Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones

Unlocking theN2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom-Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Allenes: Efficient Construction of Tertiary and Quaternary Carbon Centers

(2014) Changkun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Realistic Energy Surfaces for Real-World Systems: An IMOMO CCSD(T):DFT Scheme for Rhodium-Catalyzed Hydroformylation with the 6-DPPon Ligand

(2013) Urs Gellrich et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Fluorinated α-Sulfonyl Carbanions: Enantioselective Synthesis and Electrophilic Capture, Racemization Dynamics, and Structure

(2013) Gunther Hellmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Investigations of the Rhodium Catalyzed Propargylic CH Activation

(2013) Urs Gellrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Hydrothiolation of Alkynes by Sulfonyl Hydrazides Using Organic Ionic Base–Brønsted Acid

(2013) Rahul Singh et al.   ORGANIC LETTERS

Rhodium-catalyzed hydroformylation of alkynes employing a self-assembling ligand system

(2013) Vladislav Agabekov et al.   Chemical Science

Enantioselective Allylic Thioetherification: The Effect of Phosphoric Acid Diester on Iridium-Catalyzed Enantioconvergent Transformations

(2012) Markus Roggen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Synthesis of Branched Allylic Amines by Intermolecular Hydroamination of Terminal Allenes

(2012) Michael L. Cooke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)-Catalyzed Stereoconvergent, Intermolecular Enantioselective Hydroamination of Allenes

(2012) Kristina L. Butler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Insights into a Supramolecular Self-Assembling Catalyst System: Evidence for Hydrogen Bonding during Rhodium-Catalyzed Hydroformylation

(2012) Urs Gellrich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Emergence of Transition-Metal-Mediated Hydrothiolation of Unsaturated Carbon-Carbon Bonds: A Mechanistic Outlook

(2012) Ricardo Castarlenas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Chiral Sulfones by Ir-Catalyzed Asymmetric Hydrogenation: A Facile Approach to the Preparation of Chiral Allylic and Homoallylic Compounds

(2012) Taigang Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regioselectivity in the Hydrothiolation of Alkynes by Rhodium N-Heterocyclic Carbene Catalysts

(2012) Andrea Di Giuseppe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One pot iridium-catalyzed asymmetrical double allylations of sodium sulfide: a fast and economic way to construct chiral C2-symmetric bis(1-substituted-allyl)sulfane

(2011) Shengcai Zheng et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions

(2011) Irina P. Beletskaya et al.   CHEMICAL REVIEWS

Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2011) Alexandre Lumbroso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids

(2011) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalysed direct C–C coupling of methanol and allenes

(2011) Joseph Moran et al.   Nature Chemistry

Iridium-catalyzed asymmetric allylation of sodium triisopropylsilanethiolate: A new way to form chiral thiols

(2011) Weiqing Huang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Carbon−Sulfur Bond Formation via Iridium-Catalyzed Asymmetric Allylation of Aliphatic Thiols

(2011) Ning Gao et al.   ORGANIC LETTERS

Enantioselective carbon–sulfur bond formation: γ additions of aryl thiols to allenoates catalyzed by a chiral phosphepine

(2011) Yuji Fujiwara et al.   Chemical Science

Atom economic macrolactonization and lactonization viaredox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids

(2011) Alexandre Lumbroso et al.   Chemical Science

Highly efficient catalytic dehydrative S-allylation of thiols and thioic S-acids

(2010) Shinji Tanaka et al.   CHEMICAL COMMUNICATIONS

Enantioselective Synthesis, Configurational Stability, and Reactivity of Lithium α-tert-Butylsulfonyl Carbanion Salts

(2010) Roland Scholz et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cyclic Sulfones as Novel P3-Caps for Hepatitis C Virus NS3/4A (HCV NS3/4A) Protease Inhibitors: Synthesis and Evaluation of Inhibitors with Improved Potency and Pharmacokinetic Profiles

(2010) Francisco Velázquez et al.   JOURNAL OF MEDICINAL CHEMISTRY

Phosphine-Catalyzed Formation of Carbon−Sulfur Bonds: Catalytic Asymmetric Synthesis of γ-Thioesters

(2010) Jianwei Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism of Allylic C−H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2Catalyst System: Insights into the Effect of Naphthoquinone

(2010) Guoyin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Enantioselective Iridium-Catalyzed Allylation of Thiophenol: Synthesis of Enantiopure Allyl Phenyl Sulfides

(2010) Shengcai Zheng et al.   ORGANIC LETTERS

Gold-catalyzed regiospecific intermolecular hydrothiolation of allenes

(2010) Menggenbateer et al.   TETRAHEDRON LETTERS

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

(2009) Takahiro Kawamoto et al.   CHEMICAL COMMUNICATIONS

Fast Ruthenium-Catalysed Allylation of Thiols by Using Allyl Alcohols as Substrates

(2009) Alexey B. Zaitsev et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-metal-catalyzed hydrothiolation of cyclohexylallene with benzenethiol or diphenyl disulfide

(2009) Shintaro Kodama et al.   Journal of Sulfur Chemistry

A Highly Enantioselective Allylic Amination Reaction Using a Commercially Available Chiral Rhodium Catalyst: Resolution of Racemic Allylic Carbonates

(2009) Derek C. Vrieze et al.   ORGANIC LETTERS

Readily Prepared 3-Chloro-1-(phenylthio)propene, a Versatile Three-Carbon Annulating Agent

(2009) Taoping Liu et al.   ORGANIC LETTERS

Selective C−S Bond Formation via Fe-Catalyzed Allylic Substitution

(2009) Markus Jegelka et al.   ORGANIC LETTERS

Iridium-Catalyzed, Regio- and Enantioselective Allylic Substitution with Aromatic and Aliphatic Sulfinates

(2009) Mitsuhiro Ueda et al.   ORGANIC LETTERS

Synthesis of 1,1-Disubstituted Alkyl Vinyl Sulfides via Rhodium-Catalyzed Alkyne Hydrothiolation: Scope and Limitations

(2008) Jun Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Allyl Sulfides Are Privileged Substrates in Aqueous Cross-Metathesis: Application to Site-Selective Protein Modification

(2008) Yuya A. Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Hydrocarboxylation of 1,1-Dimethylallene:  Byproduct-Free Reverse Prenylation of Carboxylic Acids

(2008) In Su Kim et al.   ORGANIC LETTERS

Synthesis of 1,1-Disubstituted Olefins via Catalytic Alkyne Hydrothiolation/Kumada Cross-Coupling

(2008) Anthony Sabarre et al.   ORGANIC LETTERS

π-Allylic Sulfonylation in Water with Amphiphilic Resin-Supported Palladium-Phosphine Complexes

(2008) Yasuhiro Uozumi et al.   SYNTHESIS-STUTTGART

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION