Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization
出版年份 2021 全文链接
标题
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization
作者
关键词
enantioselectivity, C–H activation, C–heteroatom bond, C–H metalation, catalytic system, asymmetric catalysis
出版物
Chem
Volume 8, Issue 2, Pages 384-413
出版商
Elsevier BV
发表日期
2021-12-17
DOI
10.1016/j.chempr.2021.11.015
参考文献
相关参考文献
注意：仅列出部分参考文献，下载原文获取全部文献信息。- Teaching Aldehydes New Tricks Using Rhodium- and Cobalt-Hydride Catalysis
- (2021) Ryan T. Davison et al. ACCOUNTS OF CHEMICAL RESEARCH
- Asymmetric Synthesis of Silicon-Stereogenic Monohydrosilanes by Dehydrogenative C–H Silylation
- (2021) Wei Yuan et al. ORGANIC LETTERS
- Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles
- (2021) Shuyou Chen et al. Nature Communications
- Development of Pseudo-C2-symmetric Chiral Binaphthyl Monocarboxylic Acids for Enantioselective C(sp3)–H Functionalization Reactions under Rh(III) Catalysis
- (2021) Yoshimi Kato et al. ACS Catalysis
- Chiral Carboxylic Acid Assisted Enantioselective C–H Activation with Achiral CpxMIII (M = Co, Rh, Ir) Catalysts
- (2021) Tatsuhiko Yoshino et al. ACS Catalysis
- 2-(Pyridin-2-yl)isopropyl (PIP) Amine: An Enabling Directing Group for Divergent and Asymmetric Functionalization of Unactivated Methylene C(sp3)–H Bonds
- (2021) Qi Zhang et al. ACCOUNTS OF CHEMICAL RESEARCH
- Diverse Approaches for Enantioselective C–H Functionalization Reactions Using Group 9 CpxMIII Catalysts
- (2020) Tatsuhiko Yoshino et al. CHEMISTRY-A EUROPEAN JOURNAL
- From Pd(OAc)2 to Chiral Catalysts: The Discovery and Development of Bifunctional Mono-N-Protected Amino Acid Ligands for Diverse C–H Functionalization Reactions
- (2020) Qian Shao et al. ACCOUNTS OF CHEMICAL RESEARCH
- Cationic Iridium/Chiral Bisphosphine‐Catalyzed Enantioselective Hydroacylation of Ketones
- (2020) Tomohiko Shirai et al. Chemistry-An Asian Journal
- Mechanism of the Iridium-Catalyzed Silylation of Aromatic C–H Bonds
- (2020) Caleb Karmel et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective remote C–H activation directed by a chiral cation
- (2020) Georgi R. Genov et al. SCIENCE
- Transition Metal‐Catalyzed Enantioselective C–H Functionalization via Chiral Transient Directing Group Strategy
- (2020) Gang Liao et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Chiral Catalysts for Pd0‐Catalyzed Enantioselective C–H Activation
- (2020) Oleksandr Vyhivskyi et al. CHEMISTRY-A EUROPEAN JOURNAL
- Iridium‐Catalyzed Enantioselective C(sp 3 )‐H Borylation of Cyclobutanes
- (2020) Xiang Chen et al. CHINESE JOURNAL OF CHEMISTRY
- Well‐Designed Chiral Ligands for Enantioselective Ir‐Catalyzed C(sp 2 )−H Borylation
- (2020) Yin–Xia Wang et al. CHINESE JOURNAL OF CHEMISTRY
- Iridium-Catalyzed Enantioselective α-C(sp3)–H Borylation of Azacycles
- (2020) Lili Chen et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Streamlined Construction of Silicon-Stereogenic Silanes by Tandem Enantioselective C–H Silylation/Alkene Hydrosilylation
- (2020) Delong Mu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Dual-Ligand-Enabled Ir(III)-Catalyzed Enantioselective C–H Amidation for the Synthesis of Chiral Sulfoxides
- (2020) Wentan Liu et al. ACS Catalysis
- Achiral CpxIr(III)/Chiral Carboxylic Acid Catalyzed Enantioselective C–H Amidation of Ferrocenes under Mild Conditions
- (2020) Lei Liu et al. ACS Catalysis
- Palladium-Catalyzed Asymmetric Allylic C–H Functionalization: Mechanism, Stereo- and Regioselectivities, and Synthetic Applications
- (2020) Pu-Sheng Wang et al. ACCOUNTS OF CHEMICAL RESEARCH
- Enantioselective Silylation of Aliphatic C−H Bonds for the Synthesis of Silicon‐Stereogenic Dihydrobenzosiloles
- (2020) Bo Yang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Catalytic Enantioselective Functionalizations of C–H Bonds by Chiral Iridium Complexes
- (2020) Łukasz Woźniak et al. CHEMICAL REVIEWS
