Methanol as a greener C1 synthon under non-noble transition metal-catalyzed conditions

Recent developments in electrosynthesis of nitriles and electrocatalytic cyanations

(2022) Haiyan Hu et al.   Journal of Energy Chemistry

Simple RuCl3‐catalyzed N‐Methylation of Amines and Transfer Hydrogenation of Nitroarenes using Methanol

(2021) Kishore Natte et al.   ChemCatChem

Base Metal‐Catalyzed C‐Methylation Reactions Using Methanol

(2021) Naina Sarki et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent developments in reductive N-methylation with base-metal catalysts

(2021) Vishakha Goyal et al.   TETRAHEDRON

N-Dimethylation and N-Functionalization of Amines Using Ru Nanoparticle Catalysts and Formaldehyde or Functional Aldehydes as the Carbon Source

(2021) Jianguo Liu et al.   ACS Omega

Cobalt-catalyzed direct α-hydroxymethylation of amides with methanol as a C1 source

(2021) Ben Ma et al.   CHEMICAL COMMUNICATIONS

Holistic approach to anti-knock agents: A high-throughput screening of aniline-like compounds

(2021) Antonio Viayna et al.   FUEL

Methanol as the C1 source: redox coupling of nitrobenzenes and alcohols for the synthesis of benzimidazoles

(2021) Hengzhao Li et al.   GREEN CHEMISTRY

A review on recent developments in N-methylation using CO2

(2021) Shanshan Lin et al.   Journal of CO2 Utilization

Ruthenium(II) Complexes of Heteroditopic N-Heterocyclic Carbene Ligands: Efficient Catalysts for C–N Bond Formation via a Hydrogen-Borrowing Strategy under Solvent-Free Conditions

(2020) S. N. R. Donthireddy et al.   INORGANIC CHEMISTRY

Reversible interconversion between methanol-diamine and diamide for hydrogen storage based on manganese catalyzed (de)hydrogenation

(2020) Zhihui Shao et al.   Nature Communications

Commercial Copper-Catalyzed Aerobic Oxidative Synthesis of Quinazolinones from 2-Aminobenzamide and Methanol

(2020) Sutthichat Kerdphon et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

N-Methylation of Amines with Methanol in Aqueous Solution Catalyzed by a Water-Soluble Metal–Ligand Bifunctional Dinuclear Iridium Catalyst

(2020) Chong Meng et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Methylation of amines and nitroarenes with methanol using heterogeneous platinum catalysts

(2019) Md.A.R. Jamil et al.   JOURNAL OF CATALYSIS

Palladium-Catalyzed Methylation of Nitroarenes with Methanol

(2019) Lin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)‐Catalyzed β ‐Methylation of Alcohols using Methanol as C 1 Source

(2019) Akash Kaithal et al.   ChemCatChem

α-Methylation of Ketones with Methanol Catalyzed by Ni/SiO2 -Al2 O3

(2019) Aubin Charvieux et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Tandem Three-Component Alkylation: Access to α-Methylated Substituted Ketones

(2019) Léo Bettoni et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Synthesis of N-Methylated Amides using Methanol

(2019) Bhaskar Paul et al.   ORGANIC LETTERS

Methyl Trifluoroacetate as a Methylation Reagent for N−H, O−H, and S−H Functionalities under Mild Conditions

(2019) Xin Zheng et al.   Asian Journal of Organic Chemistry

Palladacycle-Phosphine Catalyzed Methylation of Amines and Ketones Using Methanol

(2019) Ramesh Mamidala et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Conversion of Allylic Alcohols to α-Methyl Ketones via Iron-Catalyzed Isomerization–Methylation

(2019) Daniel E. Latham et al.   ORGANIC LETTERS

Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols

(2019) Kurt Polidano et al.   ACS Catalysis

Manganese(I)-Catalyzed β-Methylation of Alcohols Using Methanol as C1 Source

(2019) Akash Kaithal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Commercial Pd/C-Catalyzed N-Methylation of Nitroarenes and Amines Using Methanol as Both C1 and H2 Source

(2019) Vishakha Goyal et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed β-Alkylation of Alcohols

(2019) Léo Bettoni et al.   ORGANIC LETTERS

Atom-Economical and Tandem Conversion of Nitriles to N-Methylated Amides Using Methanol and Water

(2019) Bhaskar Paul et al.   ACS Catalysis

Selective N ‐Monomethylation of Anilines with Methanol Catalyzed by Commercial Pd/C as an Efficient and Reusable Catalyst

(2019) Lei Jiang et al.   Asian Journal of Organic Chemistry

Iron-Catalyzed Reductive Ethylation of Imines with Ethanol

(2018) Marie Vayer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic (de)hydrogenation promoted by non-precious metals – Co, Fe and Mn: recent advances in an emerging field

(2018) Georgy A. Filonenko et al.   CHEMICAL SOCIETY REVIEWS

Electrochemical Cobalt-Catalyzed C-H Activation

(2018) Nicolas Sauermann et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Monomethylation of Aromatic Amines with Methanol via PNHP-Pincer Ru Catalysts

(2018) Osamu Ogata et al.   ORGANIC LETTERS

Iron-catalyzed urea synthesis: dehydrogenative coupling of methanol and amines

(2018) Elizabeth M. Lane et al.   Chemical Science

C-Methylation of Alcohols, Ketones, and Indoles with Methanol Using Heterogeneous Platinum Catalysts

(2018) S. M. A. Hakim Siddiki et al.   ACS Catalysis

Iron-Catalyzed Methylation Using the Borrowing Hydrogen Approach

(2018) Kurt Polidano et al.   ACS Catalysis

N-Alkylation of functionalized amines with alcohols using a copper–gold mixed photocatalytic system

(2018) Lyu-Ming Wang et al.   Scientific Reports

Hydrogenation of CO2 -Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis

(2018) Viktoriia Zubar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols

(2018) Amit Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methyl-containing pharmaceuticals: Methylation in drug design

(2018) Shaoyi Sun et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Aminotriazole Mn(I) Complexes as Effective Catalysts for Transfer Hydrogenation of Ketones

(2018) Oriol Martínez-Ferraté et al.   ChemCatChem

Well-Defined Phosphine-Free Iron-Catalyzed N-Ethylation and N-Methylation of Amines with Ethanol and Methanol

(2018) Alexis Lator et al.   ORGANIC LETTERS

Nickel-Catalyzed Hydrogen-Borrowing Strategy for α-Alkylation of Ketones with Alcohols: A New Route to Branched gem-Bis(alkyl) Ketones

(2018) Jagadish Das et al.   ORGANIC LETTERS

Methylation of Amines and Ketones with Methanol Catalyzed by an Iridium Complex Bearing a 2-Hydroxypyridylmethylene Fragment

(2018) Danfeng Deng et al.   ORGANOMETALLICS

Supported Rhodium (Rh@PS) Catalyzed Benzimidazoles Synthesis Using Ethanol/Methanol as C2 H3 /CH Source

(2018) Saurabh Sharma et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Reductive N-Alkylations using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments

(2018) Jose R. Cabrero-Antonino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

(2018) Lukas Alig et al.   CHEMICAL REVIEWS

3d Transition Metals for C–H Activation

(2018) Parthasarathy Gandeepan et al.   CHEMICAL REVIEWS

Recent Advances in Methylation: A Guide for Selecting Methylation Reagents

(2018) Yantao Chen   CHEMISTRY-A EUROPEAN JOURNAL

Selective N-Formylation and N-Methylation of Amines Using Methanol as a Sustainable C1 Source

(2018) Geunho Choi et al.   ACS Sustainable Chemistry & Engineering

Mono- N -methylation of anilines with methanol catalyzed by a manganese pincer-complex

(2017) Antoine Bruneau-Voisine et al.   JOURNAL OF CATALYSIS

Manganese-Catalyzed Aminomethylation of Aromatic Compounds with Methanol as a Sustainable C1 Building Block

(2017) Matthias Mastalir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Methylation of Amines with Methanol Catalyzed by a Cp*Ir Complex Bearing a Functional 2,2′-Bibenzimidazole Ligand

(2017) Ran Liang et al.   ORGANIC LETTERS

Copper(II)-Catalyzed Selective Reductive Methylation of Amines with Formic Acid: An Option for Indirect Utilization of CO2

(2017) Chang Qiao et al.   ORGANIC LETTERS

Methylation of C(sp3)–H/C(sp2)–H Bonds with Methanol Catalyzed by Cobalt System

(2017) Zhenghui Liu et al.   ORGANIC LETTERS

Utilization of MeOH as a C1 Building Block in Tandem Three-Component Coupling Reaction

