Cp*Ir complex bearing a flexible bridging and functional 2,2′-methylenebibenzimidazole ligand as an auto-tandem catalyst for the synthesis of N-methyl tertiary amines from imines via transfer hydrogenation/N-methylation with methanol

Recyclable covalent triazine framework-supported iridium catalyst for the N-methylation of amines with methanol in the presence of carbonate

(2021) Peng Liu et al.   JOURNAL OF CATALYSIS

N-Methylation of Amines with Methanol in the Presence of Carbonate Salt Catalyzed by a Metal–Ligand Bifunctional Ruthenium Catalyst [(p-cymene)Ru(2,2′-bpyO)(H2O)]

(2021) Peng Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Linear-Organic-Polymer-Supported Iridium Complex as a Recyclable Auto-Tandem Catalyst for the Synthesis of Quinazolinones via Selective Hydration/Acceptorless Dehydrogenative Coupling from o-Aminobenzonitriles

(2021) Shushu Hao et al.   ORGANIC LETTERS

Transfer Hydrogenation of Ketones and Imines with Methanol under Base-Free Conditions Catalyzed by an Anionic Metal–Ligand Bifunctional Iridium Catalyst

(2020) Rongzhou Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Dicarboxylic Acids from Aqueous Solutions of Diols Accompanied by the Evolution of Hydrogen Catalyzed by an Iridium Complex Bearing a Bipyridonate Ligand

(2020) Genki Toyooka et al.   ChemSusChem

N-Methylation of Amines with Methanol in Aqueous Solution Catalyzed by a Water-Soluble Metal–Ligand Bifunctional Dinuclear Iridium Catalyst

(2020) Chong Meng et al.   JOURNAL OF ORGANIC CHEMISTRY

Ni-Catalyzed Iterative Alkyl Transfer from Nitrogen Enabled by the In Situ Methylation of Tertiary Amines

(2020) Chideraa Iheanyi Nwachukwu et al.   JOURNAL OF ORGANIC CHEMISTRY

Hydrogen Production from Methanol‐Water Mixture over Immobilized Iridium Complex Catalysts in Vapor‐Phase Flow Reaction

(2020) Sho Yamaguchi et al.   ChemSusChem

Ruthenium-catalyzed acceptorless dehydrogenative coupling of o-aminobenzyl alcohols with ketones to quinolines in the presence of carbonate salt

(2020) Xiangchao Xu et al.   JOURNAL OF CATALYSIS

Metal-Catalyzed Asymmetric Hydrogenation of C═N Bonds

(2020) Racha Abed Ali Abdine et al.   ACS Catalysis

Manganese(III) Porphyrin‐Catalyzed Dehydrogenation of Alcohols to form Imines, Tertiary Amines and Quinolines

(2019) Kobra Azizi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Structure–Affinity Relationships of Spirocyclic Benzopyrans with Exocyclic Amino Moiety

(2019) Elisabeth Kronenberg et al.   JOURNAL OF MEDICINAL CHEMISTRY

Room-Temperature Chemoselective Reductive Alkylation of Amines Catalyzed by a Well-Defined Iron(II) Complex Using Hydrogen

(2019) Alexis Lator et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphine-Free Well-Defined Mn(I) Complex-Catalyzed Synthesis of Amine, Imine, and 2,3-Dihydro-1H-perimidine via Hydrogen Autotransfer or Acceptorless Dehydrogenative Coupling of Amine and Alcohol

(2019) Kalicharan Das et al.   ORGANOMETALLICS

Palladacycle-Phosphine Catalyzed Methylation of Amines and Ketones Using Methanol

(2019) Ramesh Mamidala et al.   JOURNAL OF ORGANIC CHEMISTRY

Commercial Pd/C-Catalyzed N-Methylation of Nitroarenes and Amines Using Methanol as Both C1 and H2 Source

