期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 28, 页码 12062-12068出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c06756
关键词
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资金
- National Natural Science Foundation of China [21573262, 21873261, 91956116]
- Natural Science Foundation of Jiangsu Province [BK20161259, BK20170422]
- Hangzhou Normal University
- Lanzhou Institute of Chemical Physics
We herein report an iridium-catalyzed enantioselective alpha-C(sp(3))-H borylation of a wide range of azacycles. The combination of an iridium precursor and a chiral bidentate boryl ligand has been shown to effectively differentiate enantiotropic methylene C-H bonds from a single carbon center, affording a variety of synthetically useful azacycles from readily available starting materials with good to excellent enantioselectivities.
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