- Chiral Transient Directing Groups in Transition-Metal-Catalyzed Enantioselective C–H Bond Functionalization
- (2020) Maria I. Lapuh et al. ACS Catalysis
- Chiral CpxRh complexes for C–H functionalization reactions
- (2020) Quannan Wang et al. Science Bulletin
- Iridium‐Catalyzed Regio‐ and Enantioselective Borylation of Unbiased Methylene C(sp3)‐H Bonds at the Position Beta to a Nitrogen Center
- (2020) Rongrong Du et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium‐Catalyzed Enantioselective Synthesis of β‐Amino Alcohols via Desymmetrization of gem‐Dimethyl Groups
- (2020) Xingwei Li et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Iridium‐Catalyzed Enantioselective Unbiased Methylene C(sp 3 )–H Borylation of Acyclic Amides
- (2020) Yuhuan Yang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium‐Catalyzed Synthesis of Chiral Monohydrosilanes by Intramolecular C−H Functionalization of Dihydrosilanes
- (2020) Wenpeng Ma et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Cp*Co(III)/MPAA-Catalyzed Enantioselective Amidation of Ferrocenes Directed by Thioamides under Mild Conditions
- (2019) Yan-Hua Liu et al. ORGANIC LETTERS
- Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Asymmetric C(sp2)–H Borylation of Diarylmethylamines
- (2019) Xiaoliang Zou et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Pd(II)-Catalyzed Enantioselective Alkynylation of Unbiased Methylene C(sp3)–H Bonds Using 3,3′-Fluorinated-BINOL as a Chiral Ligand
- (2019) Ye-Qiang Han et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Mechanism and Origins of Enantioselectivity of Iridium-Catalyzed Intramolecular Silylation of Unactivated C(sp3)–H Bonds
- (2019) Mei Zhang et al. JOURNAL OF ORGANIC CHEMISTRY
- Enantioselective C-H Activation with Earth-Abundant 3d Transition Metals
- (2019) Joachim Loup et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Iridium-Catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds
- (2019) Ronald L. Reyes et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Enantioselective C(sp3)–H Borylation of Cyclopropanes
- (2019) Yongjia Shi et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Chiral 2-Aryl Ferrocene Carboxylic Acids for the Catalytic Asymmetric C(sp3)–H Activation of Thioamides
- (2019) Daichi Sekine et al. ORGANOMETALLICS
- Catalytic Enantioselective Methylene C(sp3 )−H Amidation of 8-Alkylquinolines Using a Cp*RhIII /Chiral Carboxylic Acid System
- (2019) Seiya Fukagawa et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Synthesis of Chiral β‐Lactams by Pd‐Catalyzed Enantioselective Amidation of Methylene C(sp 3 )–H Bonds
- (2019) Tao Zhou et al. CHINESE JOURNAL OF CHEMISTRY
- Asymmetric Synthesis of α-Aminoboronates via Rhodium-Catalyzed Enantioselective C(sp3)–H Borylation
- (2019) Ronald L. Reyes et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Asymmetric Synthesis of β-Lactam via Palladium-Catalyzed Enantioselective Intramolecular C(sp3)–H Amidation
- (2019) Hua-Rong Tong et al. ACS Catalysis
- Palladium(II)-Catalyzed Enantioselective Arylation of Unbiased Methylene C(sp3 )−H Bonds Enabled by a 2-Pyridinylisopropyl Auxiliary and Chiral Phosphoric Acids
- (2018) Sheng-Yi Yan et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Enantioselective Aliphatic C-H Bond Oxidation Catalyzed by Bioinspired Complexes
- (2018) Michela Milan et al. CHEMICAL COMMUNICATIONS
- Controlling Pd(iv) reductive elimination pathways enables Pd(ii)-catalysed enantioselective C(sp3)−H fluorination
- (2018) Hojoon Park et al. Nature Chemistry
- Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts
- (2018) Tyler G. Saint-Denis et al. SCIENCE
- Copper-Catalyzed Radical Relay for Asymmetric Radical Transformations
- (2018) Fei Wang et al. ACCOUNTS OF CHEMICAL RESEARCH
- Chiral Carboxylic Acid Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C−H Functionalization
- (2018) Luqing Lin et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Enantioselective Cobalt(III)-Catalyzed C−H Activation Enabled by Chiral Carboxylic Acid Cooperation
- (2018) Fabio Pesciaioli et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Enantioselective C(sp3 )-H Amidation of Thioamides Catalyzed by a CobaltIII /Chiral Carboxylic Acid Hybrid System
- (2018) Seiya Fukagawa et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- 3d Transition Metals for C–H Activation
- (2018) Parthasarathy Gandeepan et al. CHEMICAL REVIEWS
- Iridium-Catalyzed, β-Selective C(sp3)–H Silylation of Aliphatic Amines To Form Silapyrrolidines and 1,2-Amino Alcohols
- (2018) Bo Su et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Pd(II)-Catalyzed Enantioselective C(sp3)–H Borylation
- (2017) Jian He et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C–H Bonds
- (2017) Bo Su et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C–H Bonds
- (2017) Taegyo Lee et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Formation of α-chiral centers by asymmetric β-C(sp 3 )–H arylation, alkenylation, and alkynylation
- (2017) Qing-Feng Wu et al. SCIENCE
- A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C−H Bonds
- (2016) Bo Su et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Construction of Chiral Tetraorganosilicons by Tandem Desymmetrization of Silacyclobutanes/Intermolecular Dehydrogenative Silylation
- (2016) Qing-Wei Zhang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C−H Bonds
- (2016) Taegyo Lee et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Theoretical study on the mechanism of iridium-catalyzed γ-functionalization of primary alkyl C–H bonds
- (2016) Zhe Li et al. CANADIAN JOURNAL OF CHEMISTRY
- Palladium-Catalyzed Transformations of Alkyl C–H Bonds
- (2016) Jian He et al. CHEMICAL REVIEWS
- Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters
- (2016) Masahito Murai et al. CHEMISTRY-A EUROPEAN JOURNAL
- Diastereodivergent Construction of Bicyclic γ-Lactones via Enantioselective Ketone Hydroacylation
- (2016) Xuesong Wu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- N,B-Bidentate Boryl Ligand-Supported Iridium Catalyst for Efficient Functional-Group-Directed C–H Borylation
- (2016) Guanghui Wang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Functionalization of C(sp3)-H bonds using a transient directing group
- (2016) F.-L. Zhang et al. SCIENCE
- Ligand-accelerated enantioselective methylene C(sp3)–H bond activation
- (2016) Gang Chen et al. SCIENCE
- Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds
- (2015) Olafs Daugulis et al. ACCOUNTS OF CHEMICAL RESEARCH
- Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations
- (2015) Baihua Ye et al. ACCOUNTS OF CHEMICAL RESEARCH
- Rhodium-Catalyzed Enantioselective Intramolecular CH Silylation for the Syntheses of Planar-Chiral Metallocene Siloles
- (2015) Qing-Wei Zhang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C–H silylation
- (2015) Takanori Shibata et al. CHEMICAL COMMUNICATIONS
- Catalytic Silylation of Unactivated C–H Bonds
- (2015) Chen Cheng et al. CHEMICAL REVIEWS
- A Combined IM-MS/DFT Study on [Pd(MPAA)]-Catalyzed Enantioselective CH Activation: Relay of Chirality through a Rigid Framework
- (2015) Gui-Juan Cheng et al. CHEMISTRY-A EUROPEAN JOURNAL
- Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation and Germylation of Unactivated C(sp3)–H Bonds
- (2015) Masahito Murai et al. JOURNAL OF ORGANIC CHEMISTRY
- Rhodium-Catalyzed Enantioselective Silylation of Arene C–H Bonds: Desymmetrization of Diarylmethanols
- (2015) Taegyo Lee et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Rhodium-Catalyzed Synthesis of Benzosilolometallocenes via the Dehydrogenative Silylation of C(sp2)–H Bonds
- (2015) Masahito Murai et al. ORGANIC LETTERS
- Palladium-Catalyzed Asymmetric Arylation of C(sp3)–H Bonds of Aliphatic Amides: Controlling Enantioselectivity Using Chiral Phosphoric Amides/Acids
- (2015) Shao-Bai Yan et al. ORGANIC LETTERS
- Dual role of carboxylic acid additive: mechanistic studies and implication for the asymmetric C–H amidation
- (2015) Donghyeon Gwon et al. TETRAHEDRON
- Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization
- (2014) Ke Gao et al. ACCOUNTS OF CHEMICAL RESEARCH
- Iridium-Catalyzed Enantioselective CH Alkylation of Ferrocenes with Alkenes Using Chiral Diene Ligands
- (2014) Takanori Shibata et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rh(I)-Catalyzed Intermolecular Hydroacylation: Enantioselective Cross-Coupling of Aldehydes and Ketoamides
- (2014) Kevin G. M. Kou et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis
- (2014) Behnaz Ghaffari et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Cobalt-Catalyzed Enantioselective Intramolecular Hydroacylation of Ketones and Olefins
- (2014) Junfeng Yang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Room-temperature enantioselective C–H iodination via kinetic resolution
- (2014) Ling Chu et al. SCIENCE
- Pd(II)-Catalyzed Intermolecular Direct C–H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution
- (2014) De-Wei Gao et al. ACS Catalysis
- Pd(II)-Catalyzed Enantioselective C–H Activation/C–O Bond Formation: Synthesis of Chiral Benzofuranones
- (2013) Xiu-Fen Cheng et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Pd-Catalyzed Enantioselective C–H Iodination: Asymmetric Synthesis of Chiral Diarylmethylamines
- (2013) Ling Chu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Role of N-Acyl Amino Acid Ligands in Pd(II)-Catalyzed Remote C–H Activation of Tethered Arenes
- (2013) Gui-Juan Cheng et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- C–H bond activation enables the rapid construction and late-stage diversification of functional molecules
- (2013) Joanna Wencel-Delord et al. Nature Chemistry
- Mechanism of Catalytic Functionalization of Primary C–H Bonds Using a Silylation Strategy
- (2013) Abhishek Parija et al. ORGANIC LETTERS
- Enantioselective [3 + 2] annulation via C–H activation between cyclic N-acyl ketimines and 1,3-dienes catalyzed by iridium/chiral diene complexes
- (2013) Takahiro Nishimura et al. Chemical Science
- Recent development of direct asymmetric functionalization of inert C–H bonds
- (2013) Chao Zheng et al. RSC Advances
- Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives
- (2012) Yoichiro Kuninobu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation
- (2012) T. K. Hyster et al. SCIENCE
- Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization
- (2012) B. Ye et al. SCIENCE
- Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation
- (2011) Lindsay McMurray et al. CHEMICAL SOCIETY REVIEWS
- Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
- (2010) Thomas W. Lyons et al. CHEMICAL REVIEWS
- Nitrogen-directed ketone hydroacylation: Enantioselective synthesis of benzoxazecinones
- (2010) Hasan A. Khan et al. Chemical Science
- Mechanistic Insights into the Rhodium-Catalyzed Intramolecular Ketone Hydroacylation
- (2009) Zengming Shen et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Phthalides by Rhodium-Catalyzed Ketone Hydroacylation
- (2009) Diem H. T. Phan et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- PdII-Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands
- (2008) Bing-Feng Shi et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rh-Catalyzed Carbonyl Hydroacylation: An Enantioselective Approach to Lactones
- (2008) Zengming Shen et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
- (2008) Huw M. L. Davies et al. NATURE
Become a Peeref-certified reviewer
The Peeref Institute provides free reviewer training that teaches the core competencies of the academic peer review process.
Get StartedAsk a Question. Answer a Question.
Quickly pose questions to the entire community. Debate answers and get clarity on the most important issues facing researchers.
Get Started