(2019) Vishakha Goyal et al.   JOURNAL OF ORGANIC CHEMISTRY

Advances in One-Pot Synthesis through Borrowing Hydrogen Catalysis

(2018) Avelino Corma et al.   CHEMICAL REVIEWS

Transfer Hydrogenation of Aldehydes and Ketones with Isopropanol under Neutral Conditions Catalyzed by a Metal–Ligand Bifunctional Catalyst [Cp*Ir(2,2′-bpyO)(H2O)]

(2018) Rongzhou Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Monomethylation of Aromatic Amines with Methanol via PNHP-Pincer Ru Catalysts

(2018) Osamu Ogata et al.   ORGANIC LETTERS

Iron-Catalyzed Methylation Using the Borrowing Hydrogen Approach

(2018) Kurt Polidano et al.   ACS Catalysis

DARK Classics in Chemical Neuroscience: Opium, a historical perspective

(2018) Christopher Presley et al.   ACS Chemical Neuroscience

Auto-Tandem Catalysis with Ruthenium: From o -Aminobenzamides and Allylic Alcohols to Quinazolinones via Redox Isomerization/Acceptorless Dehydrogenation

(2018) Weikang Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study

(2018) Duo Wei et al.   JOURNAL OF CATALYSIS

TiO2 Nanoparticles Functionalized with Non-Innocent Ligands Allow Oxidative Photocyanation of Amines with Visible/Near-Infrared Photons

(2018) Alexander M. Nauth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Well-Defined Phosphine-Free Iron-Catalyzed N-Ethylation and N-Methylation of Amines with Ethanol and Methanol

(2018) Alexis Lator et al.   ORGANIC LETTERS

Methylation of Amines and Ketones with Methanol Catalyzed by an Iridium Complex Bearing a 2-Hydroxypyridylmethylene Fragment

(2018) Danfeng Deng et al.   ORGANOMETALLICS

Efficient and Versatile Catalytic Systems for the N-Methylation of Primary Amines with Methanol Catalyzed by N-Heterocyclic Carbene Complexes of Iridium

(2018) Ken-ichi Fujita et al.   SYNTHESIS-STUTTGART

Regio- and chemoselective Csp3–H arylation of benzylamines by single electron transfer/hydrogen atom transfer synergistic catalysis

(2018) Takafumi Ide et al.   Chemical Science

DARK Classics in Chemical Neuroscience: Atropine, Scopolamine, and Other Anticholinergic Deliriant Hallucinogens

(2018) Anton M. Lakstygal et al.   ACS Chemical Neuroscience

3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer

(2018) Torsten Irrgang et al.   CHEMICAL REVIEWS

Hydride Transfer Reactions Catalyzed by Cobalt Complexes

(2018) Wenying Ai et al.   CHEMICAL REVIEWS

Selective N-Formylation and N-Methylation of Amines Using Methanol as a Sustainable C1 Source

(2018) Geunho Choi et al.   ACS Sustainable Chemistry & Engineering

Enhanced Catalytic Activity of Iridium(III) Complexes by Facile Modification of C,N-Bidentate Chelating Pyridylideneamide Ligands

(2017) Miquel Navarro et al.   INORGANIC CHEMISTRY

Triazolylidene Iridium Complexes for Highly Efficient and Versatile Transfer Hydrogenation of C═O, C═N, and C═C Bonds and for Acceptorless Alcohol Oxidation

(2017) Zahra Mazloomi et al.   INORGANIC CHEMISTRY

Use of a Cyclometalated Iridium(III) Complex Containing a N∧C∧N-Coordinating Terdentate Ligand as a Catalyst for the α-Alkylation of Ketones and N-Alkylation of Amines with Alcohols

(2017) Pengcheng Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Manganese-Catalyzed Aminomethylation of Aromatic Compounds with Methanol as a Sustainable C1 Building Block

(2017) Matthias Mastalir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Methylation of Amines with Methanol Catalyzed by a Cp*Ir Complex Bearing a Functional 2,2′-Bibenzimidazole Ligand

(2017) Ran Liang et al.   ORGANIC LETTERS

Dehydrogenative Oxidation of Alcohols in Aqueous Media Catalyzed by a Water-Soluble Dicationic Iridium Complex Bearing a Functional N-Heterocyclic Carbene Ligand without Using Base

