Stereodivergent and Protecting-Group-Free Synthesis of the Helicascolide Family: A Rhodium-Catalyzed Atom-Economical Lactonization Strategy

Regio- and Enantioselective Synthesis of N-Substituted Pyrazoles by Rhodium-Catalyzed Asymmetric Addition to Allenes

(2015) Alexander M. Haydl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Z-Selective Hydrothiolation of Racemic 1,3-Disubstituted Allenes: An Atom-Economic Rhodium-Catalyzed Dynamic Kinetic Resolution

(2015) Adrian B. Pritzius et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones

(2015) Adrian B. Pritzius et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification

(2015) Alexander M. Haydl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-catalyzed asymmetric cyclization of alkenoic acids leading to γ-lactones

(2015) Midori Nagamoto et al.   CHEMICAL COMMUNICATIONS

Iridium-Catalyzed C–C Coupling of a Simple Propargyl Ether with Primary Alcohols: Enantioselective Homoaldol Addition via Redox-Triggered (Z)-Siloxyallylation

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Redox-Neutral Rh-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2015) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and Enantioselective Lactonization Reactions

(2015) Xing-Zhong Shu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of 3-Hydroxy-3-trifluoromethyl Benzofuranones via Tandem Friedel–Crafts/Lactonization Reaction

(2015) Hai Ren et al.   ORGANIC LETTERS

Catalytic and Highly Enantioselective Selenolactonization

(2015) Wenxue Niu et al.   ORGANIC LETTERS

Regioselective Rhodium-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Terminal Alkynes

(2015) Thorsten M. Beck et al.   ORGANIC LETTERS

Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Addition of 2-Pyridones to Terminal Allenes

(2014) Changkun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unlocking theN2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of the Antimitotic Marine Macrolide (−)-Leiodermatolide

(2014) Ian Paterson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom-Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (18S)- and (18R)-Homolargazole by Rhodium-Catalyzed Hydrocarboxylation

(2014) Christoph Schotes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Mediated/Catalyzed Oxyalkylation of Alkenes with Alkylnitriles

(2014) Ala Bunescu et al.   CHEMISTRY-A EUROPEAN JOURNAL

One-Pot Sequential Organocatalytic Michael–Tishchenko–Lactonization Reactions. Synthesis of Enantioenriched 4,5,6-Trisubstituted δ-Lactones

(2014) James O. Guevara-Pulido et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Asymmetric Intermolecular Hydroalkoxylation of Allene: An Entry to Cyclic Acetals with Activating Group-Free and Flexible Anomeric Control

(2014) Wontaeck Lim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Allenes: Efficient Construction of Tertiary and Quaternary Carbon Centers

(2014) Changkun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of a Concise Synthesis of (+)-Ingenol

(2014) Steven J. McKerrall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discovery of a Highly Potent Anti-inflammatory Epoxyisoprostane-Derived Lactone

(2014) Julian Egger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and their Applications in Organic Synthesis

(2013) Alexandre Lumbroso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

14-Step Synthesis of (+)-Ingenol from (+)-3-Carene

(2013) L. Jorgensen et al.   SCIENCE

Concise Total Synthesis of Helicascolides A, B, and C

(2013) Jhillu Yadav et al.   SYNTHESIS-STUTTGART

Concise total synthesis of botryolide B

(2013) Debendra K. Mohapatra et al.   RSC Advances

Enantioselective Rhodium-Catalyzed Synthesis of Branched Allylic Amines by Intermolecular Hydroamination of Terminal Allenes

(2012) Michael L. Cooke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalysed Enantioselective Addition of OH and NH Bonds to Allenes: A New Model for Stereoselectivity Based on Noncovalent Interactions

(2012) Jannine L. Arbour et al.   CHEMISTRY-A EUROPEAN JOURNAL

Directed Metal (Oxo) Aliphatic C–H Hydroxylations: Overriding Substrate Bias

(2012) Marinus A. Bigi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

First stereoselective total synthesis of helicascolides A and C

(2012) Palakodety Radha Krishna et al.   TETRAHEDRON LETTERS

Iodolactonization: Synthesis, Stereocontrol, and Compatibility Studies

(2011) Martins S. Oderinde et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthetic Versatility in C–H Oxidation: A Rapid Approach to Differentiated Diols and Pyrans from Simple Olefins

(2011) Paul E. Gormisky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2011) Alexandre Lumbroso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids

(2011) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalysed direct C–C coupling of methanol and allenes

(2011) Joseph Moran et al.   Nature Chemistry

Helicascolide C, a new lactone from an Indonesian marine algicolous strain of Daldinia eschscholzii (Xylariaceae, Ascomycota)

(2011) Kustiariyah Tarman et al.   Phytochemistry Letters

Atom economic macrolactonization and lactonization viaredox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids

(2011) Alexandre Lumbroso et al.   Chemical Science

Catalytic Asymmetric Formation of δ-Lactones from Unsaturated Acyl Halides

(2010) Paolo S. Tiseni et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of (+)-Chinensiolide B via Tandem Allylboration/Lactonization

(2010) Tim G. Elford et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism of Allylic C−H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2Catalyst System: Insights into the Effect of Naphthoquinone

(2010) Guoyin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis base catalysis of bromo- and iodolactonization, and cycloetherification

(2010) S. E. Denmark et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

(2009) Takahiro Kawamoto et al.   CHEMICAL COMMUNICATIONS

A General and Efficient Catalyst System for a Wacker-Type Oxidation Using TBHP as the Terminal Oxidant: Application to Classically Challenging Substrates

(2009) Brian W. Michel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Enantioselective Allylic Amination Reaction Using a Commercially Available Chiral Rhodium Catalyst: Resolution of Racemic Allylic Carbonates

(2009) Derek C. Vrieze et al.   ORGANIC LETTERS

Copper-catalysed intramolecular O–H addition to unactivated alkenes

(2009) Luis A. Adrio et al.   TETRAHEDRON

Iridium-Catalyzed Hydrocarboxylation of 1,1-Dimethylallene:  Byproduct-Free Reverse Prenylation of Carboxylic Acids

(2008) In Su Kim et al.   ORGANIC LETTERS

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION