Multi-Functionality of Methanol in Sustainable Catalysis: Beyond Methanol Economy

Recent Advances On Direct Formylation Reactions

(2023) Aditya Kherudkar et al.   CHEMICAL RECORD

N-Alkylation of Amines by C1–C10 Aliphatic Alcohols Using A Well-Defined Ru(II)-Catalyst. A Metal–Ligand Cooperative Approach

(2023) Amit Kumar Guin et al.   Journal of Organic Chemistry

Methanol as a Potential Hydrogen Source for Reduction Reactions Enabled by a Commercial Pt/C Catalyst

(2023) Vishakha Goyal et al.   Journal of Organic Chemistry

Statistical and analytical investigation of methanol applications, production technologies, value-chain and economy with a special focus on renewable methanol

(2023) Seyed Shayan Tabibian et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

General and selective homogeneous Ru-catalyzed transfer hydrogenation, deuteration, and methylation of functional compounds using methanol

(2023) Murugan Subaramanian et al.   JOURNAL OF CATALYSIS

Recent Developments for the Deuterium and Tritium Labeling of Organic Molecules

(2022) Sara Kopf et al.   CHEMICAL REVIEWS

Perspective on the hydrogen economy as a pathway to reach net-zero CO2 emissions in Europe

(2022) Mijndert van der Spek et al.   Energy & Environmental Science

Investigation of NNN Pincer Ruthenium(II) Complexes with a Pendant Hydroxyl Group for N‐Monomethylation of amines and Nitroarenes by Methanol

(2022) Kangkang Li et al.   ChemCatChem

Homogeneous Hydrogenation of CO2 and CO to Methanol: The Renaissance of Low Temperature Catalysis in the Context of the Methanol Economy

(2022) Surya G. Prakash et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methanol fuel production, utilization, and techno-economy: a review

(2022) Tanmay J. Deka et al.   Environmental Chemistry Letters

Iron-Catalyzed α-Methylation of Ketones Using Methanol as the C1 Source under Photoirradiation

(2022) Balakumar Emayavaramban et al.   ORGANIC LETTERS

Well-Defined Bis(NHC)Mn(I) Complex Catalyzed Tandem Transformation of α,β-Unsaturated Ketones to α-Methylated Ketones Using Methanol

(2022) Kasturi Ganguli et al.   ACS Catalysis

Toward a Hydrogen Economy: Development of Heterogeneous Catalysts for Chemical Hydrogen Storage and Release Reactions

(2022) Duo Wei et al.   ACS Energy Letters

Methanol as a greener C1 synthon under non-noble transition metal-catalyzed conditions

(2022) Sheetal et al.   COORDINATION CHEMISTRY REVIEWS

Sustainable and Affordable Synthesis of (Deuterated) N-Methyl/Ethyl Amines from Nitroarenes

(2022) Akash Mondal et al.   Organic Letters

α-Methylation of Ketones and Indoles Catalyzed by a Manganese(I) PCNHCP Pincer Complex with Methanol as a C1 Source

(2022) Ranjeesh Thenarukandiyil et al.   Organometallics

Simple RuCl3‐catalyzed N‐Methylation of Amines and Transfer Hydrogenation of Nitroarenes using Methanol

(2021) Kishore Natte et al.   ChemCatChem

N-Methylation of Amines with Methanol in the Presence of Carbonate Salt Catalyzed by a Metal–Ligand Bifunctional Ruthenium Catalyst [(p-cymene)Ru(2,2′-bpyO)(H2O)]

(2021) Peng Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent developments on methanol as liquid organic hydrogen carrier in transfer hydrogenation reactions

(2021) Nidhi Garg et al.   COORDINATION CHEMISTRY REVIEWS

Rhenium(I)-Catalyzed C-Methylation of Ketones, Indoles, and Arylacetonitriles Using Methanol

(2021) Sujan Shee et al.   JOURNAL OF ORGANIC CHEMISTRY

Moving ahead from hydrogen to methanol economy: scope and challenges

(2021) Ankit Sonthalia et al.   Clean Technologies and Environmental Policy

Ru-Catalyzed Selective Catalytic Methylation and Methylenation Reaction Employing Methanol as the C1 Source

(2021) Nandita Biswas et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly efficient NHC-iridium-catalyzed β-methylation of alcohols with methanol at low catalyst loadings

(2021) Zeye Lu et al.   Science China-Chemistry

Recent developments in reductive N-methylation with base-metal catalysts

(2021) Vishakha Goyal et al.   TETRAHEDRON

Single-atom catalyst for high-performance methanol oxidation

(2021) Zhiqi Zhang et al.   Nature Communications

Identification of active catalysts for the acceptorless dehydrogenation of alcohols to carbonyls

(2021) Tao Wang et al.   Nature Communications

N ‐Monomethylation of Amines with Methanol by Syndiotactic Poly(aminostyrene)‐supported Palladium Nanoparticle Catalyst

(2021) Lei Jiang et al.   Asian Journal of Organic Chemistry

Oxidative N-Formylation of Secondary Amines Catalyzed by Reusable Bimetallic AuPd–Fe3O4 Nanoparticles

(2021) Sabyuk Yang et al.   Nanomaterials

Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics

(2021) Amit Kumar et al.   CHEMICAL REVIEWS

Cp*Ir complex bearing a flexible bridging and functional 2,2′-methylenebibenzimidazole ligand as an auto-tandem catalyst for the synthesis of N-methyl tertiary amines from imines via transfer hydrogenation/N-methylation with methanol

(2021) Xiaozhong Chen et al.   JOURNAL OF CATALYSIS

Reusable Co-nanoparticles for general and selective N-alkylation of amines and ammonia with alcohols

(2021) Zhuang Ma et al.   Chemical Science

Recent Advances in Liquid Organic Hydrogen Carriers: An Alcohol-Based Hydrogen Economy

(2021) Vinita Yadav et al.   ACS Catalysis

Copper‐Catalyzed Formylation of Amines by using Methanol as the C1 Source

(2020) Manuel Carmona Pichardo et al.   ChemSusChem

A Review of The Methanol Economy: The Fuel Cell Route

(2020) Samuel Simon Araya et al.   Energies

Manganese-Catalyzed One-Pot Conversion of Nitroarenes into N -Methylarylamines Using Methanol

(2020) Benjamin G. Reed-Berendt et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ruthenium(II) Complexes of Heteroditopic N-Heterocyclic Carbene Ligands: Efficient Catalysts for C–N Bond Formation via a Hydrogen-Borrowing Strategy under Solvent-Free Conditions

(2020) S. N. R. Donthireddy et al.   INORGANIC CHEMISTRY

Transfer Hydrogenation of Ketones and Imines with Methanol under Base-Free Conditions Catalyzed by an Anionic Metal–Ligand Bifunctional Iridium Catalyst

(2020) Rongzhou Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium Pincer Complex Catalyzed Selective Synthesis of C‐3 Alkylated Indoles and Bisindolylmethanes Directly from Indoles and Alcohols

(2020) Nandita Biswas et al.   ADVANCED SYNTHESIS & CATALYSIS

Cu/Al2O3 Catalyst Prepared by a Double Hydrolysis Method for a Green, Continuous and Controlled N-Methylation Reaction of Nitroarenes with Methanol

(2020) Hao Zhang et al.   APPLIED SURFACE SCIENCE

Efficient Transfer Hydrogenation of Ketones using Methanol as Liquid Organic Hydrogen Carrier

(2020) Nidhi Garg et al.   ChemCatChem

N-Methylation of Amines with Methanol in Aqueous Solution Catalyzed by a Water-Soluble Metal–Ligand Bifunctional Dinuclear Iridium Catalyst

(2020) Chong Meng et al.   JOURNAL OF ORGANIC CHEMISTRY

Methanol as the Hydrogen Source in the Selective Transfer Hydrogenation of Alkynes Enabled by a Manganese Pincer Complex

(2020) Jan Sklyaruk et al.   ORGANIC LETTERS

Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature

(2020) Zhenyu Chen et al.   Asian Journal of Organic Chemistry

Selective mono-N-methylation of nitroarenes with methanol catalyzed by atomically dispersed NHC-Ir solid assemblies

(2020) Jiaquan Wang et al.   JOURNAL OF CATALYSIS

Bimetallic Bis-NHC-Ir(III) Complex Bearing 2-Arylbenzo[d]oxazolyl Ligand: Synthesis, Catalysis, and Bimetallic Effects

(2020) Shuang Huang et al.   ORGANOMETALLICS

A comprehensive review of hydrogen production from methanol thermochemical conversion for sustainability

(2020) Gabriel Garcia et al.   ENERGY

Applications of deuterium in medicinal chemistry

(2019) Tracey Pirali et al.   JOURNAL OF MEDICINAL CHEMISTRY

Selective N‐Monomethylation of Amines and Nitroarenes using Methanol over an Encapsulated Iridium Nanocatalyst

(2019) Aixiao Fu et al.   Asian Journal of Organic Chemistry

N-Methylation of amines and nitroarenes with methanol using heterogeneous platinum catalysts

(2019) Md.A.R. Jamil et al.   JOURNAL OF CATALYSIS

Palladium-Catalyzed Methylation of Nitroarenes with Methanol

(2019) Lin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)‐Catalyzed β ‐Methylation of Alcohols using Methanol as C 1 Source

(2019) Akash Kaithal et al.   ChemCatChem

α-Methylation of Ketones with Methanol Catalyzed by Ni/SiO2 -Al2 O3

(2019) Aubin Charvieux et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed α-Methylation of α-Aryl Esters Using Methanol as the C1 Source

(2019) Yuya Tsukamoto et al.   ORGANIC LETTERS

Iron-Catalyzed Tandem Three-Component Alkylation: Access to α-Methylated Substituted Ketones

(2019) Léo Bettoni et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Synthesis of N-Methylated Amides using Methanol

(2019) Bhaskar Paul et al.   ORGANIC LETTERS

Tandem Transformation of Aldoximes to N‐Methylated Amides using Methanol

(2019) Bhaskar Paul et al.   ADVANCED SYNTHESIS & CATALYSIS

N-Methylation Of Nitrogen-Containing Organic Substrates: A Comprehensive Overview

(2019) Saad Moulay   CURRENT ORGANIC CHEMISTRY

Palladacycle-Phosphine Catalyzed Methylation of Amines and Ketones Using Methanol

(2019) Ramesh Mamidala et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols

(2019) Kurt Polidano et al.   ACS Catalysis

Manganese(I)-Catalyzed β-Methylation of Alcohols Using Methanol as C1 Source

(2019) Akash Kaithal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Commercial Pd/C-Catalyzed N-Methylation of Nitroarenes and Amines Using Methanol as Both C1 and H2 Source

(2019) Vishakha Goyal et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed β-Alkylation of Alcohols

(2019) Léo Bettoni et al.   ORGANIC LETTERS

Atom-Economical and Tandem Conversion of Nitriles to N-Methylated Amides Using Methanol and Water

(2019) Bhaskar Paul et al.   ACS Catalysis

Manganese-Catalyzed β-Methylation of Alcohols by Methanol

(2019) Martin Schlagbauer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Monomethylation of Amines with Methanol as the C1 Source

(2018) Geunho Choi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Integrative CO2 Capture and Hydrogenation to Methanol with Reusable Catalyst and Amine: Toward a Carbon Neutral Methanol Economy

(2018) Sayan Kar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Monomethylation of Aromatic Amines with Methanol via PNHP-Pincer Ru Catalysts

(2018) Osamu Ogata et al.   ORGANIC LETTERS

Direct Synthesis of N,N-Dimethylated and β-Methyl N,N-Dimethylated Amines from Nitriles Using Methanol: Experimental and Computational Studies

(2018) Bhaskar Paul et al.   ACS Catalysis

C-Methylation of Alcohols, Ketones, and Indoles with Methanol Using Heterogeneous Platinum Catalysts

(2018) S. M. A. Hakim Siddiki et al.   ACS Catalysis

Iron-Catalyzed Methylation Using the Borrowing Hydrogen Approach

(2018) Kurt Polidano et al.   ACS Catalysis

N-Alkylation of functionalized amines with alcohols using a copper–gold mixed photocatalytic system

(2018) Lyu-Ming Wang et al.   Scientific Reports

Current advance in bioconversion of methanol to chemicals

(2018) Wenming Zhang et al.   Biotechnology for Biofuels

Methanol as hydrogen source: Transfer Hydrogenation of Aromatic Aldehydes with a Rhodacycle

(2018) Ahmed H. Aboo et al.   CHEMICAL COMMUNICATIONS

Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study

(2018) Duo Wei et al.   JOURNAL OF CATALYSIS

Well-Defined Phosphine-Free Iron-Catalyzed N-Ethylation and N-Methylation of Amines with Ethanol and Methanol

(2018) Alexis Lator et al.   ORGANIC LETTERS

Nickel-Catalyzed Hydrogen-Borrowing Strategy for α-Alkylation of Ketones with Alcohols: A New Route to Branched gem-Bis(alkyl) Ketones

(2018) Jagadish Das et al.   ORGANIC LETTERS

Methylation of Amines and Ketones with Methanol Catalyzed by an Iridium Complex Bearing a 2-Hydroxypyridylmethylene Fragment

(2018) Danfeng Deng et al.   ORGANOMETALLICS

Efficient and Versatile Catalytic Systems for the N-Methylation of Primary Amines with Methanol Catalyzed by N-Heterocyclic Carbene Complexes of Iridium

(2018) Ken-ichi Fujita et al.   SYNTHESIS-STUTTGART

Catalytic C1  Alkylation with Methanol and Isotope-Labeled Methanol

(2018) Jan Sklyaruk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer

(2018) Torsten Irrgang et al.   CHEMICAL REVIEWS

Recent Advances in Methylation: A Guide for Selecting Methylation Reagents

(2018) Yantao Chen   CHEMISTRY-A EUROPEAN JOURNAL

Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates

(2018) Lyu-Ming Wang et al.   ACS Sustainable Chemistry & Engineering

Selective N-Formylation and N-Methylation of Amines Using Methanol as a Sustainable C1 Source

(2018) Geunho Choi et al.   ACS Sustainable Chemistry & Engineering

Mono- N -methylation of anilines with methanol catalyzed by a manganese pincer-complex

(2017) Antoine Bruneau-Voisine et al.   JOURNAL OF CATALYSIS

Manganese-Catalyzed Aminomethylation of Aromatic Compounds with Methanol as a Sustainable C1 Building Block

(2017) Matthias Mastalir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Methylation of Amines with Methanol Catalyzed by a Cp*Ir Complex Bearing a Functional 2,2′-Bibenzimidazole Ligand

(2017) Ran Liang et al.   ORGANIC LETTERS

Methylation of C(sp3)–H/C(sp2)–H Bonds with Methanol Catalyzed by Cobalt System

(2017) Zhenghui Liu et al.   ORGANIC LETTERS

Utilization of MeOH as a C1 Building Block in Tandem Three-Component Coupling Reaction

(2017) Kaushik Chakrabarti et al.   ORGANIC LETTERS

Iron-Catalyzed Amide Formation from the Dehydrogenative Coupling of Alcohols and Secondary Amines

(2017) Elizabeth M. Lane et al.   ORGANOMETALLICS

Sustainable and Selective Monomethylation of Anilines by Methanol with Solid Molecular NHC-Ir Catalysts

(2017) Jiangbo Chen et al.   ACS Sustainable Chemistry & Engineering

Selective Transfer Hydrogenation of Biomass-Based Furfural and 5-Hydroxymethylfurfural over Hydrotalcite-Derived Copper Catalysts Using Methanol as a Hydrogen Donor

(2017) Jun Zhang et al.   ACS Sustainable Chemistry & Engineering

Supported Palladium Nanoparticle Catalyzed α-Alkylation of Ketones Using Alcohols as Alkylating Agents

(2017) C. Bal Reddy et al.   ACS Sustainable Chemistry & Engineering

A Convenient Ruthenium-Catalysed α-Methylation of Carbonyl Compounds using Methanol

(2016) Tuan Thanh Dang et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic conversion of methanol/ethanol to isobutanol – a highly selective route to an advanced biofuel

(2016) Richard L. Wingad et al.   CHEMICAL COMMUNICATIONS

Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes

(2016) Saravanakumar Elangovan et al.   Nature Communications

Hydrogen Acceptor- and Base-FreeN-Formylation of Nitriles and Amines using Methanol as C1Source

(2015) Byungjoon Kang et al.   ADVANCED SYNTHESIS & CATALYSIS

Towards a methanol economy based on homogeneous catalysis: methanol to H2 and CO2 to methanol

(2015) E. Alberico et al.   CHEMICAL COMMUNICATIONS

The Golden Age of Transfer Hydrogenation

(2015) Dong Wang et al.   CHEMICAL REVIEWS

CC Coupling of Ketones with Methanol Catalyzed by a N-Heterocyclic Carbene-Phosphine Iridium Complex

(2015) Xu Quan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Methanol Dehydrogenation by Iridium N-Heterocyclic Carbene Complexes

(2015) Jesús Campos et al.   INORGANIC CHEMISTRY

Highly Selective Formation of n-Butanol from Ethanol through the Guerbet Process: A Tandem Catalytic Approach

(2015) Sumit Chakraborty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohols as alkylating agents in heteroarene C–H functionalization

(2015) Jian Jin et al.   NATURE

N-Methylation of Amines with Methanol at Room Temperature

(2015) Vasily N. Tsarev et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Urea Synthesis Using Methanol as the C1 Source

(2015) Seung Hyo Kim et al.   ORGANIC LETTERS

Efficient Ruthenium-Catalyzed N-Methylation of Amines Using Methanol

(2015) Tuan Thanh Dang et al.   ACS Catalysis

Iridium-catalyzed methylation of indoles and pyrroles using methanol as feedstock

(2015) Shu-Jie Chen et al.   RSC Advances

Light-promoted N,N-dimethylation of amine and nitro compound with methanol catalyzed by Pd/TiO2 at room temperature

(2015) Lina Zhang et al.   RSC Advances

Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock

(2014) Yang Li et al.   CHEMICAL COMMUNICATIONS

Iridium-catalyzed selective α-methylation of ketones with methanol

(2014) Shinji Ogawa et al.   CHEMICAL COMMUNICATIONS

Bond Activation and Catalysis by Ruthenium Pincer Complexes

(2014) Chidambaram Gunanathan et al.   CHEMICAL REVIEWS

Profound Methyl Effects in Drug Discovery and a Call for New CH Methylation Reactions

(2013) Heike Schönherr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Ketone Methylation Using Methanol Under Mild Conditions: Formation of α-Branched Products

(2013) Louis K. M. Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Aerobic Oxidation of Methanol in the Coexistence of Amines by Nanoporous Gold Catalysts: Highly Efficient Synthesis of Formamides

(2013) Shinya Tanaka et al.   CHEMISTRY-A EUROPEAN JOURNAL

A step closer to a methanol economy

(2013) Douglas W. Stephan   NATURE

N-Formylation of Amines by Methanol Activation

(2013) Nuria Ortega et al.   ORGANIC LETTERS

Nickel-Catalyzed Alkylation and Transfer Hydrogenation of α,β-Unsaturated Enones with Methanol

(2012) Nahury Castellanos-Blanco et al.   ORGANOMETALLICS

General and efficient method for direct N-monomethylation of aromatic primary amines with methanol

(2012) Feng Li et al.   RSC Advances

The Methylation Effect in Medicinal Chemistry

(2011) Eliezer J. Barreiro et al.   CHEMICAL REVIEWS

Fundamentals of green chemistry: efficiency in reaction design

(2011) Roger A. Sheldon   CHEMICAL SOCIETY REVIEWS

On-resin N-methylation of cyclic peptides for discovery of orally bioavailable scaffolds

(2011) Tina R White et al.   Nature Chemical Biology

Efficient and chemoselective alkylation of amines/amino acids using alcohols as alkylating reagents under mild conditions

(2010) Chu-Pei Xu et al.   CHEMICAL COMMUNICATIONS

N-Formylation of Amines Catalyzed by Nanogold under Aerobic Oxidation Conditions with MeOH or Formalin

(2010) Patcharee Preedasuriyachai et al.   CHEMISTRY LETTERS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

N-Formylation of Amines via the Aerobic Oxidation of Methanol over Supported Gold Nanoparticles

(2009) Tamao Ishida et al.   ChemSusChem

One-pot synthesis of N,N-dimethylaniline from nitrobenzene and methanol

(2009) Long Xu et al.   NEW JOURNAL OF CHEMISTRY