(2017) Ken-ichi Fujita et al.   ACS Catalysis

Metal–Ligand Bifunctional Catalysis: The “Accepted” Mechanism, the Issue of Concertedness, and the Function of the Ligand in Catalytic Cycles Involving Hydrogen Atoms

(2017) Pavel A. Dub et al.   ACS Catalysis

Sustainable and Selective Monomethylation of Anilines by Methanol with Solid Molecular NHC-Ir Catalysts

(2017) Jiangbo Chen et al.   ACS Sustainable Chemistry & Engineering

Transfer Hydrogenation from Glycerol: Activity and Recyclability of Iridium and Ruthenium Sulfonate-Functionalized N-Heterocyclic Carbene Catalysts

(2017) Arturo Azua et al.   ACS Sustainable Chemistry & Engineering

Contra-thermodynamic Hydrogen Atom Abstraction in the Selective C–H Functionalization of Trialkylamine N-CH3 Groups

(2016) Joshua P. Barham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acceptorless Dehydrogenative Coupling of o-Aminobenzamides with the Activation of Methanol as a C1 Source for the Construction of Quinazolinones

(2016) Feng Li et al.   ORGANIC LETTERS

Acceptorless Dehydrogenative Cyclization of o-Aminobenzyl Alcohols with Ketones to Quinolines in Water Catalyzed by Water-Soluble Metal–Ligand Bifunctional Catalyst [Cp*(6,6′-(OH)2bpy)(H2O)][OTf]2

(2016) Rongzhou Wang et al.   ORGANIC LETTERS

Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes

(2016) Saravanakumar Elangovan et al.   Nature Communications

Direct Coupling of Arylacetonitriles and Primary Alcohols to α-Alkylated Arylacetamides with Complete Atom Economy Catalyzed by a Rhodium Complex-Triphenylphosphine- Potassium Hydroxide System

(2015) Feng Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Hydrogen Production from a Methanol-Water Solution Catalyzed by an Anionic Iridium Complex Bearing a Functional Bipyridonate Ligand under Weakly Basic Conditions

(2015) Ken-ichi Fujita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Golden Age of Transfer Hydrogenation

(2015) Dong Wang et al.   CHEMICAL REVIEWS

Methanol Dehydrogenation by Iridium N-Heterocyclic Carbene Complexes

(2015) Jesús Campos et al.   INORGANIC CHEMISTRY

Tertiary Amine Pyrazolones and Their Salts as Inhibitors of Mutant Superoxide Dismutase 1-Dependent Protein Aggregation for the Treatment of Amyotrophic Lateral Sclerosis

(2015) Yinan Zhang et al.   JOURNAL OF MEDICINAL CHEMISTRY

Effective Recognition of Different Types of Amino Groups: From Aminobenzenesulfonamides to Amino-(N-alkyl)benzenesulfonamides via Iridium-Catalyzed N-Alkylation with Alcohols

(2015) Lei Lu et al.   ORGANIC LETTERS

Benzylamines via Iron-Catalyzed Direct Amination of Benzyl Alcohols

(2015) Tao Yan et al.   ACS Catalysis

Efficient Ruthenium-Catalyzed N-Methylation of Amines Using Methanol

(2015) Tuan Thanh Dang et al.   ACS Catalysis

Hydrogen-Free Cobalt–Rhodium Heterobimetallic Nanoparticle-Catalyzed Reductive Amination of Aldehydes and Ketones with Amines and Nitroarenes in the Presence of Carbon Monoxide and Water

(2015) Jang Won Park et al.   ACS Catalysis

TheN-Alkylation of Sulfonamides with Alcohols in Water Catalyzed by the Water-Soluble Iridium Complex {Cp*Ir[6,6′-(OH)2bpy](H2O)}[OTf]2

(2014) Panpan Qu et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium-Catalyzed Reductive Methylation of Imines Using Carbon Dioxide and Molecular Hydrogen

(2014) Kassem Beydoun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Amines by Reductive Amination of Aldehydes and Ketones using Co3O4/NGr@C Catalyst

(2014) Sabine Pisiewicz et al.   ChemCatChem

Metal-Free Reduction of Secondary and Tertiary N-Phenyl Amides by Tris(pentafluorophenyl)boron-Catalyzed Hydrosilylation

(2014) Ryan C. Chadwick et al.   JOURNAL OF ORGANIC CHEMISTRY

α-Alkylation of Ketones with Primary Alcohols Catalyzed by a Cp*Ir Complex Bearing a Functional Bipyridonate Ligand

(2014) Feng Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Unravelling the Mechanism of the Asymmetric Hydrogenation of Acetophenone by [RuX2(diphosphine)(1,2-diamine)] Catalysts

(2014) Pavel A. Dub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of Heteroditopic Dicarbene Rhodium(I) and Iridium(I) Complexes Bearing Chelating 1,2,3-Triazolylidene–Imidazolylidene Ligands

(2014) Soraya N. Sluijter et al.   ORGANOMETALLICS

Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect

(2014) Cheng Hou et al.   ACS Catalysis

Copper-Catalyzed Intermolecular Regioselective Hydroamination of Styrenes with Polymethylhydrosiloxane and Hydroxylamines

(2013) Yuya Miki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bifunctional (Cyclopentadienone)Iron-Tricarbonyl Complexes: Synthesis, Computational Studies and Application in Reductive Amination

(2013) Solenne Moulin et al.   CHEMISTRY-A EUROPEAN JOURNAL

A step closer to a methanol economy

(2013) Douglas W. Stephan   NATURE

Selective Alkylation of Amines with Alcohols by Cp*–Iridium(III) Half-Sandwich Complexes

(2013) Alexander Wetzel et al.   ORGANIC LETTERS

The Iridium-Catalyzed Synthesis of Symmetrically and Unsymmetrically Alkylated Diamines under Mild Reaction Conditions

(2012) Stefan Michlik et al.   ADVANCED SYNTHESIS & CATALYSIS

Cooperative Catalysis by Iridium Complexes with a Bipyridonate Ligand: Versatile Dehydrogenative Oxidation of Alcohols and Reversible Dehydrogenation-Hydrogenation between 2-Propanol and Acetone

(2012) Ryoko Kawahara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Second-coordination-sphere and electronic effects enhance iridium(iii)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure

(2012) Wan-Hui Wang et al.   Energy & Environmental Science

Dehydrogenative Oxidation of Alcohols in Aqueous Media Using Water-Soluble and Reusable Cp*Ir Catalysts Bearing a Functional Bipyridine Ligand

(2012) Ryoko Kawahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General and efficient method for direct N-monomethylation of aromatic primary amines with methanol

(2012) Feng Li et al.   RSC Advances

The Catalytic Amination of Alcohols

(2011) Sebastian Bähn et al.   ChemCatChem

Iridium-catalysed direct C–C coupling of methanol and allenes

(2011) Joseph Moran et al.   Nature Chemistry

Dehydrogenative Oxidation of Primary and Secondary Alcohols Catalyzed by a Cp*Ir Complex Having a Functional C,N-Chelate Ligand

(2011) Ken-ichi Fujita et al.   ORGANIC LETTERS

Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst

(2010) Brian L. Conley et al.   CHEMICAL REVIEWS

Transition Metal-Catalyzed Enantioselective Hydrogenation of Enamines and Imines

(2010) Jian-Hua Xie et al.   CHEMICAL REVIEWS

Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis

(2010) James D. Blakemore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multialkylation of Aqueous Ammonia with Alcohols Catalyzed by Water-Soluble Cp*Ir−Ammine Complexes

(2010) Ryoko Kawahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Convenient and General Iron-Catalyzed Reduction of Amides to Amines

(2009) Shaolin Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Autotransfer in theN-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

(2009) Gabriela Guillena et al.   CHEMICAL REVIEWS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS