标题
Recent development of direct asymmetric functionalization of inert C–H bonds
作者
关键词
-
出版物
RSC Advances
Volume 4, Issue 12, Pages 6173
出版商
Royal Society of Chemistry (RSC)
发表日期
2013-12-06
DOI
10.1039/c3ra46996d
参考文献
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- Stereoselective Construction of Quaternary Carbon Stereocenters via a Semipinacol Rearrangement Strategy
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- Iron-Catalyzed CH Fuctionalization of Indoles
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- Bystanding F+ Oxidants Enable Selective Reductive Elimination from High-Valent Metal Centers in Catalysis
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- Oxidizing Directing Groups Enable Efficient and Innovative CH Activation Reactions
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- Oxidative Biaryl Coupling of Thiophenes and Thiazoles with Arylboronic Acids through Palladium Catalysis: Otherwise Difficult C4-Selective CH Arylation Enabled by Boronic Acids
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- Computationally Guided Stereocontrol of the Combined CH Functionalization/Cope Rearrangement
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- Oxidative and Enantioselective Cross-Coupling of Aldehydes and Nitromethane Catalyzed by Diphenylprolinol Silyl Ether
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- Modulating the Acidity: Highly Acidic Brønsted Acids in Asymmetric Catalysis
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- Catalytic Asymmetric Activation of a C sp 3H Bond Adjacent to a Nitrogen Atom: A Versatile Approach to Optically Active α-Alkyl α-Amino Acids and C1-Alkylated Tetrahydroisoquinoline Derivatives
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- Allylic CH Alkylation of Unactivated α-Olefins: Serial Ligand Catalysis Resumed
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- Enantioselective Intramolecular Benzylic CH Bond Amination: Efficient Synthesis of Optically Active Benzosultams
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- Enantioselective Rhodium(I)-Catalyzed [3+2] Annulations of Aromatic Ketimines Induced by Directed CH Activations
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- Fused Indolines by Palladium-Catalyzed Asymmetric CC Coupling Involving an Unactivated Methylene Group
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- N-Heterocyclic Carbene Catalyzed Domino Reactions
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- Biocatalytic Enantioselective Oxidative CC Coupling by Aerobic CH Activation
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- Magical Power of Transition Metals: Past, Present, and Future (Nobel Lecture)
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- If CH Bonds Could Talk: Selective CH Bond Oxidation
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- Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)
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- Enantioselective Rhodium-Catalyzed Allylic CH Activation for the Addition to Conjugated Dienes
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- Microwave-Assisted Organocatalytic Synthesis of Tetrahydroquinolines via Hydride Transfer and Cyclization
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- Enantioselective synthesis of 2-methyl indolines by palladium catalysed asymmetric C(sp3)–H activation/cyclisation
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- Synthesis of a [2.2]paracyclophane based planar chiral palladacycle by a highly selective kinetic resolution/C–H activation reaction
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- Transition-metal-catalyzed aminations and aziridinations of CH and CC bonds with iminoiodinanes
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- The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress†
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- Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions
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- Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds
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- Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope
- (2011) Lutz Ackermann CHEMICAL REVIEWS
- Chiral Brønsted acids in enantioselective carbonyl activations – activation modes and applications
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- Role of metal–oxo complexes in the cleavage of C–H bonds
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- C–H functionalization logic in total synthesis
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- Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts
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- Catalytic C–H amination: the stereoselectivity issue
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- Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds
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- Towards mild metal-catalyzed C–H bond activation
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- Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation
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- Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes
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- Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups
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- Gold catalysis in total synthesis—an update
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- Enantioselective Gold-Catalyzed Functionalization of Unreactive sp3 CH Bonds through a Redox-Neutral Domino Reaction
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- Highly Selective Rhodium Catalyzed Domino C–H Activation/Cyclizations
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- N-Heterocyclic Carbene-Catalyzed Redox Reactions of α-Functionalized Aldehydes
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- Tandem 1,5-Hydride Shift/6π Electrocyclization of Ketenimines and Carbodiimides Substituted with Cyclic Acetal and Dithioacetal Functions: Experiments and Computations
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- Dienamine Catalysis: An Emerging Technology in Organic Synthesis
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- Transition Metal-Catalyzed Formation of N-Heterocycles via Aryl- or Vinyl C-H Bond Amination
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- Dehydrogenative coupling reactions catalysed by Rose Bengal using visible light irradiation
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- Heterogeneous catalysts for carbene insertion reactions
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- Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C–H Functionalization
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- Rhodium(II)-Catalyzed Enantioselective C−H Functionalization of Indoles
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- Catalytic Asymmetric C–H Insertions of Rhodium(II) Azavinyl Carbenes
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- Ligand-Accelerated Cross-Coupling of C(sp2)–H Bonds with Arylboron Reagents
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- Combined C–H Functionalization/Cope Rearrangement with Vinyl Ethers as a Surrogate for the Vinylogous Mukaiyama Aldol Reaction
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- Pd(II)-Catalyzed Enantioselective C–H Activation of Cyclopropanes
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- Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile
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- Gold and Brønsted Acid Catalyzed Hydride Shift onto Allenes: Divergence in Product Selectivity
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- Highly Convergent Total Synthesis of (+)-Lithospermic Acid via a Late-Stage Intermolecular C−H Olefination
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- Selective Activation of Enantiotopic C(sp3)−Hydrogen by Means of Chiral Phosphoric Acid: Asymmetric Synthesis of Tetrahydroquinoline Derivatives
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- Divergent C–H Functionalizations Directed by Sulfonamide Pharmacophores: Late-Stage Diversification as a Tool for Drug Discovery
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- The Catalytic Asymmetric Fischer Indolization
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- Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies
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- A Diruthenium Catalyst for Selective, Intramolecular Allylic C–H Amination: Reaction Development and Mechanistic Insight Gained through Experiment and Theory
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- On the Mechanism and Selectivity of the Combined C−H Activation/Cope Rearrangement
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- Key Mechanistic Features of Enantioselective C–H Bond Activation Reactions Catalyzed by [(Chiral Mono-N-Protected Amino Acid)–Pd(II)] Complexes
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- Palladium Catalyzed Allylic C-H Alkylation: A Mechanistic Perspective
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- Diverting non-haem iron catalysed aliphatic C–H hydroxylations towards desaturations
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- Intramolecular catalytic asymmetric carbon–hydrogen insertion reactions. Synthetic advantages in total synthesis in comparison with alternative approaches
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- Enantioselective C–H carbene insertions with homogeneous and immobilized copper complexes
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- Organocatalytic Asymmetric Intermolecular Dehydrogenative α-Alkylation of Aldehydes Using Molecular Oxygen as Oxidant
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- α,β-Divinyl Tetrahydropyrroles as Chiral Chain Diene Ligands in Rhodium(I)-Catalyzed Enantioselective Conjugated Additions
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- Enantioselective Cyclization of 4-Alkenoic Acids via an Oxidative Allylic C–H Esterification
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- Highly Enantioselective Synthesis of Tetrahydroquinolines via Cobalt(II)-Catalyzed Tandem 1,5-Hydride Transfer/Cyclization
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- Ir(I)-Catalyzed Enantioselective Secondary sp3C–H Bond Activation of 2-(Alkylamino)pyridines with Alkenes
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- Stereoselective Rhodium-Catalyzed Amination of Alkenes
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- Rhodium-Catalyzed C–H Amination. An Enabling Method for Chemical Synthesis
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- N-Heterocyclic Pyridylmethylamines: Synthesis, Complexation, Molecular Structure, and Application to Asymmetric Suzuki–Miyaura and Oxidative Coupling Reactions
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- Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
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- β-Carbon Elimination from Cyclobutanols: A Clean Access to Alkylrhodium Intermediates Bearing a Quaternary Stereogenic Center
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- A reusable enantioselective catalytic system for the Kharasch–Sosnovsky allylic oxidation of alkenes based on a ditopic azabis(oxazoline) ligand
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- Asymmetric sp3 C–H functionalization via a chiral Brønsted acid-catalyzed redox reaction for the synthesis of cyclic aminals
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- Catalytic enantioselective C–H functionalization of indoles with α-diazopropionates using chiral dirhodium(II) carboxylates: asymmetric synthesis of the (+)-α-methyl-3-indolylacetic acid fragment of acremoauxin A
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- Hydroxyl-directed C–H carbonylation enabled by mono-N-protected amino acid ligands: An expedient route to 1-isochromanones
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- Organocatalytic enantioselective β-functionalization of aldehydes by oxidation of enamines and their application in cascade reactions
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- Challenge and progress: palladium-catalyzed sp3 C–H activation
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- Artificial Metalloenzymes Based on the Biotin−Avidin Technology: Enantioselective Catalysis and Beyond
- (2010) Thomas R. Ward ACCOUNTS OF CHEMICAL RESEARCH
- Constructing Multiply Substituted Arenes Using Sequential Palladium(II)-Catalyzed CH Olefination
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- Palladium-Catalyzed β Arylation of Carboxylic Esters
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- Enantioselective Palladium-Catalyzed Direct Alkylation and Olefination Reaction of Simple Arenes
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- Cross-Dehydrogenative Coupling Reactions by Transition-Metal and Aminocatalysis for the Synthesis of Amino Acid Derivatives
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- syn-Selective Rhodium(I)-Catalyzed Allylations of Ketimines Proceeding through a Directed CH Activation/Allene Addition Sequence
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- Enantioselective Oxidative Cross-Coupling Reaction of 3-Indolylmethyl CH Bonds with 1,3-Dicarbonyls Using a Chiral Lewis Acid-Bonded Nucleophile to Control Stereochemistry
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- Autoxidative Carbon-Carbon Bond Formation from Carbon-Hydrogen Bonds
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- Laboratory Evolution of Stereoselective Enzymes: A Prolific Source of Catalysts for Asymmetric Reactions
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- Product-selectivity control by the nature of the catalyst: Lewis acid-catalyzed selective formation of ring-fused tetrahydroquinolines and tetrahydroazepines via intramolecular redox reaction
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- Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation
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- Dual catalysis: combining photoredox and Lewis base catalysis for direct Mannich reactions
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- Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
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- Direct C−H Transformation via Iron Catalysis
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- Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products
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- Transition Metal Catalyzed Enantioselective α-Heterofunctionalization of Carbonyl Compounds
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- Copper-catalyzed azide–alkyne cycloaddition (CuAAC) and beyond: new reactivity of copper(i) acetylides
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- Organocatalytic strategies for the asymmetric functionalization of indoles
- (2010) Giuseppe Bartoli et al. CHEMICAL SOCIETY REVIEWS
- The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis
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- Enzymatic functionalization of carbon–hydrogen bonds
