Controlling Pd(iv) reductive elimination pathways enables Pd(ii)-catalysed enantioselective C(sp3)−H fluorination

The Evolution of Pd0/PdII-Catalyzed Aromatic Fluorination

(2016) Aaron C. Sather et al.   ACCOUNTS OF CHEMICAL RESEARCH

Benzazetidine synthesis via palladium-catalysed intramolecular C−H amination

(2016) Gang He et al.   Nature Chemistry

Functionalization of C(sp3)-H bonds using a transient directing group

(2016) F.-L. Zhang et al.   SCIENCE

Practical Synthesis ofanti-β-Hydroxy-α-Amino Acids by PdII-Catalyzed Sequential C(sp3)H Functionalization

(2015) Kai Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed Enantioselective Fluorination of Racemic, Secondary Allylic Trichloroacetimidates

(2015) Qi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled Stereoselective β-C(sp3)–H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino Acids

(2015) Ru-Yi Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Chiral β-Fluoro α-Amino Acids via Pd(II)-Catalyzed Fluorination of Unactivated Methylene C(sp3)–H Bonds: Scope and Mechanistic Studies

(2015) Qi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Radical Fluorination

(2015) Jean-François Paquin et al.   SYNTHESIS-STUTTGART

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Successful fluorine-containing herbicide agrochemicals

(2014) Tomoya Fujiwara et al.   JOURNAL OF FLUORINE CHEMISTRY

C(sp3)–O Bond-Forming Reductive Elimination from PdIV with Diverse Oxygen Nucleophiles

(2014) Nicole M. Camasso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Late Stage Benzylic C–H Fluorination with [18F]Fluoride for PET Imaging

(2014) Xiongyi Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Palladium-Catalyzed Directed Intermolecular Fluoroarylation of Styrenes

(2014) Eric P. A. Talbot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Competition between sp3-C–N vs sp3-C–F Reductive Elimination from PdIV Complexes

(2014) Mónica H. Pérez-Temprano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of Palladium-Catalyzed Allylic Fluorination

(2014) Matthew H. Katcher et al.   ORGANOMETALLICS

Anion-Dependent Switch in C–X Reductive Elimination Diastereoselectivity

(2014) Michael J. Geier et al.   ORGANOMETALLICS

An efficient one-pot synthesis of 1,2,4-triazoloquinoxalines

(2014) Xiaoyi Niu et al.   TETRAHEDRON

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Allylic C–H Fluorination

(2013) Marie-Gabrielle Braun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Cyclization and C3-Fluorination of Polyenes

(2013) Nikki A. Cochrane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination

(2013) Ji-Bao Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Polycomponent Metal-Catalyzed Aliphatic, Allylic, and Benzylic Fluorination

(2012) Steven Bloom et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes

(2012) Joy M. Racowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine Transfer to Alkyl Radicals

(2012) Montserrat Rueda-Becerril et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed C–H Fluorination with Nucleophilic Fluoride

(2012) Kate B. McMurtrey et al.   ORGANIC LETTERS

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Bystanding F+ Oxidants Enable Selective Reductive Elimination from High-Valent Metal Centers in Catalysis

(2011) Keary M. Engle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed Selective Monofluorination of Benzoic Acids Using a Practical Auxiliary: A Weak-Coordination Approach

(2011) Kelvin S. L. Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal catalysis and nucleophilic fluorination

(2011) Charlotte Hollingworth et al.   CHEMICAL COMMUNICATIONS

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Steric Crowding Makes Challenging Csp3–F Reductive Eliminations Feasible

(2011) Shu-Bin Zhao et al.   ORGANOMETALLICS

Asymmetric Electrophilic Fluorination Using an Anionic Chiral Phase-Transfer Catalyst

(2011) V. Rauniyar et al.   SCIENCE

Palladium-Catalyzed Asymmetric Synthesis of Allylic Fluorides

(2010) Matthew H. Katcher et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides

(2010) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Ring Opening of Epoxides by Fluoride Anion Promoted by a Cooperative Dual-Catalyst System

(2010) Julia A. Kalow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Carboamination of Alkenes Promoted byN-Fluorobenzenesulfonimide via C−H Activation of Arenes

(2009) Carolyn F. Rosewall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism ofN-Fluorobenzenesulfonimide Promoted Diamination and Carboamination Reactions: Divergent Reactivity of a Pd(IV) Species

(2009) Paul A. Sibbald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatile Pd(OTf)2·2H2O-Catalyzedortho-Fluorination Using NMP as a Promoter

(2009) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS

Xenon Difluoride Induced Aryl Iodide Reductive Elimination:  a Simple Access to Difluoropalladium(II) Complexes

(2007) Ariela W. Kaspi et al.   INORGANIC CHEMISTRY