(2017) Kaushik Chakrabarti et al.   ORGANIC LETTERS

Recent Advances in Cobalt-Catalyzed Csp2 and Csp3 Cross-Couplings

(2017) Paul Knochel et al.   SYNTHESIS-STUTTGART

Recent Developments of Manganese Complexes for Catalytic Hydrogenation and Dehydrogenation Reactions

(2017) Biplab Maji et al.   SYNTHESIS-STUTTGART

Recent Advances in the Pauson–Khand Reaction

(2017) J. David Ricker et al.   TOPICS IN CATALYSIS

Supported Palladium Nanoparticle Catalyzed α-Alkylation of Ketones Using Alcohols as Alkylating Agents

(2017) C. Bal Reddy et al.   ACS Sustainable Chemistry & Engineering

Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

(2017) Gregory C. Fu   ACS Central Science

Catalyst: Sustainable Catalysis

(2017) Jacob R. Ludwig et al.   Chem

A Convenient Ruthenium-Catalysed α-Methylation of Carbonyl Compounds using Methanol

(2016) Tuan Thanh Dang et al.   ADVANCED SYNTHESIS & CATALYSIS

C−C Bond-Forming Strategy by Manganese-Catalyzed Oxidative Ring-Opening Cyanation and Ethynylation of Cyclobutanol Derivatives

(2016) Rongguo Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Molecularly Defined Manganese Pincer Complexes for Selective Transfer Hydrogenation of Ketones

(2016) Marc Perez et al.   ChemSusChem

CeO 2 -catalyzed direct synthesis of dialkylureas from CO 2 and amines

(2016) Masazumi Tamura et al.   JOURNAL OF CATALYSIS

Scalable, One-Pot, Microwave-Accelerated Tandem Synthesis of Unsymmetrical Urea Derivatives

(2016) Abhijit R. Kulkarni et al.   JOURNAL OF ORGANIC CHEMISTRY

Manganese-Catalyzed Environmentally Benign Dehydrogenative Coupling of Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic Study

(2016) Arup Mukherjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Catalytic Hydrogenations of Nitriles, Ketones, and Aldehydes by Well-Defined Manganese Pincer Complexes

(2016) Saravanakumar Elangovan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes

(2016) Saravanakumar Elangovan et al.   Nature Communications

Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands

(2015) Paul J. Chirik   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen Acceptor- and Base-FreeN-Formylation of Nitriles and Amines using Methanol as C1Source

(2015) Byungjoon Kang et al.   ADVANCED SYNTHESIS & CATALYSIS

Manganese-Catalyzed Oxidative Azidation of Cyclobutanols: Regiospecific Synthesis of Alkyl Azides by CC Bond Cleavage

(2015) Rongguo Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed α-Alkylation of Ketones with Alcohols

(2015) Saravanakumar Elangovan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Addition of Unactivated C–H Bonds to Polar Unsaturated Bonds

(2015) Lei Yang et al.   CHEMICAL REVIEWS

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

(2015) Chao Liu et al.   CHEMICAL REVIEWS

CC Coupling of Ketones with Methanol Catalyzed by a N-Heterocyclic Carbene-Phosphine Iridium Complex

(2015) Xu Quan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Research Progress on the Indirect Hydrogenation of Carbon Dioxide to Methanol

(2015) Xian-Long Du et al.   ChemSusChem

Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives

(2015) Anis Tlili et al.   GREEN CHEMISTRY

N-Methylation of Amines with Methanol at Room Temperature

(2015) Vasily N. Tsarev et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Urea Synthesis Using Methanol as the C1 Source

(2015) Seung Hyo Kim et al.   ORGANIC LETTERS

C–N Bond Formation between Alcohols and Amines Using an Iron Cyclopentadienone Catalyst

(2015) Andrew J. Rawlings et al.   ORGANIC LETTERS

Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes

(2015) N. M. Camasso et al.   SCIENCE

Efficient Ruthenium-Catalyzed N-Methylation of Amines Using Methanol

(2015) Tuan Thanh Dang et al.   ACS Catalysis

Cobalt-Catalyzed C–H Activation

(2015) Marc Moselage et al.   ACS Catalysis

Transition-Metal-Catalyzed Site-Selective C–H Functionalization of Quinolines beyond C2 Selectivity