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- Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions
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- Gold-mediated C–H bond functionalisation
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- Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway
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- Tertiary Carbinamine Synthesis by Rhodium-Catalyzed [3+2] Annulation of N-Unsubstituted Aromatic Ketimines and Alkynes
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- Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis
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- Unifying Metal and Brønsted Acid Catalysis-Concepts, Mechanisms, and Classifications
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- Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation
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- Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction
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- Studies in catalytic C–H amination involving nitrene C–H insertion
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- Copper-Catalyzed Intramolecular C-H Amination
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- When Organocatalysis Meets Transition-Metal Catalysis
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- Cross-Coupling of C(sp3)-H Bonds with Organometallic Reagents via Pd(II)/Pd(0) Catalysis
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- Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover
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- Rhodium-Catalyzed Synthesis of Silafluorene Derivatives via Cleavage of Silicon−Hydrogen and Carbon−Hydrogen Bonds
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- Synthesis and Reactivity of Rhodium(II)N-Triflyl Azavinyl Carbenes
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- Pd(II)-Catalyzed Hydroxyl-Directed C−H Activation/C−O Cyclization: Expedient Construction of Dihydrobenzofurans
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- Pd(II)-Catalyzed Hydroxyl-Directed C−H Olefination Enabled by Monoprotected Amino Acid Ligands
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- Nature of Intermediates in Organo-SOMO Catalysis of α-Arylation of Aldehydes
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- Highly Enantioselective Intramolecular Copper Catalyzed C−H Insertion Reactions of α-Diazosulfones
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- Conjugated Diene-Assisted Allylic C−H Bond Activation: Cationic Rh(I)-Catalyzed Syntheses of Polysubstituted Tetrahydropyrroles, Tetrahydrofurans, and Cyclopentanes from Ene-2-Dienes
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- Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism
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- Enantioselective Polyene Cyclization via Organo-SOMO Catalysis
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- Hydroalkylation of Alkynyl Ethers via a Gold(I)-Catalyzed 1,5-Hydride Shift/Cyclization Sequence
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- Pd(II)-Catalyzed Olefination ofsp3C−H Bonds
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- Pd-Catalyzed Intermolecularortho-C−H Amidation of Anilides byN-Nosyloxycarbamate
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- Palladium-Catalyzed Amination of Aromatic C−H Bonds with Oxime Esters
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- Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center
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- Enantioenriched Synthesis ofC1-Symmetric BINOLs: Iron-Catalyzed Cross-Coupling of 2-Naphthols and Some Mechanistic Insight
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- Pd(II)-Catalyzed Carbonylation of C(sp3)−H Bonds: A New Entry to 1,4-Dicarbonyl Compounds
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- Enantioselective Organocatalytic C−H Bond Functionalization via Tandem 1,5-Hydride Transfer/Ring Closure: Asymmetric Synthesis of Tetrahydroquinolines
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- Catalytic Asymmetric Roskamp Reaction of α-Alkyl-α-diazoesters with Aromatic Aldehydes: Highly Enantioselective Synthesis of α-Alkyl-β-keto Esters
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- Organocatalytic cascade reactions as a new tool in total synthesis
- (2010) Christoph Grondal et al. Nature Chemistry
- Selectivity enhancement in functionalization of C–H bonds: A review
- (2010) Georgiy B. Shul'pin ORGANIC & BIOMOLECULAR CHEMISTRY
- Asymmetric copper-catalysed intramolecular C–H insertion reactions of α-diazo-β-keto sulfones
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- Expeditious Synthesis of Benzopyrans via Lewis Acid-Catalyzed C−H Functionalization: Remarkable Enhancement of Reactivity by anOrthoSubstituent
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- Efficient Synthesis of 1-Sulfonyl-1,2,3-triazoles
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- On the Mechanism of Ligand-Assisted, Copper-Catalyzed Benzylic Amination by Chloramine-T
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- Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation
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- Catalytic Oxidative Coupling Reactions for the Formation of Carbon-Carbon Bonds without Carbon-Metal Intermediates
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- Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations
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- Catalytic asymmetric C–H insertion reactions of α-diazocarbonyl compounds
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- Ligand-assisted, copper-catalyzed enantioselective benzylic amination
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- Solvent-free catalytic enantioselective C–C bond forming reactions with very high catalyst turnover numbers
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- Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation
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- Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds
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- A Direct Amine-Palladium Acetate Cocatalyzed Saegusa Oxidation Reaction of Unmodified Aldehydes to α,β-Unsaturated Aldehydes
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- Enantioselective Synthesis of Indanols from tert-Cyclobutanols Using a Rhodium-Catalyzed CC/CH Activation Sequence
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- Enantioselective Palladium-Catalyzed Direct Arylations at Ambient Temperature: Access to Indanes with Quaternary Stereocenters
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- Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality
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- Catalytic Functionalization of Indoles in a New Dimension
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- Development of Chiral Spiro Ligands for Metal-Catalyzed Asymmetric Reactions
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- Catalytic C–H amination: recent progress and future directions
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- Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C–H bond activation
- (2009) Andy S. Tsai et al. CHEMICAL COMMUNICATIONS
- Oxidative coupling of amines and ketones by combined vanadium- and organocatalysis
- (2009) Abhishek Sud et al. CHEMICAL COMMUNICATIONS
- Catalytic stereoselective benzylic C–H functionalizations by oxidative C–H activation and organocatalysis
- (2009) Fides Benfatti et al. CHEMICAL COMMUNICATIONS
- Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides
- (2009) Fabio Bellina et al. CHEMICAL REVIEWS
- Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
- (2009) Denise A. Colby et al. CHEMICAL REVIEWS
- Transition Metal Catalyzed Alkene and Alkyne Hydroacylation
- (2009) Michael C. Willis CHEMICAL REVIEWS
- Catalytic Carbene Insertion into C−H Bonds
- (2009) Michael P. Doyle et al. CHEMICAL REVIEWS
- C−H Activation for the Construction of C−B Bonds
- (2009) Ibraheem A. I. Mkhalid et al. CHEMICAL REVIEWS
- Combining transition metal catalysis and organocatalysis: a broad new concept for catalysis
- (2009) Zhihui Shao et al. CHEMICAL SOCIETY REVIEWS
- Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling
- (2009) Marisa C. Kozlowski et al. CHEMICAL SOCIETY REVIEWS
- Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity
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- Organopalladium(iv) chemistry
- (2009) Ling-Min Xu et al. CHEMICAL SOCIETY REVIEWS
- Expeditious Construction of Quinazolines via Brønsted Acid-induced C–H Activation: Further Extension of “tert-Amino Effect”
- (2009) Keiji Mori et al. CHEMISTRY LETTERS
- Stereoselective Restructuring of 3-Arylcyclobutanols into 1-Indanols by Sequential Breaking and Formation of CarbonâCarbon Bonds
- (2009) Masanori Shigeno et al. CHEMISTRY-A EUROPEAN JOURNAL
- Toward Efficient Palladium-Catalyzed Allylic CH Alkylation
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- CH bond activation in heme proteins: the role of thiolate ligation in cytochrome P450
- (2009) Michael T Green CURRENT OPINION IN CHEMICAL BIOLOGY
- Mechanisms of C–H bond activation: rich synergy between computation and experiment
- (2009) Youcef Boutadla et al. DALTON TRANSACTIONS
- Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes
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- Electrooxidative Desulfurization/Chlorination. A Facile Synthesis of 4-Chloro-2-azetidinones, a Potent Intermediate for Carbapenems
- (2009) Hideo Tanaka et al. HETEROCYCLES
- Highly Efficient, Enantioselective Syntheses of (S)-(+)- and (R)-(−)-Dapoxetine Starting with 3-Phenyl-1-propanol
- (2009) Soyeong Kang et al. JOURNAL OF ORGANIC CHEMISTRY
- Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters
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- Rhodium-Catalyzed Enantioselective Cyclopropanation of Olefins withN-Sulfonyl 1,2,3-Triazoles
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- Iron-Catalyzed Asymmetric Aerobic Oxidation: Oxidative Coupling of 2-Naphthols
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- Enantioselective Intramolecular Friedel−Crafts-Type α-Arylation of Aldehydes
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- Catalytic Enantioselective Intramolecular Redox Reactions: Ring-Fused Tetrahydroquinolines
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- C−H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp3C−H Bonds Catalyzed by Platinum Tetraiodide
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- Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis ofcis-Cyclopropane α-Amino Acids
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- Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions
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- Iridium(III) Catalyzed Diastereo- and Enantioselective C−H Bond Functionalization
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- Enantioselective α-Arylation of Aldehydes via Organo-SOMO Catalysis. An Ortho-Selective Arylation Reaction Based on an Open-Shell Pathway
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- Rhodium-Catalyzed [3 + 2] Annulation of Indoles
- (2009) Yajing Lian et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Pd(II)-Catalyzed Enantioselective C−H Olefination of Diphenylacetic Acids
- (2009) Bing-Feng Shi et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Asymmetric Desymmetrization of 4,5-Epoxycyclohex-1-ene by Enantioselective Allylic Oxidation
- (2009) Qitao Tan et al. ORGANIC LETTERS
- Enantioselective Reactions of Donor/Acceptor Carbenoids Derived from α-Aryl-α-Diazoketones
- (2009) Justin R. Denton et al. ORGANIC LETTERS
- C−H Bond Functionalization via Hydride Transfer: Synthesis of Dihydrobenzopyrans fromortho-Vinylaryl Akyl Ethers
- (2009) Kevin M. McQuaid et al. ORGANIC LETTERS
- Synthesis of Planar Chiral Phosphapalladacycles byN-Acyl Amino Acid Mediated Enantioselective Palladation
- (2009) M. Emin Günay et al. ORGANOMETALLICS
- Ligand-Enabled Reactivity and Selectivity in a Synthetically Versatile Aryl C-H Olefination
- (2009) D.-H. Wang et al. SCIENCE
- Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates
- (2009) Fabio Bellina et al. TETRAHEDRON
- Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation
- (2008) Jared C. Lewis et al. ACCOUNTS OF CHEMICAL RESEARCH
- Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations
- (2008) Chao-Jun Li ACCOUNTS OF CHEMICAL RESEARCH
- Asymmetric Synthesis of Polyfunctionalized Mono-, Bi-, and Tricyclic Carbon Frameworksvia Organocatalytic Domino Reactions
- (2008) Dieter Enders et al. ADVANCED SYNTHESIS & CATALYSIS
- Novel N,N-Bidentate Ligands for Enantioselective Copper(I)- Catalyzed Allylic Oxidation of Cyclic Olefins
- (2008) Qitao Tan et al. ADVANCED SYNTHESIS & CATALYSIS
- PdII-Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands
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- Highly Selective Metal Catalysts for Intermolecular Carbenoid Insertion into Primary CH Bonds and Enantioselective CC Bond Formation
- (2008) Hung-Yat Thu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Enantioselective CH Amination Using Cationic Ruthenium(II)-pybox Catalysts
- (2008) Erika Milczek et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Chiral Olefins as Steering Ligands in Asymmetric Catalysis
- (2008) Christian Defieber et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?
- (2008) Stephan Enthaler et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A Chiral Lewis Acid Strategy for Enantioselective Allylic CH Oxidation
- (2008) Dustin J. Covell et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Azaarene cis-dihydrodiol-derived 2,2′-bipyridine ligands for asymmetric allylic oxidation and cyclopropanation
- (2008) Derek R. Boyd et al. CHEMICAL COMMUNICATIONS
- Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions
- (2008) Masahiro Terada CHEMICAL COMMUNICATIONS
- Gold-Catalyzed Organic Transformations
- (2008) Zigang Li et al. CHEMICAL REVIEWS
- Ligand Effects in Homogeneous Au Catalysis
- (2008) David J. Gorin et al. CHEMICAL REVIEWS
- Recent advances in carbon–carbon bond-forming reactions involving homoenolates generated by NHC catalysis
- (2008) Vijay Nair et al. CHEMICAL SOCIETY REVIEWS
- Ruthenium catalyzed biomimetic oxidation in organic synthesis inspired by cytochrome P-450
- (2008) Shun-Ichi Murahashi et al. CHEMICAL SOCIETY REVIEWS
- Iron-catalysed carbon–heteroatom and heteroatom–heteroatom bond forming processes
- (2008) Arkaitz Correa et al. CHEMICAL SOCIETY REVIEWS
- De-racemization of Enantiomers versus De-epimerization of Diastereomers-Classification of Dynamic Kinetic Asymmetric Transformations (DYKAT)
- (2008) Johannes Steinreiber et al. CHEMISTRY-A EUROPEAN JOURNAL
- Chiral Boron-Bridged Bisoxazoline (Borabox) Ligands: Structures and Reactivities of Pd and Cu Complexes
- (2008) Valentin Köhler et al. CHEMISTRY-A EUROPEAN JOURNAL
- Theoretical Insights into Enantioselective Catalysis: The Mechanism of the Kharasch-Sosnovsky Reaction
- (2008) José Antonio Mayoral et al. CHEMISTRY-A EUROPEAN JOURNAL
- Heme-iron oxygenases: powerful industrial biocatalysts?
