to α,β-Unsaturated Amides: Highly Reactive Copper-1,2- Bis(diphenylphosphino)benzene Catalyst System

(2009) Heesung Chea et al.   ADVANCED SYNTHESIS & CATALYSIS

Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes

(2009) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

(2009) Xinhui Feng et al.   CHEMICAL COMMUNICATIONS

Bis(imidazoline-2-thione)–copper(i) catalyzed regioselective boron addition to internal alkynes

(2009) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Enantioselective β-Boration of Acyclic Enones

(2009) Hak-Suk Sim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Monodentate Non-C2-symmetric ChiralN-Heterocyclic Carbene Complexes for Enantioselective Synthesis. Cu-Catalyzed Conjugate Additions of Aryl- and Alkenylsilylfluorides to Cyclic Enones

(2009) Kang-sang Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric 1,4-Dihydroxylation of 1,3-Dienes by Catalytic Enantioselective Diboration

(2009) Heather E. Burks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pt-Catalyzed Enantioselective Diboration of Terminal Alkenes with B2(pin)2

(2009) Laura T. Kliman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2009) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones

(2009) I-Hon Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines

(2008) Masakatsu Shibasaki et al.   CHEMICAL REVIEWS

Asymmetric Copper-Catalyzed Synthesis of α-Amino Boronate Esters fromN-tert-Butanesulfinyl Aldimines

(2008) Melissa A. Beenen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Boration of Acyclic α,β-Unsaturated Esters and Nitriles

(2007) Ji-Eon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A dipseudoacid, C16H18O6

(2007) Dmitriy V. Liskin et al.   JOURNAL OF MOLECULAR STRUCTURE