(2015) Tomohiro Iwai et al.   ACS Catalysis

Magnesium in Prevention and Therapy

(2015) Uwe Gröber et al.   Nutrients

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen-Borrowing and Interrupted-Hydrogen-Borrowing Reactions of Ketones and Methanol Catalyzed by Iridium

(2014) Di Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock

(2014) Yang Li et al.   CHEMICAL COMMUNICATIONS

Iridium-catalyzed selective α-methylation of ketones with methanol

(2014) Shinji Ogawa et al.   CHEMICAL COMMUNICATIONS

Recycling of carbon dioxide to methanol and derived products – closing the loop

(2014) Alain Goeppert et al.   CHEMICAL SOCIETY REVIEWS

General Catalytic Methylation of Amines with Formic Acid under Mild Reaction Conditions

(2014) Iván Sorribes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organometallic Nickel(III) Complexes Relevant to Cross-Coupling and Carbon–Heteroatom Bond Formation Reactions

(2014) Bo Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formylation of Amines

(2014) Ciera Gerack et al.   MOLECULES

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

An overview on the production of bio-methanol as potential renewable energy

(2014) N.S. Shamsul et al.   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Iron catalysed direct alkylation of amines with alcohols

(2014) Tao Yan et al.   Nature Communications

Iron-catalyzed transformations of diazo compounds

(2014) Shou-Fei Zhu et al.   National Science Review

Iron-catalyzed/mediated oxidative transformation of C–H bonds

(2014) Fan Jia et al.   Organic Chemistry Frontiers

Profound Methyl Effects in Drug Discovery and a Call for New CH Methylation Reactions

(2013) Heike Schönherr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Oxidative Benzylic C-H Fluorination by Fluoride Ions

(2013) Wei Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols

(2013) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Ketone Methylation Using Methanol Under Mild Conditions: Formation of α-Branched Products

(2013) Louis K. M. Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Biological Activity of Substituted Urea and Thiourea Derivatives Containing 1,2,4-Triazole Moieties

(2013) Bedia Kocyigit-Kaymakcioglu et al.   MOLECULES

N-Formylation of Amines by Methanol Activation

(2013) Nuria Ortega et al.   ORGANIC LETTERS

Conversion of carbon dioxide into methanol – a potential liquid fuel: Fundamental challenges and opportunities (a review)

(2013) Ibram Ganesh   RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Abundant Metals Give Precious Hydrogenation Performance

(2013) R. M. Bullock   SCIENCE

General and efficient method for direct N-monomethylation of aromatic primary amines with methanol

(2012) Feng Li et al.   RSC Advances

The Methylation Effect in Medicinal Chemistry

(2011) Eliezer J. Barreiro et al.   CHEMICAL REVIEWS

Fundamentals of green chemistry: efficiency in reaction design

(2011) Roger A. Sheldon   CHEMICAL SOCIETY REVIEWS

Methylation of Glycerol with Dimethyl Sulfate To Produce a New Oxygenate Additive for Diesels

(2011) Jyh-Shyong Chang et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Iridium-catalysed direct C–C coupling of methanol and allenes

(2011) Joseph Moran et al.   Nature Chemistry

N-Alkylation of N-arylsulfonyl-α-amino acid methyl esters by trialkyloxonium tetrafluoroborates

(2011) Rosaria De Marco et al.   TETRAHEDRON

Efficient and chemoselective alkylation of amines/amino acids using alcohols as alkylating reagents under mild conditions

(2010) Chu-Pei Xu et al.   CHEMICAL COMMUNICATIONS

Cobalt-Catalyzed Cross-Coupling Reactions

(2010) Gérard Cahiez et al.   CHEMICAL REVIEWS

Assessment of Methanol Synthesis Utilizing Exhaust CO2for Chemical Storage of Electrical Energy

(2010) Liisa K. Rihko-Struckmann et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Vitamin B12 in Health and Disease

(2010) Fiona O’Leary et al.   Nutrients

Green chemistry metrics: a comparative evaluation of dimethyl carbonate, methyl iodide, dimethyl sulfate and methanol as methylating agents

(2008) Maurizio Selva et al.   GREEN CHEMISTRY

Manganese-catalyzed oxidative homo-coupling of aryl Grignard chlorides

(2008) Zhiming Zhou et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Role of magnesium in carbon partitioning and alleviating photooxidative damage

(2008) Ismail Cakmak et al.   PHYSIOLOGIA PLANTARUM