- (2008) Mattijs K Julsing et al. CURRENT OPINION IN CHEMICAL BIOLOGY
- Mechanistic Studies on the Catalytic Asymmetric Mannich-Type Reaction with Dihydroisoquinolines and Development of Oxidative Mannich-Type Reactions Starting from Tetrahydroisoquinolines
- (2008) Christian Dubs et al. JOURNAL OF ORGANIC CHEMISTRY
- Enantioselective Intramolecular Hydroarylation of Alkenes via Directed C−H Bond Activation
- (2008) Hitoshi Harada et al. JOURNAL OF ORGANIC CHEMISTRY
- Cationic iridium–BINAP complex-catalyzed addition of aryl ketones to alkynes and alkenes via directed C–H bond cleavage
- (2008) Kyoji Tsuchikama et al. JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Asymmetric Synthesis of (−)-Incarvillateine Employing an Intramolecular Alkylation via Rh-Catalyzed Olefinic C−H Bond Activation
- (2008) Andy S. Tsai et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Pd(II)-Catalyzed Cross-Coupling of sp3C−H Bonds with sp2and sp3Boronic Acids Using Air as the Oxidant
- (2008) Dong-Hui Wang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Synthesis of β-, γ-, and δ-Lactams via Pd(II)-Catalyzed C−H Activation Reactions
- (2008) Masayuki Wasa et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- A Chiral Rhodium Carboxamidate Catalyst for Enantioselective C−H Amination
- (2008) David N. Zalatan et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions
- (2008) Sarah E. Reisman et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles with Nitriles
- (2008) Tony Horneff et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalytic Asymmetric Allylic and Homoallylic Diamination of Terminal Olefins via Formal C−H Activation
- (2008) Haifeng Du et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective Organo-Singly Occupied Molecular Orbital Catalysis: The Carbo-oxidation of Styrenes
- (2008) Thomas H. Graham et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- C−H Bond Functionalization via Hydride Transfer: Lewis Acid Catalyzed Alkylation Reactions by Direct Intramolecular Coupling of sp3C−H Bonds and Reactive Alkenyl Oxocarbenium Intermediates
- (2008) Kevin M. McQuaid et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
- (2008) Huw M. L. Davies et al. NATURE
- A concerted mechanism for berberine bridge enzyme
- (2008) Andreas Winkler et al. Nature Chemical Biology
- Organocatalysis: asymmetric cascade reactions catalysed by chiral secondary amines
- (2008) Xinhong Yu et al. ORGANIC & BIOMOLECULAR CHEMISTRY
- Lewis Acid Catalyzed Formation of Tetrahydroquinolines via an Intramolecular Redox Process
- (2008) Sandip Murarka et al. ORGANIC LETTERS
- Asymmetric Allylic Oxidation Catalyzed by Copper(I) Complexes of Chiral (Iminophosphoranyl)ferrocenes
- (2008) Vo D. M. Hoang et al. ORGANOMETALLICS
- Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes
- (2008) D. A. Nicewicz et al. SCIENCE
- C–H bond functionalizations with palladium(II): intramolecular oxidative annulations of arenes
- (2008) Eric M. Ferreira et al. TETRAHEDRON
- The Fe(PDP)-catalyzed aliphatic C–H oxidation: a slow addition protocol
- (2008) Nicolaas A. Vermeulen et al. TETRAHEDRON
- A mechanistic analysis of the Rh-catalyzed intramolecular C–H amination reaction
- (2008) Kristin Williams Fiori et al. TETRAHEDRON
- Asymmetric formal synthesis of (−)-pancracine via catalytic enantioselective C–H amination process
- (2008) Masahiro Anada et al. TETRAHEDRON
- Function-Oriented Synthesis, Step Economy, and Drug Design
- (2007) Paul A. Wender et al. ACCOUNTS OF CHEMICAL RESEARCH
- Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis
- (2007) Zhan Lu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Recent advances in copper-catalyzed oxidation of organic compounds
- (2007) T. Punniyamurthy et al. COORDINATION CHEMISTRY REVIEWS
- Toward a Synthetically Useful Stereoselective C−H Amination of Hydrocarbons
- (2007) Chungen Liang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective Organo-SOMO Catalysis: The α-Vinylation of Aldehydes
- (2007) Hahn Kim et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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