Recent Advances On Direct Formylation Reactions

Site‐Selective Decarboxylative Direct Formylation of Nitrogen Heterocycles (Azaindoles, Indoles, Pyrroles) and Anilines Utilizing Glyoxylic Acid

(2023) Joydev K. Laha et al.   ADVANCED SYNTHESIS & CATALYSIS

(NH4)2S2O8-Mediated Metal-Free Decarboxylative Formylation/Acylation of α-Oxo/Ketoacids and Its Application to the Synthesis of Indole Alkaloids

(2022) Votarikari Dinesh et al.   JOURNAL OF ORGANIC CHEMISTRY

Integration of Milstein Ru–PNN and Rh–Tribi/Tetrabi for Isomerization Linear Selective Hydroformylation of Far Internal Alkenes

(2022) Runtong Zhang et al.   Journal of Organic Chemistry

Decarboxylative Coupling of Glyoxylic Acid and Its Acetal Derivatives: A Unique C1 Formylation Synthon

(2021) Yunyu Xiang et al.   TETRAHEDRON

Styrene Hydroformylation with In situ H: Regioselectivity Control by Coupling with Low-temperature Water Gas Shift Reaction

(2020) Botao Qiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly active cationic cobalt(II) hydroformylation catalysts

(2020) Drew M. Hood et al.   SCIENCE

Rational Redesign of a Regioselective Hydroformylation Catalyst for 3‐Butenoic Acid by Supramolecular Substrate Orientation

(2019) Shao‐Tao Bai et al.   ChemCatChem

TBSOTf-promoted versatile N-formylation using DMF at room temperature

(2019) Masayoshi Sakurai et al.   TETRAHEDRON LETTERS

Synthesis of 3-Formylindoles via Electrochemical Decarboxylation of Glyoxylic Acid with an Amine as a Dual Function Organocatalyst

(2019) Dian-Zhao Lin et al.   ORGANIC LETTERS

Selective nickel-catalyzed dehydrogenative–decarboxylative formylation of indoles with glyoxylic acid

(2018) Zhiping Yin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Visible light induced tetramethylethylenediamine assisted formylation of imidazopyridines

(2018) Golam Kibriya et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Electrochemical N-Formylation of Amines via Decarboxylation of Glyoxylic Acid

(2018) Dian-Zhao Lin et al.   ORGANIC LETTERS

Supramolecular Approaches To Control Activity and Selectivity in Hydroformylation Catalysis

(2018) Sandra S. Nurttila et al.   ACS Catalysis

Decarboxylative formylation of aryl halides with glyoxylic acid by merging organophotoredox with palladium catalysis

(2018) Bin Zhao et al.   Organic Chemistry Frontiers

Metal- and Acid-Free C–H Formylation of Nitrogen Heterocycles: Using Trioxane as an Aldehyde Equivalent Enabled by an Organic-Soluble Oxidant

(2018) Jacob M. Ganley et al.   ORGANIC LETTERS

Catalytic Deprotonative α-Formylation of Heteroarenes by an Amide Base Generated in Situ from Tetramethylammonium Fluoride and Tris(trimethylsilyl)amine

(2018) Masanori Shigeno et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Iron-Rich Natural Mineral Gibeon Meteorite Catalyzed N -formylation of Amines using CO2 as the C1 Source

(2018) Aswin Gopakumar et al.   ChemistrySelect

N-formylation and N-methylation of amines using metal-free N-heterocyclic carbene catalysts and CO2 as carbon source

(2017) Felix D Bobbink et al.   Nature Protocols

Formylation of phenols using formamidine acetate

(2017) S. Hessam M. Mehr et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Aerobic iron(III)-catalyzed direct formylation of imidazo[1,2- a ]pyridine using DMSO as carbon source

(2016) Shijian Xiang et al.   TETRAHEDRON LETTERS

Formylation of Electron-Rich Aromatic Rings Mediated by Dichloromethyl Methyl Ether and TiCl4: Scope and Limitations

(2015) Iván Ramos-Tomillero et al.   MOLECULES

Accessible protocol for asymmetric hydroformylation of vinylarenes using formaldehyde

(2015) Tsumoru Morimoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Hydroformylation of olefins and reductive carbonylation of aryl halides with syngas formed ex situ from dehydrogenative decarbonylation of hexane-1,6-diol

(2015) Stig Holden Christensen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of [13C6]-labelled phenethylamine derivatives for drug quantification in biological samples

(2014) Morten Karlsen et al.   JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS

Formylation of Amines

(2014) Ciera Gerack et al.   MOLECULES

The ammonium-promoted formylation of indoles by DMSO and H2O

(2013) Haiyang Fei et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The Copper-Catalyzed C-3-Formylation of Indole CH Bonds using Tertiary Amines and Molecular Oxygen

(2012) Jianbin Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

nBu4NI-catalyzed C3-formylation of indoles with N-methylaniline

(2012) Lan-Tao Li et al.   CHEMICAL COMMUNICATIONS

Applied Hydroformylation

(2012) Robert Franke et al.   CHEMICAL REVIEWS

Recycling of Carbon and Silicon Wastes: Room Temperature Formylation of N–H Bonds Using Carbon Dioxide and Polymethylhydrosiloxane

(2012) Olivier Jacquet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Melamine trisulfonic acid-catalyzed N-formylation of amines under solvent-free conditions

(2012) Xiao Juan Yang et al.   RESEARCH ON CHEMICAL INTERMEDIATES

General and Efficient Protocol for Formylation of Aromatic and Heterocyclic Phenols

(2012) Athanassios Coutsolelos et al.   SYNTHESIS-STUTTGART

Silica supported perchloric acid catalyzed rapid N-formylation under solvent-free conditions

(2012) Mohd. Imran Ansari et al.   TETRAHEDRON LETTERS

Synthesis of Azomethines from α-Oxocarboxylates, Amines and Aryl Bromides via One-Pot Three-Component Decarboxylative Coupling

(2011) Felix Rudolphi et al.   ADVANCED SYNTHESIS & CATALYSIS

Mild, Simple, and Efficient Method forN-Formylation of Secondary Amines via Reimer–Tiemann Reaction

(2011) Lokesh A. Shastri et al.   SYNTHETIC COMMUNICATIONS

Directed metalation and regioselective functionalization of 3-bromofuran and related heterocycles with NaHMDS

(2011) Hang Zhao et al.   TETRAHEDRON LETTERS

“One-Pot” Synthesis of 5-(Hydroxymethyl)furfural from Carbohydrates using Tin-Beta Zeolite

(2011) Eranda Nikolla et al.   ACS Catalysis

Sulfonic acid supported on hydroxyapatite-encapsulated-γ-Fe2O3 nanocrystallites as a magnetically Brønsted acid for N-formylation of amines

(2010) Leila Ma’mani et al.   APPLIED CATALYSIS A-GENERAL

Facile N-formylation of amines using Lewis acids as novel catalysts

(2009) A. Chandra Shekhar et al.   TETRAHEDRON LETTERS

Ion Exchange Resins: Catalyst Recovery and Recycle

(2008) Pierluigi Barbaro et al.   CHEMICAL REVIEWS

Regioselective formylation of pyrazolo[3,4-b]pyridine and pyrazolo[1,5-a]pyrimidine systems using Vilsmeier–Haack conditions

(2008) Jairo Quiroga et al.   TETRAHEDRON LETTERS

A remarkably simple N-formylation of anilines using polyethylene glycol

(2008) Biswanath Das et al.   TETRAHEDRON LETTERS